BaS + Rb2CO3 💧→ BaCO3↓ + Rb2S
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The reaction of barium sulfide and rubidium carbonate yields barium carbonate and rubidium sulfide. This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of barium sulfide and rubidium carbonate
General equation
- Precipitation reaction
- Miscible with water/Very soluble in water/Soluble in waterLewis acid + Miscible with water/Very soluble in water/Soluble in waterLewis base💧⟶ Insoluble in water/Very slightly soluble in water/Slightly soluble in waterLewis conjugate + Product(Non-redox product)
Oxidation state of each atom
- Reaction of barium sulfide and rubidium carbonate
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
BaS | Barium sulfide | 1 | Lewis acid | Soluble in water |
Rb2CO3 | Rubidium carbonate | 1 | Lewis base | Very soluble in water |
Products
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
BaCO3 | Barium carbonate | 1 | Lewis conjugate | Insoluble in water |
Rb2S | Rubidium sulfide | 1 | Non-redox product | – |
Thermodynamic changes
Changes in standard condition
- Reaction of barium sulfide and rubidium carbonate
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | 19 | – | – | – |
per 1 mol of | 19 | – | – | – |
per 1 mol of | 19 | – | – | – |
per 1 mol of | 19 | – | – | – |
per 1 mol of | 19 | – | – | – |
Changes in aqueous solution
- Reaction of barium sulfide and rubidium carbonate
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −12.9 | – | – | – |
per 1 mol of | −12.9 | – | – | – |
per 1 mol of | −12.9 | – | – | – |
per 1 mol of | −12.9 | – | – | – |
per 1 mol of | −12.9 | – | – | – |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
BaS (cr) | -460[1] | -456[1] | 78.2[1] | 49.37[1] |
BaS (g) | 50[1] | – | – | – |
BaS (aq) | -493.3[1] | – | – | – |
Rb2CO3 (cr) | -1136.0[1] | -1051.0[1] | 181.33[1] | 117.61[1] |
Rb2CO3 (ai) | -1179.47[1] | -1095.78[1] | 186.2[1] | – |
Rb2CO3 (cr) 1 hydrate | -1448.5[1] | – | – | – |
Rb2CO3 (cr) 1.5 hydrate | -1604.5[1] | – | – | – |
Rb2CO3 (cr) 3 hydrate | -2048.1[1] | – | – | – |
* (cr):Crystalline solid, (g):Gas, (aq):Aqueous solution, (ai):Ionized aqueous solution
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
BaCO3 (cr) | -1216.3[1] | -1137.6[1] | 112.1[1] | 85.35[1] |
BaCO3 (ai) | -1214.78[1] | -1088.59[1] | -47.3[1] | – |
Rb2S (cr) | -360.7[1] | – | – | – |
Rb2S (ai) | -469.4[1] | -482.0[1] | 228.4[1] | – |
* (cr):Crystalline solid, (ai):Ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -460. kJ · mol−1
- ^ ΔfG°, -456. kJ · mol−1
- ^ S°, 78.2 J · K−1 · mol−1
- ^ Cp°, 49.37 J · K−1 · mol−1
- ^ ΔfH°, 50. kJ · mol−1
- ^ ΔfH°, -493.3 kJ · mol−1
- ^ ΔfH°, -1136.0 kJ · mol−1
- ^ ΔfG°, -1051.0 kJ · mol−1
- ^ S°, 181.33 J · K−1 · mol−1
- ^ Cp°, 117.61 J · K−1 · mol−1
- ^ ΔfH°, -1179.47 kJ · mol−1
- ^ ΔfG°, -1095.78 kJ · mol−1
- ^ S°, 186.2 J · K−1 · mol−1
- ^ ΔfH°, -1448.5 kJ · mol−1
- ^ ΔfH°, -1604.5 kJ · mol−1
- ^ ΔfH°, -2048.1 kJ · mol−1
- ^ ΔfH°, -1216.3 kJ · mol−1
- ^ ΔfG°, -1137.6 kJ · mol−1
- ^ S°, 112.1 J · K−1 · mol−1
- ^ Cp°, 85.35 J · K−1 · mol−1
- ^ ΔfH°, -1214.78 kJ · mol−1
- ^ ΔfG°, -1088.59 kJ · mol−1
- ^ S°, -47.3 J · K−1 · mol−1
- ^ ΔfH°, -360.7 kJ · mol−1
- ^ ΔfH°, -469.4 kJ · mol−1
- ^ ΔfG°, -482.0 kJ · mol−1
- ^ S°, 228.4 J · K−1 · mol−1