CaCrO4 → Ca2+ + CrO42−
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- Electrolytic dissociation of calcium chromate
Electrolytic dissociation of calcium chromate yields calcium ion and chromate ion. This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Electrolytic dissociation of calcium chromate
General equation
- Electrolytic dissociation of salt
- SaltLewis conjugate ⟶ CationLewis acid + AnionLewis base
Oxidation state of each atom
- Electrolytic dissociation of calcium chromate
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| CaCrO4 | Calcium chromate | 1 | Lewis conjugate | Salt |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| Ca2+ | Calcium ion | 1 | Lewis acid | Cation |
| CrO42− | Chromate ion | 1 | Lewis base | Anion |
Thermodynamic changes
Changes in aqueous solution
- Electrolytic dissociation of calcium chromate
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 2.3 | – | – | – |
per 1 mol of | 2.3 | – | – | – |
per 1 mol of Calcium ion | 2.3 | – | – | – |
per 1 mol of Chromate ion | 2.3 | – | – | – |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| CaCrO4 (aq) | -1426.3[1] | – | – | – |
* (aq):Aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| Ca2+ (g) | 1925.90[1] | – | – | – |
| Ca2+ (ao) | -542.83[1] | -553.58[1] | -53.1[1] | – |
| CrO42− (ao) | -881.15[1] | -727.75[1] | 50.21[1] | – |
* (g):Gas, (ao):Un-ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)