Ca(NO3)2 + Li2CO3 ๐งโ CaCO3โ + 2LiNO3
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- Reaction of calcium nitrate and lithium carbonate
The reaction of calcium nitrate and lithium carbonate yields calcium carbonate and lithium nitrate. This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of calcium nitrate and lithium carbonate
General equation
- Precipitation reaction
- Miscible with water/Very soluble in water/Soluble in waterLewis acid + Miscible with water/Very soluble in water/Soluble in waterLewis base๐งโถ Insoluble in water/Very slightly soluble in water/Slightly soluble in waterLewis conjugate + Product(Non-redox product)
Oxidation state of each atom
- Reaction of calcium nitrate and lithium carbonate
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| Ca(NO3)2 | Calcium nitrate | 1 | Lewis acid | Very soluble in water |
| Li2CO3 | Lithium carbonate | 1 | Lewis base | Soluble in water |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| CaCO3 | Calcium carbonate | 1 | Lewis conjugate | Insoluble in water |
| LiNO3 | Lithium nitrate | 2 | Non-redox product | โ |
Thermodynamic changes
Changes in standard condition
- Reaction of calcium nitrate and lithium carbonateโ
ฮrG โ14.8 kJ/mol K 3.92 ร 102 pK โ2.59
| Standard enthalpy of reaction ฮrHยฐ kJ ยท molโ1 | Standard Gibbs energy of reaction ฮrGยฐ kJ ยท molโ1 | Standard entropy of reaction ฮrSยฐ J ยท Kโ1 ยท molโ1 | Standard heat capacity of reaction at constant pressure ฮrCpยฐ J ยท Kโ1 ยท molโ1 | |
|---|---|---|---|---|
per 1 mol of Equation | โ19.1 | โ14.8 | โ15.0 | โ |
per 1 mol of | โ19.1 | โ14.8 | โ15.0 | โ |
per 1 mol of | โ19.1 | โ14.8 | โ15.0 | โ |
per 1 mol of | โ19.1 | โ14.8 | โ15.0 | โ |
per 1 mol of | โ9.55 | โ7.40 | โ7.50 | โ |
Changes in aqueous solution (1)
- Reaction of calcium nitrate and lithium carbonateโ
ฮrG โ28.6 kJ/mol K 1.02 ร 105 pK โ5.01
| Standard enthalpy of reaction ฮrHยฐ kJ ยท molโ1 | Standard Gibbs energy of reaction ฮrGยฐ kJ ยท molโ1 | Standard entropy of reaction ฮrSยฐ J ยท Kโ1 ยท molโ1 | Standard heat capacity of reaction at constant pressure ฮrCpยฐ J ยท Kโ1 ยท molโ1 | |
|---|---|---|---|---|
per 1 mol of Equation | โ5.4 | โ28.6 | 79.0 | โ |
per 1 mol of | โ5.4 | โ28.6 | 79.0 | โ |
per 1 mol of | โ5.4 | โ28.6 | 79.0 | โ |
per 1 mol of | โ5.4 | โ28.6 | 79.0 | โ |
per 1 mol of | โ2.7 | โ14.3 | 39.5 | โ |
Changes in aqueous solution (2)
- Reaction of calcium nitrate and lithium carbonateโ
ฮrG โ32.8 kJ/mol K 5.58 ร 105 pK โ5.75
| Standard enthalpy of reaction ฮrHยฐ kJ ยท molโ1 | Standard Gibbs energy of reaction ฮrGยฐ kJ ยท molโ1 | Standard entropy of reaction ฮrSยฐ J ยท Kโ1 ยท molโ1 | Standard heat capacity of reaction at constant pressure ฮrCpยฐ J ยท Kโ1 ยท molโ1 | |
|---|---|---|---|---|
per 1 mol of Equation | โ | โ32.8 | โ | โ |
per 1 mol of | โ | โ32.8 | โ | โ |
per 1 mol of | โ | โ32.8 | โ | โ |
per 1 mol of | โ | โ32.8 | โ | โ |
