C6H5SO3− + H2O → C6H5O− + SO32− + 2H+
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The reaction of benzenesulfonate ion and water yields phenolate ion, sulfurous ion, and hydrogen ion (Other reactions are here). This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of benzenesulfonate ion and water
General equation
- Cation/AnionBrønsted acid + H2OBrønsted base ⟶ Proton accepting ion/BaseConjugate base + H+Conjugate acid
Oxidation state of each atom
- Reaction of benzenesulfonate ion and water
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| C6H5SO3− | Benzenesulfonate ion | 1 | Brønsted acid | Anion |
| H2O | Water | 1 | Brønsted base | Water |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| C6H5O− | Phenolate ion | 1 | Conjugate base | Proton accepting ion |
| SO32− | Sulfurous ion | 1 | Conjugate base | Proton accepting ion |
| H+ | Hydrogen ion | 2 | Conjugate acid | Hydrogen ion |
Thermodynamic changes
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| C6H5SO3− | – | – | – | – |
| H2O (cr) | – | – | – | – |
| H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
| H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
* (cr):Crystalline solid, (l):Liquid, (g):Gas
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| C6H5O− | – | – | – | – |
| SO32− (ao) | -635.5[1] | -486.5[1] | -29[1] | – |
| H+ (g) | 1536.202[1] | – | – | – |
| H+ (ao) | 0[1] | 0[1] | 0[1] | 0[1] |
* (ao):Un-ionized aqueous solution, (g):Gas
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1
- ^ ΔfH°, -635.5 kJ · mol−1
- ^ ΔfG°, -486.5 kJ · mol−1
- ^ S°, -29. J · K−1 · mol−1
- ^ ΔfH°, 1536.202 kJ · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 0 J · K−1 · mol−1
- ^ Cp°, 0 J · K−1 · mol−1