Chemical formula	Name	Coefficient	Type	Type in general equation
Li₂O	Lithium oxide	9	–	–
MnO₂	Manganese(IV) oxide	48	Reduced	–
Al(OH)₃	Aluminium hydroxide	8	Oxidized	–
Al₂O₃	Aluminium oxide	5	–	–
KOH	Potassium hydroxide	48	Oxidized	–

Thermodynamic changes

Changes in standard condition (1)

Reaction of lithium tetrahydridoaluminate and potassium permanganate ◆ Δ_rG −27723 kJ/mol K 7.24 × 10⁴⁸⁵⁶ pK −4856.86: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Crystalline solid + 8Al(OH)₃Crystalline solid + 5Al₂O₃Crystalline solidα, corundum + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−27103	−27723	−2165	200.2
per 1 mol of Lithium tetrahydridoaluminate	−1505.7	−1540.2	−120.3	11.12
per 1 mol of Potassium permanganate	−564.65	−577.56	−45.10	4.171
per 1 mol of Lithium oxide	−3011.4	−3080.3	−240.6	22.24
per 1 mol of Manganese(IV) oxide	−564.65	−577.56	−45.10	4.171
per 1 mol of Aluminium hydroxide	−3387.9	−3465.4	−270.6	25.02
per 1 mol of Aluminium oxide	−5420.6	−5544.6	−433.0	40.04
per 1 mol of Potassium hydroxide	−564.65	−577.56	−45.10	4.171

Changes in standard condition (2)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Crystalline solid + 8Al(OH)₃Crystalline solid + 5Al₂O₃Crystalline solidδ + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−27057	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1503.2	–	–	–
per 1 mol of Potassium permanganate	−563.69	–	–	–
per 1 mol of Lithium oxide	−3006.3	–	–	–
per 1 mol of Manganese(IV) oxide	−563.69	–	–	–
per 1 mol of Aluminium hydroxide	−3382.1	–	–	–
per 1 mol of Aluminium oxide	−5411.4	–	–	–
per 1 mol of Potassium hydroxide	−563.69	–	–	–

Changes in standard condition (3)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Crystalline solid + 8Al(OH)₃Crystalline solid + 5Al₂O₃Crystalline solidρ + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−27010	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1500.6	–	–	–
per 1 mol of Potassium permanganate	−562.71	–	–	–
per 1 mol of Lithium oxide	−3001.1	–	–	–
per 1 mol of Manganese(IV) oxide	−562.71	–	–	–
per 1 mol of Aluminium hydroxide	−3376.3	–	–	–
per 1 mol of Aluminium oxide	−5402.0	–	–	–
per 1 mol of Potassium hydroxide	−562.71	–	–	–

Changes in standard condition (4)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Crystalline solid + 8Al(OH)₃Crystalline solid + 5Al₂O₃Crystalline solidκ + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−27036	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1502.0	–	–	–
per 1 mol of Potassium permanganate	−563.25	–	–	–
per 1 mol of Lithium oxide	−3004.0	–	–	–
per 1 mol of Manganese(IV) oxide	−563.25	–	–	–
per 1 mol of Aluminium hydroxide	−3379.5	–	–	–
per 1 mol of Aluminium oxide	−5407.2	–	–	–
per 1 mol of Potassium hydroxide	−563.25	–	–	–

Changes in standard condition (5)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Crystalline solid + 8Al(OH)₃Crystalline solid + 5Al₂O₃Crystalline solidγ + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−27009	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1500.5	–	–	–
per 1 mol of Potassium permanganate	−562.69	–	–	–
per 1 mol of Lithium oxide	−3001.0	–	–	–
per 1 mol of Manganese(IV) oxide	−562.69	–	–	–
per 1 mol of Aluminium hydroxide	−3376.1	–	–	–
per 1 mol of Aluminium oxide	−5401.8	–	–	–
per 1 mol of Potassium hydroxide	−562.69	–	–	–

Changes in standard condition (6)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Crystalline solid + 8Al(OH)₃Crystalline solid + 5Al₂O₃Amorphous solid + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−26885	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1493.6	–	–	–
per 1 mol of Potassium permanganate	−560.10	–	–	–
per 1 mol of Lithium oxide	−2987.2	–	–	–
per 1 mol of Manganese(IV) oxide	−560.10	–	–	–
per 1 mol of Aluminium hydroxide	−3360.6	–	–	–
per 1 mol of Aluminium oxide	−5377.0	–	–	–
per 1 mol of Potassium hydroxide	−560.10	–	–	–

