10NaCl + 2CaCrO4 → 5Na2O + 3Cl2↑ + Cr2O3 + 2CaCl2
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- Reaction of sodium chloride and calcium chromate
The reaction of sodium chloride and calcium chromate yields sodium oxide, , chromium(III) oxide, and calcium chloride (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of sodium chloride and calcium chromate
General equation
- Reaction of hardly oxidizable species and oxidizing species
- Hardly oxidizable speciesReducing agent + Oxidizing speciesOxidizing agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of sodium chloride and calcium chromate
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| NaCl | Sodium chloride | 10 | Reducing | Hardly oxidizable |
| CaCrO4 | Calcium chromate | 2 | Oxidizing | Oxidizing |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| Na2O | Sodium oxide | 5 | – | – |
| 3 | Oxidized | – | ||
| Cr2O3 | Chromium(III) oxide | 1 | Reduced | – |
| CaCl2 | Calcium chloride | 2 | – | – |
Thermodynamic changes
Changes in aqueous solution (1)
- Reaction of sodium chloride and calcium chromate
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 1960.2 | – | – | – |
per 1 mol of | 196.02 | – | – | – |
per 1 mol of | 980.10 | – | – | – |
per 1 mol of | 392.04 | – | – | – |
| 653.40 | – | – | – | |
per 1 mol of | 1960.2 | – | – | – |
per 1 mol of | 980.10 | – | – | – |
Changes in aqueous solution (2)
- Reaction of sodium chloride and calcium chromate
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 1890.0 | – | – | – |
per 1 mol of | 189.00 | – | – | – |
per 1 mol of | 945.00 | – | – | – |
per 1 mol of | 378.00 | – | – | – |
| 630.00 | – | – | – | |
per 1 mol of | 1890.0 | – | – | – |
per 1 mol of | 945.00 | – | – | – |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| NaCl (cr) | -411.153[1] | -384.138[1] | 72.13[1] | 50.50[1] |
| NaCl (g) | -176.65[1] | -196.66[1] | 229.81[1] | 35.77[1] |
| NaCl (ai) | -407.27[1] | -393.133[1] | 115.5[1] | -90.0[1] |
| CaCrO4 (aq) | -1426.3[1] | – | – | – |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (aq):Aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| Na2O (cr) | -414.22[1] | -375.46[1] | 75.06[1] | 69.12[1] |
| Na2O (g) | -35.6[1] | -52.3[1] | 261.2[1] | 55.2[1] |
| (g) | 0[1] | 0[1] | 223.066[1] | 33.907[1] |
| (ao) | -23.4[1] | 6.94[1] | 121[1] | – |
| Cr2O3 (cr) | -1139.7[1] | -1058.1[1] | 81.2[1] | 118.74[1] |
| Cr2O3 (cr) 1 hydrate | -1506[1] | – | – | – |
| Cr2O3 (cr) 2 hydrate | -1845[1] | – | – | – |
| Cr2O3 (cr) 3 hydrate | -2171[1] | – | – | – |
| CaCl2 (cr) | -795.8[1] | -748.1[1] | 104.6[1] | 72.59[1] |
| CaCl2 (g) | -471.5[1] | -479.24[1] | 290.27[1] | 59.33[1] |
| CaCl2 (ai) | -877.13[1] | -816.01[1] | 59.8[1] | – |
| CaCl2 (cr) 1 hydrate | -1109.2[1] | – | – | – |
| CaCl2 (cr) 2 hydrate | -1402.9[1] | – | – | – |
| CaCl2 (cr) 4 hydrate | -2009.6[1] | – | – | – |
| CaCl2 (cr) 6 hydrate | -2607.9[1] | – | – | – |
* (cr):Crystalline solid, (g):Gas, (ao):Un-ionized aqueous solution, (ai):Ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -411.153 kJ · mol−1
- ^ ΔfG°, -384.138 kJ · mol−1
- ^ S°, 72.13 J · K−1 · mol−1
- ^ Cp°, 50.50 J · K−1 · mol−1
- ^ ΔfH°, -176.65 kJ · mol−1
- ^ ΔfG°, -196.66 kJ · mol−1
- ^ S°, 229.81 J · K−1 · mol−1
- ^ Cp°, 35.77 J · K−1 · mol−1
- ^ ΔfH°, -407.27 kJ · mol−1
- ^ ΔfG°, -393.133 kJ · mol−1
- ^ S°, 115.5 J · K−1 · mol−1
- ^ Cp°, -90.0 J · K−1 · mol−1
- ^ ΔfH°, -1426.3 kJ · mol−1
- ^ ΔfH°, -414.22 kJ · mol−1
- ^ ΔfG°, -375.46 kJ · mol−1
- ^ S°, 75.06 J · K−1 · mol−1
- ^ Cp°, 69.12 J · K−1 · mol−1
- ^ ΔfH°, -35.6 kJ · mol−1
- ^ ΔfG°, -52.3 kJ · mol−1
- ^ S°, 261.2 J · K−1 · mol−1
- ^ Cp°, 55.2 J · K−1 · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 223.066 J · K−1 · mol−1
- ^ Cp°, 33.907 J · K−1 · mol−1
- ^ ΔfH°, -23.4 kJ · mol−1
- ^ ΔfG°, 6.94 kJ · mol−1
- ^ S°, 121. J · K−1 · mol−1
- ^ ΔfH°, -1139.7 kJ · mol−1
- ^ ΔfG°, -1058.1 kJ · mol−1
- ^ S°, 81.2 J · K−1 · mol−1
- ^ Cp°, 118.74 J · K−1 · mol−1
- ^ ΔfH°, -1506. kJ · mol−1
- ^ ΔfH°, -1845. kJ · mol−1
- ^ ΔfH°, -2171. kJ · mol−1
- ^ ΔfH°, -795.8 kJ · mol−1
- ^ ΔfG°, -748.1 kJ · mol−1
- ^ S°, 104.6 J · K−1 · mol−1
- ^ Cp°, 72.59 J · K−1 · mol−1
- ^ ΔfH°, -471.5 kJ · mol−1
- ^ ΔfG°, -479.24 kJ · mol−1
- ^ S°, 290.27 J · K−1 · mol−1
- ^ Cp°, 59.33 J · K−1 · mol−1
- ^ ΔfH°, -877.13 kJ · mol−1
- ^ ΔfG°, -816.01 kJ · mol−1
- ^ S°, 59.8 J · K−1 · mol−1
- ^ ΔfH°, -1109.2 kJ · mol−1
- ^ ΔfH°, -1402.9 kJ · mol−1
- ^ ΔfH°, -2009.6 kJ · mol−1
- ^ ΔfH°, -2607.9 kJ · mol−1