per 1 mol of | โ | โ16.4 | โ | โ |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ฮfHยฐ kJ ยท molโ1 | Standard Gibbs energy of formation ฮfGยฐ kJ ยท molโ1 | Standard molar entropy Sยฐ J ยท Kโ1 ยท molโ1 | Standard molar heat capacity at constant pressure Cpยฐ J ยท Kโ1 ยท molโ1 |
|---|---|---|---|---|
| Ca(NO3)2 (cr) | -938.39[1] | -743.07[1] | 193.3[1] | 149.37[1] |
| Ca(NO3)2 (ai) | -957.55[1] | -776.09[1] | 239.7[1] | โ |
| Ca(NO3)2 (cr) 2 hydrate | -1540.76[1] | -1229.11[1] | 269.4[1] | โ |
| Ca(NO3)2 (cr) 3 hydrate | -1838.0[1] | -1471.7[1] | 319.2[1] | โ |
| Ca(NO3)2 (cr) 4 hydrate | -2132.33[1] | -1713.15[1] | 375.3[1] | โ |
| Li2CO3 (cr) | -1215.9[1] | -1132.06[1] | 90.37[1] | 99.12[1] |
| Li2CO3 (ai) | -1234.11[1] | -1114.6[1] | -29.7[1] | โ |
* (cr):Crystalline solid, (ai):Ionized aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ฮfHยฐ kJ ยท molโ1 | Standard Gibbs energy of formation ฮfGยฐ kJ ยท molโ1 | Standard molar entropy Sยฐ J ยท Kโ1 ยท molโ1 | Standard molar heat capacity at constant pressure Cpยฐ J ยท Kโ1 ยท molโ1 |
|---|---|---|---|---|
| CaCO3 (cr) | -1207.13[1] | -1127.75[1] | 88.7[1] | 81.25[1] |
| CaCO3 (ai) | -1219.97[1] | -1081.39[1] | -110.0[1] | โ |
| LiNO3 (cr) | -483.13[1] | -381.1[1] | 90.0[1] | โ |
| LiNO3 (ai) | -485.85[1] | -404.5[1] | 160.2[1] | -18.0[1] |
| LiNO3 (ao) | โ | -406.6[1] | โ | โ |
| LiNO3 (cr) 3 hydrate | -1374.4[1] | -1103.5[1] | 223.4[1] | โ |
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ฮfHยฐ, -938.39 kJ ยท molโ1
- ^ ฮfGยฐ, -743.07 kJ ยท molโ1
- ^ Sยฐ, 193.3 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 149.37 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -957.55 kJ ยท molโ1
- ^ ฮfGยฐ, -776.09 kJ ยท molโ1
- ^ Sยฐ, 239.7 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1540.76 kJ ยท molโ1
- ^ ฮfGยฐ, -1229.11 kJ ยท molโ1
- ^ Sยฐ, 269.4 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1838.0 kJ ยท molโ1
- ^ ฮfGยฐ, -1471.7 kJ ยท molโ1
- ^ Sยฐ, 319.2 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -2132.33 kJ ยท molโ1
- ^ ฮfGยฐ, -1713.15 kJ ยท molโ1
- ^ Sยฐ, 375.3 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1215.9 kJ ยท molโ1
- ^ ฮfGยฐ, -1132.06 kJ ยท molโ1
- ^ Sยฐ, 90.37 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 99.12 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1234.11 kJ ยท molโ1
- ^ ฮfGยฐ, -1114.6 kJ ยท molโ1
- ^ Sยฐ, -29.7 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1207.13 kJ ยท molโ1
- ^ ฮfGยฐ, -1127.75 kJ ยท molโ1
- ^ Sยฐ, 88.7 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 81.25 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1219.97 kJ ยท molโ1
- ^ ฮfGยฐ, -1081.39 kJ ยท molโ1
- ^ Sยฐ, -110.0 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -483.13 kJ ยท molโ1
- ^ ฮfGยฐ, -381.1 kJ ยท molโ1
- ^ Sยฐ, 90.0 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -485.85 kJ ยท molโ1
- ^ ฮfGยฐ, -404.5 kJ ยท molโ1
- ^ Sยฐ, 160.2 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, -18.0 J ยท Kโ1 ยท molโ1
- ^ ฮfGยฐ, -406.6 kJ ยท molโ1
- ^ ฮfHยฐ, -1374.4 kJ ยท molโ1
- ^ ฮfGยฐ, -1103.5 kJ ยท molโ1
- ^ Sยฐ, 223.4 J ยท Kโ1 ยท molโ1