Changes in standard condition (7)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Crystalline solid + 8Al(OH)₃Amorphous solid + 5Al₂O₃Crystalline solidα, corundum + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−27039	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1502.2	–	–	–
per 1 mol of Potassium permanganate	−563.31	–	–	–
per 1 mol of Lithium oxide	−3004.3	–	–	–
per 1 mol of Manganese(IV) oxide	−563.31	–	–	–
per 1 mol of Aluminium hydroxide	−3379.9	–	–	–
per 1 mol of Aluminium oxide	−5407.8	–	–	–
per 1 mol of Potassium hydroxide	−563.31	–	–	–

Changes in standard condition (8)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Crystalline solid + 8Al(OH)₃Amorphous solid + 5Al₂O₃Crystalline solidδ + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−26993	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1499.6	–	–	–
per 1 mol of Potassium permanganate	−562.35	–	–	–
per 1 mol of Lithium oxide	−2999.2	–	–	–
per 1 mol of Manganese(IV) oxide	−562.35	–	–	–
per 1 mol of Aluminium hydroxide	−3374.1	–	–	–
per 1 mol of Aluminium oxide	−5398.6	–	–	–
per 1 mol of Potassium hydroxide	−562.35	–	–	–

Changes in standard condition (9)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Crystalline solid + 8Al(OH)₃Amorphous solid + 5Al₂O₃Crystalline solidρ + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−26946	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1497.0	–	–	–
per 1 mol of Potassium permanganate	−561.38	–	–	–
per 1 mol of Lithium oxide	−2994.0	–	–	–
per 1 mol of Manganese(IV) oxide	−561.38	–	–	–
per 1 mol of Aluminium hydroxide	−3368.3	–	–	–
per 1 mol of Aluminium oxide	−5389.2	–	–	–
per 1 mol of Potassium hydroxide	−561.38	–	–	–

Changes in standard condition (10)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Crystalline solid + 8Al(OH)₃Amorphous solid + 5Al₂O₃Crystalline solidκ + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−26972	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1498.4	–	–	–
per 1 mol of Potassium permanganate	−561.92	–	–	–
per 1 mol of Lithium oxide	−2996.9	–	–	–
per 1 mol of Manganese(IV) oxide	−561.92	–	–	–
per 1 mol of Aluminium hydroxide	−3371.5	–	–	–
per 1 mol of Aluminium oxide	−5394.4	–	–	–
per 1 mol of Potassium hydroxide	−561.92	–	–	–

Changes in standard condition (11)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Crystalline solid + 8Al(OH)₃Amorphous solid + 5Al₂O₃Crystalline solidγ + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−26945	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1496.9	–	–	–
per 1 mol of Potassium permanganate	−561.35	–	–	–
per 1 mol of Lithium oxide	−2993.9	–	–	–
per 1 mol of Manganese(IV) oxide	−561.35	–	–	–
per 1 mol of Aluminium hydroxide	−3368.1	–	–	–
per 1 mol of Aluminium oxide	−5389.0	–	–	–
per 1 mol of Potassium hydroxide	−561.35	–	–	–

Changes in standard condition (12)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Crystalline solid + 8Al(OH)₃Amorphous solid + 5Al₂O₃Amorphous solid + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−26821	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1490.1	–	–	–
per 1 mol of Potassium permanganate	−558.77	–	–	–
per 1 mol of Lithium oxide	−2980.1	–	–	–
per 1 mol of Manganese(IV) oxide	−558.77	–	–	–
per 1 mol of Aluminium hydroxide	−3352.6	–	–	–
per 1 mol of Aluminium oxide	−5364.2	–	–	–
per 1 mol of Potassium hydroxide	−558.77	–	–	–

Changes in standard condition (13)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Amorphous solidprecipitated + 8Al(OH)₃Crystalline solid + 5Al₂O₃Crystalline solidα, corundum + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−26262	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1459.0	–	–	–
per 1 mol of Potassium permanganate	−547.13	–	–	–
per 1 mol of Lithium oxide	−2918.0	–	–	–
per 1 mol of Manganese(IV) oxide	−547.13	–	–	–
per 1 mol of Aluminium hydroxide	−3282.8	–	–	–
per 1 mol of Aluminium oxide	−5252.4	–	–	–
per 1 mol of Potassium hydroxide	−547.13	–	–	–

Changes in standard condition (14)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Amorphous solidprecipitated + 8Al(OH)₃Crystalline solid + 5Al₂O₃Crystalline solidδ + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−26216	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1456.4	–	–	–
per 1 mol of Potassium permanganate	−546.17	–	–	–
per 1 mol of Lithium oxide	−2912.9	–	–	–
per 1 mol of Manganese(IV) oxide	−546.17	–	–	–
per 1 mol of Aluminium hydroxide	−3277.0	–	–	–
per 1 mol of Aluminium oxide	−5243.2	–	–	–
per 1 mol of Potassium hydroxide	−546.17	–	–	–

