H2 + Cs2O 🔥→ 2Cs + H2O
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- Reaction of and caesium oxide
The reaction of and caesium oxide yields and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of and caesium oxide
General equation
- Reaction of reducing species and hardly reducible species
- Reducing speciesReducing agent + Hardly reducible speciesOxidizing agent ⟶ ProductOxidation product + ProductReduction product
- Reducing agent + OxideOxidizing agent🔥⟶ Elementary substance/OxideReduction product + Oxidation product
Oxidation state of each atom
- Reaction of and caesium oxide
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| 1 | Reducing | Reducing Reducing nonmetal | ||
| Cs2O | Caesium oxide | 1 | Oxidizing | Hardly reducible Oxide |
Products
Thermodynamic changes
Changes in standard condition
- Reaction of and caesium oxide◆
ΔrG 71.01 kJ/mol K 0.36 × 10−12 pK 12.44
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 59.94 | 71.01 | −37.17 | 34.83 |
| 59.94 | 71.01 | −37.17 | 34.83 | |
per 1 mol of | 59.94 | 71.01 | −37.17 | 34.83 |
| 29.97 | 35.51 | −18.59 | 17.41 | |
per 1 mol of | 59.94 | 71.01 | −37.17 | 34.83 |
Changes in aqueous solution
- Reaction of and caesium oxide◆
ΔrG 53.4 kJ/mol K 0.44 × 10−9 pK 9.36
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 64.1 | 53.4 | −483 | – |
| 64.1 | 53.4 | −483 | – | |
per 1 mol of | 64.1 | 53.4 | −483 | – |
| 32.0 | 26.7 | −242 | – | |
per 1 mol of | 64.1 | 53.4 | −483 | – |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| (g) | 0[1] | 0[1] | 130.684[1] | 28.824[1] |
| (ao) | -4.2[1] | 17.6[1] | 577[1] | – |
| Cs2O (cr) | -345.77[1] | -308.14[1] | 146.86[1] | 75.98[1] |
* (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| (cr) | 0[1] | 0[1] | 85.23[1] | 32.17[1] |
| (g) | 76.065[1] | 49.121[1] | 175.595[1] | 20.786[1] |
| H2O (cr) | – | – | – | – |
| H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
| H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
* (cr):Crystalline solid, (g):Gas, (l):Liquid
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 130.684 J · K−1 · mol−1
- ^ Cp°, 28.824 J · K−1 · mol−1
- ^ ΔfH°, -4.2 kJ · mol−1
- ^ ΔfG°, 17.6 kJ · mol−1
- ^ S°, 577 J · K−1 · mol−1
- ^ ΔfH°, -345.77 kJ · mol−1
- ^ ΔfG°, -308.14 kJ · mol−1
- ^ S°, 146.86 J · K−1 · mol−1
- ^ Cp°, 75.98 J · K−1 · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 85.23 J · K−1 · mol−1
- ^ Cp°, 32.17 J · K−1 · mol−1
- ^ ΔfH°, 76.065 kJ · mol−1
- ^ ΔfG°, 49.121 kJ · mol−1
- ^ S°, 175.595 J · K−1 · mol−1
- ^ Cp°, 20.786 J · K−1 · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1