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15Cu + 8Pb3(PO4)2 ๐Ÿ”ฅโ†’ 5Cu3(PO4)2 + 6P + 24PbO

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Reaction of copper and lead(II) phosphate
15CuCopper + 8Pb3(PO4)2Lead(II) phosphate
๐Ÿ”ฅ
โŸถ
5Cu3(PO4)2Copper(II) phosphate + 6PPhosphorus + 24PbOLead(II) oxide

The reaction of copper and lead(II) phosphate yields copper(II) phosphate, phosphorus, and lead(II) oxide (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

Reaction of copper and lead(II) phosphate
15CuCopper + 8Pb3(PO4)2Lead(II) phosphate
๐Ÿ”ฅ
โŸถ
5Cu3(PO4)2Copper(II) phosphate + 6PPhosphorus + 24PbOLead(II) oxide

General equation

Reaction of oxidizable species and reducible species
Oxidizable speciesReducing agent + Reducible speciesOxidizing agent
๐Ÿ”ฅ
โŸถ
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reaction of copper and lead(II) phosphate

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
CuCopper15
Reducing
Oxidizable
Pb3(PO4)2Lead(II) phosphate8
Oxidizing
Reducible

Products

Chemical formulaNameCoefficientTypeType in general
equation
Cu3(PO4)2Copper(II) phosphate5
Oxidized
โ€“
PPhosphorus6
Reduced
โ€“
PbOLead(II) oxide24
โ€“
โ€“

Thermodynamic changes

Changes in standard condition (1)

Reaction of copper and lead(II) phosphate
15CuCrystalline solid + 8Pb3(PO4)2Crystalline solid
๐Ÿ”ฅ
โŸถ
5Cu3(PO4)2Crystalline solid + 6PCrystalline solidwhite + 24PbOCrystalline solidmassicot, yellow
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“

Changes in standard condition (2)

Reaction of copper and lead(II) phosphate
15CuCrystalline solid + 8Pb3(PO4)2Crystalline solid
๐Ÿ”ฅ
โŸถ
5Cu3(PO4)2Crystalline solid + 6PCrystalline solidwhite + 24PbOCrystalline solidlitharge, red
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“

Changes in standard condition (3)

Reaction of copper and lead(II) phosphate
15CuCrystalline solid + 8Pb3(PO4)2Crystalline solid
๐Ÿ”ฅ
โŸถ
5Cu3(PO4)2Crystalline solid + 6PCrystalline solidred, triclinic + 24PbOCrystalline solidmassicot, yellow
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“

Changes in standard condition (4)

Reaction of copper and lead(II) phosphate
15CuCrystalline solid + 8Pb3(PO4)2Crystalline solid
๐Ÿ”ฅ
โŸถ
5Cu3(PO4)2Crystalline solid + 6PCrystalline solidred, triclinic + 24PbOCrystalline solidlitharge, red
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“

Changes in standard condition (5)

Reaction of copper and lead(II) phosphate
15CuCrystalline solid + 8Pb3(PO4)2Crystalline solid
๐Ÿ”ฅ
โŸถ
5Cu3(PO4)2Crystalline solid + 6PCrystalline solidblack + 24PbOCrystalline solidmassicot, yellow
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“

Changes in standard condition (6)

Reaction of copper and lead(II) phosphate
15CuCrystalline solid + 8Pb3(PO4)2Crystalline solid
๐Ÿ”ฅ
โŸถ
5Cu3(PO4)2Crystalline solid + 6PCrystalline solidblack + 24PbOCrystalline solidlitharge, red
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“

Changes in standard condition (7)

Reaction of copper and lead(II) phosphate
15CuCrystalline solid + 8Pb3(PO4)2Crystalline solid
๐Ÿ”ฅ
โŸถ
5Cu3(PO4)2Crystalline solid + 6PAmorphous solidred + 24PbOCrystalline solidmassicot, yellow
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“

Changes in standard condition (8)

Reaction of copper and lead(II) phosphate
15CuCrystalline solid + 8Pb3(PO4)2Crystalline solid
๐Ÿ”ฅ
โŸถ
5Cu3(PO4)2Crystalline solid + 6PAmorphous solidred + 24PbOCrystalline solidlitharge, red
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“

Changes in aqueous solution

Reaction of copper and lead(II) phosphate
15CuCrystalline solid + 8Pb3(PO4)2Crystalline solid
๐Ÿ”ฅ
โŸถ
5Cu3(PO4)2Crystalline solid + 6PCrystalline solidwhite + 24PbOCrystalline solidmassicot, yellow
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“
per 1 mol of
โ€“โ€“โ€“โ€“

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ฮ”fHยฐ
kJ ยท molโˆ’1		Standard Gibbs
energy of
formation
ฮ”fGยฐ
kJ ยท molโˆ’1		Standard
molar entropy
Sยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard molar
heat capacity at
constant pressure
Cpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Cu (cr)0[1]0[1]33.150[1]24.435[1]
Cu (g)338.32[1]298.58[1]166.38[1]20.786[1]
Pb3(PO4)2 (cr)โ€“โ€“353.1[1]256.27[1]
* (cr):Crystalline solid, (g):Gas

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ฮ”fHยฐ
kJ ยท molโˆ’1		Standard Gibbs
energy of
formation
ฮ”fGยฐ
kJ ยท molโˆ’1		Standard
molar entropy
Sยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard molar
heat capacity at
constant pressure
Cpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Cu3(PO4)2 (cr)โ€“-2051.3[1]โ€“โ€“
P (cr)
white
0[1]0[1]41.09[1]23.84[1]
P (cr)
red, triclinic
-17.6[1]-12.1[1]22.80[1]21.21[1]
P (cr)
black
-39.3[1]โ€“โ€“โ€“
P (am)
red
-7.5[1]โ€“โ€“โ€“
P (g)314.64[1]278.25[1]163.193[1]20.786[1]
PbO (cr)
massicot, yellow
-217.32[1]-187.89[1]68.70[1]45.77[1]
PbO (cr)
litharge, red
-218.99[1]-188.93[1]66.5[1]45.81[1]
PbO (cr)
1/3 hydrate
โ€“-266.5[1]โ€“โ€“
* (cr):Crystalline solid, (am):Amorphous solid, (g):Gas

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)