Changes in standard condition (15)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Amorphous solidprecipitated + 8Al(OH)₃Crystalline solid + 5Al₂O₃Crystalline solidρ + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−26168	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1453.8	–	–	–
per 1 mol of Potassium permanganate	−545.17	–	–	–
per 1 mol of Lithium oxide	−2907.6	–	–	–
per 1 mol of Manganese(IV) oxide	−545.17	–	–	–
per 1 mol of Aluminium hydroxide	−3271.0	–	–	–
per 1 mol of Aluminium oxide	−5233.6	–	–	–
per 1 mol of Potassium hydroxide	−545.17	–	–	–

Changes in standard condition (16)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Amorphous solidprecipitated + 8Al(OH)₃Crystalline solid + 5Al₂O₃Crystalline solidκ + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−26195	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1455.3	–	–	–
per 1 mol of Potassium permanganate	−545.73	–	–	–
per 1 mol of Lithium oxide	−2910.6	–	–	–
per 1 mol of Manganese(IV) oxide	−545.73	–	–	–
per 1 mol of Aluminium hydroxide	−3274.4	–	–	–
per 1 mol of Aluminium oxide	−5239.0	–	–	–
per 1 mol of Potassium hydroxide	−545.73	–	–	–

Changes in standard condition (17)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Amorphous solidprecipitated + 8Al(OH)₃Crystalline solid + 5Al₂O₃Crystalline solidγ + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−26168	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1453.8	–	–	–
per 1 mol of Potassium permanganate	−545.17	–	–	–
per 1 mol of Lithium oxide	−2907.6	–	–	–
per 1 mol of Manganese(IV) oxide	−545.17	–	–	–
per 1 mol of Aluminium hydroxide	−3271.0	–	–	–
per 1 mol of Aluminium oxide	−5233.6	–	–	–
per 1 mol of Potassium hydroxide	−545.17	–	–	–

Changes in standard condition (18)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Amorphous solidprecipitated + 8Al(OH)₃Crystalline solid + 5Al₂O₃Amorphous solid + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−26043	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1446.8	–	–	–
per 1 mol of Potassium permanganate	−542.56	–	–	–
per 1 mol of Lithium oxide	−2893.7	–	–	–
per 1 mol of Manganese(IV) oxide	−542.56	–	–	–
per 1 mol of Aluminium hydroxide	−3255.4	–	–	–
per 1 mol of Aluminium oxide	−5208.6	–	–	–
per 1 mol of Potassium hydroxide	−542.56	–	–	–

Changes in standard condition (19)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Amorphous solidprecipitated + 8Al(OH)₃Amorphous solid + 5Al₂O₃Crystalline solidα, corundum + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−26198	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1455.4	–	–	–
per 1 mol of Potassium permanganate	−545.79	–	–	–
per 1 mol of Lithium oxide	−2910.9	–	–	–
per 1 mol of Manganese(IV) oxide	−545.79	–	–	–
per 1 mol of Aluminium hydroxide	−3274.8	–	–	–
per 1 mol of Aluminium oxide	−5239.6	–	–	–
per 1 mol of Potassium hydroxide	−545.79	–	–	–

Changes in standard condition (20)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Amorphous solidprecipitated + 8Al(OH)₃Amorphous solid + 5Al₂O₃Crystalline solidδ + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−26152	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1452.9	–	–	–
per 1 mol of Potassium permanganate	−544.83	–	–	–
per 1 mol of Lithium oxide	−2905.8	–	–	–
per 1 mol of Manganese(IV) oxide	−544.83	–	–	–
per 1 mol of Aluminium hydroxide	−3269.0	–	–	–
per 1 mol of Aluminium oxide	−5230.4	–	–	–
per 1 mol of Potassium hydroxide	−544.83	–	–	–

Changes in standard condition (21)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Amorphous solidprecipitated + 8Al(OH)₃Amorphous solid + 5Al₂O₃Crystalline solidρ + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−26104	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1450.2	–	–	–
per 1 mol of Potassium permanganate	−543.83	–	–	–
per 1 mol of Lithium oxide	−2900.4	–	–	–
per 1 mol of Manganese(IV) oxide	−543.83	–	–	–
per 1 mol of Aluminium hydroxide	−3263.0	–	–	–
per 1 mol of Aluminium oxide	−5220.8	–	–	–
per 1 mol of Potassium hydroxide	−543.83	–	–	–

Changes in standard condition (22)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Amorphous solidprecipitated + 8Al(OH)₃Amorphous solid + 5Al₂O₃Crystalline solidκ + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−26131	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1451.7	–	–	–
per 1 mol of Potassium permanganate	−544.40	–	–	–
per 1 mol of Lithium oxide	−2903.4	–	–	–
per 1 mol of Manganese(IV) oxide	−544.40	–	–	–
per 1 mol of Aluminium hydroxide	−3266.4	–	–	–
per 1 mol of Aluminium oxide	−5226.2	–	–	–
per 1 mol of Potassium hydroxide	−544.40	–	–	–

Changes in standard condition (23)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Amorphous solidprecipitated + 8Al(OH)₃Amorphous solid + 5Al₂O₃Crystalline solidγ + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−26104	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1450.2	–	–	–
per 1 mol of Potassium permanganate	−543.83	–	–	–
per 1 mol of Lithium oxide	−2900.4	–	–	–
per 1 mol of Manganese(IV) oxide	−543.83	–	–	–
per 1 mol of Aluminium hydroxide	−3263.0	–	–	–
per 1 mol of Aluminium oxide	−5220.8	–	–	–
per 1 mol of Potassium hydroxide	−543.83	–	–	–

Changes in standard condition (24)

Reaction of lithium tetrahydridoaluminate and potassium permanganate: 18Li[AlH₄]Crystalline solid + 48KMnO₄Crystalline solid
⟶
9Li₂OCrystalline solid + 48MnO₂Amorphous solidprecipitated + 8Al(OH)₃Amorphous solid + 5Al₂O₃Amorphous solid + 48KOHCrystalline solid

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−25979	–	–	–
per 1 mol of Lithium tetrahydridoaluminate	−1443.3	–	–	–
per 1 mol of Potassium permanganate	−541.23	–	–	–
per 1 mol of Lithium oxide	−2886.6	–	–	–
per 1 mol of Manganese(IV) oxide	−541.23	–	–	–
per 1 mol of Aluminium hydroxide	−3247.4	–	–	–
per 1 mol of Aluminium oxide	−5195.8	–	–	–
per 1 mol of Potassium hydroxide	−541.23	–	–	–

Changes in aqueous solution

Reaction of lithium tetrahydridoaluminate and potassium permanganate ◆ Δ_rG −31012 kJ/mol K 1.17 × 10⁵⁴³³ pK −5433.07: 18Li[AlH₄]Crystalline solid + 48KMnO₄Ionized aqueous solution
⟶
9Li₂OCrystalline solid + 48MnO₂Crystalline solid + 8Al(OH)₃Crystalline solid + 5Al₂O₃Crystalline solidα, corundum + 48KOHIonized aqueous solution

	Standard enthalpy of reaction Δ_rH° kJ · mol⁻¹	Standard Gibbs energy of reaction Δ_rG° kJ · mol⁻¹	Standard entropy of reaction Δ_rS° J · K⁻¹ · mol⁻¹	Standard heat capacity of reaction at constant pressure Δ_rC_p° J · K⁻¹ · mol⁻¹
per 1 mol of Equation	−31951	−31012	−7411	−468.4
per 1 mol of Lithium tetrahydridoaluminate	−1775.1	−1722.9	−411.7	−26.02
per 1 mol of Potassium permanganate	−665.65	−646.08	−154.4	−9.758
per 1 mol of Lithium oxide	−3550.1	−3445.8	−823.4	−52.04
per 1 mol of Manganese(IV) oxide	−665.65	−646.08	−154.4	−9.758
per 1 mol of Aluminium hydroxide	−3993.9	−3876.5	−926.4	−58.55
per 1 mol of Aluminium oxide	−6390.2	−6202.4	−1482	−93.68
per 1 mol of Potassium hydroxide	−665.65	−646.08	−154.4	−9.758

Thermodynamic data of reactants

Chemical formula	Standard enthalpy of formation Δ_fH° kJ · mol⁻¹	Standard Gibbs energy of formation Δ_fG° kJ · mol⁻¹	Standard molar entropy S° J · K⁻¹ · mol⁻¹	Standard molar heat capacity at constant pressure C_p° J · K⁻¹ · mol⁻¹
Li[AlH₄] (cr)	-116.3^[1]	-44.7^[1]	78.74^[1]	83.18^[1]
KMnO₄ (cr)	-837.2^[1]	-737.6^[1]	171.71^[1]	117.57^[1]
KMnO₄ (ai)	-793.8^[1]	-730.5^[1]	293.7^[1]	-60.2^[1]

* (cr):Crystalline solid, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formula	Standard enthalpy of formation Δ_fH° kJ · mol⁻¹	Standard Gibbs energy of formation Δ_fG° kJ · mol⁻¹	Standard molar entropy S° J · K⁻¹ · mol⁻¹	Standard molar heat capacity at constant pressure C_p° J · K⁻¹ · mol⁻¹
Li₂O (cr)	-597.94^[1]	-561.18^[1]	37.57^[1]	54.10^[1]
Li₂O (g)	-160.7^[1]	-181.6^[1]	231.48^[1]	49.83^[1]
MnO₂ (cr)	-520.03^[1]	-465.14^[1]	53.05^[1]	54.14^[1]
MnO₂ (am) precipitated	-502.5^[1]	–	–	–
Al(OH)₃ (cr)	-1284^[2]	-1306^[2]	71^[2]	93.1^[2]
Al(OH)₃ (am)	-1276^[1]	–	–	–
Al₂O₃ (cr) α, corundum	-1675.7^[1]	-1582.3^[1]	50.92^[1]	79.04^[1]
Al₂O₃ (cr) δ	-1666.5^[1]	–	–	–
Al₂O₃ (cr) ρ	-1657^[1]	–	–	–
Al₂O₃ (cr) κ	-1662.3^[1]	–	–	–
Al₂O₃ (cr) γ	-1656.9^[1]	–	–	–
Al₂O₃ (am)	-1632^[1]	–	–	–
Al₂O₃ (cr) 1 hydrate	-1998.91^[1]	-1841.78^[1]	70.67^[1]	106.19^[1]
Al₂O₃ (cr) 3 hydrate	-2576.5^[1]	–	–	–
KOH (cr)	-424.764^[1]	-379.08^[1]	78.9^[1]	64.9^[1]
KOH (g)	-231.0^[1]	-232.6^[1]	238.3^[1]	49.20^[1]
KOH (ai)	-482.37^[1]	-440.50^[1]	91.6^[1]	-126.8^[1]
KOH (cr) 1 hydrate	-748.9^[1]	-645.1^[1]	117.2^[1]	–
KOH (cr) 2 hydrate	-1051.0^[1]	-887.3^[1]	150.6^[1]	–

* (cr):Crystalline solid, (g):Gas, (am):Amorphous solid, (ai):Ionized aqueous solution

References

List of references

1
Janiel J. Reed (1989)
The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
https://doi.org/10.18434/M32124
National Institute of Standards and Technology (NIST)
Citation list
2
James G. Speight (2017)
Lange's Handbook of Chemistry, 17th edition
https://www.accessengineeringlibrary.com/content/book/9781259586095
McGraw Hill Education
- Amazon
Citation list
- ^ Δ_fH°, -1284 kJ · mol⁻¹ - p.254
- ^ Δ_fG°, -1306 kJ · mol⁻¹ - p.254
- ^ S°, 71 J · K⁻¹ · mol⁻¹ - p.254
- ^ C_p°, 93.1 J · K⁻¹ · mol⁻¹ - p.254

Δ_rG	−27723 kJ/mol
K	7.24 × 10⁴⁸⁵⁶
pK	−4856.86

Δ_rG	−31012 kJ/mol
K	1.17 × 10⁵⁴³³
pK	−5433.07

18Li[AlH4] + 48KMnO4 → 9Li2O + 48MnO2 + 8Al(OH)3 + 5Al2O3 + 48KOH

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Products

Thermodynamic changes

Changes in standard condition (1)

Changes in standard condition (2)

Changes in standard condition (3)

Changes in standard condition (4)

Changes in standard condition (5)

Changes in standard condition (6)

Changes in standard condition (7)

Changes in standard condition (8)

Changes in standard condition (9)

Changes in standard condition (10)

Changes in standard condition (11)

Changes in standard condition (12)

Changes in standard condition (13)

Changes in standard condition (14)

Changes in standard condition (15)

Changes in standard condition (16)

Changes in standard condition (17)

Changes in standard condition (18)

Changes in standard condition (19)

Changes in standard condition (20)

Changes in standard condition (21)

Changes in standard condition (22)

Changes in standard condition (23)

Changes in standard condition (24)

Changes in aqueous solution

Thermodynamic data of reactants

Thermodynamic data of products

References

List of references

Related reactions

Reactions with same reactants

Related categories

Type of reaction

General equation

Reactant

Product

18Li[AlH₄] + 48KMnO₄ → 9Li₂O + 48MnO₂ + 8Al(OH)₃ + 5Al₂O₃ + 48KOH