CH3COOLi + HCl → LiCl + CH3COOH
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The reaction of lithium acetate and hydrogen chloride yields lithium chloride and acetic acid. This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of lithium acetate and hydrogen chloride
General equation
- Salt of weak acidBrønsted base + Strong acidBrønsted acid ⟶ Salt of strong acidConjugate base + Weak acidConjugate acid
Oxidation state of each atom
- Reaction of lithium acetate and hydrogen chloride
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| CH3COOLi | Lithium acetate | 1 | Brønsted base | Salt of weak acid |
| HCl | Hydrogen chloride | 1 | Brønsted acid | Strong acid |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| LiCl | Lithium chloride | 1 | Conjugate base | Salt of strong acid |
| CH3COOH | Acetic acid | 1 | Conjugate acid | Weak acid |
Thermodynamic changes
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| CH3COOLi | – | – | – | – |
| HCl (g) | -92.307[1] | -95.299[1] | 186.908[1] | 29.12[1] |
| HCl (ai) | -167.159[1] | -131.228[1] | 56.5[1] | -136.4[1] |
* (g):Gas, (ai):Ionized aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| LiCl (cr) | -408.61[1] | -384.37[1] | 59.33[1] | 47.99[1] |
| LiCl (g) | -195.4[1] | -216.7[1] | 212.824[1] | 33.22[1] |
| LiCl (ai) | -445.64[1] | -424.58[1] | 69.9[1] | -67.8[1] |
| LiCl (cr) 1 hydrate | -712.58[1] | -631.80[1] | 102.84[1] | – |
| LiCl (cr) 2 hydrate | -1012.65[1] | – | – | – |
| LiCl (cr) 3 hydrate | -1311.3[1] | – | – | – |
| CH3COOH (l) | -484.5[1] | -389.9[1] | 159.8[1] | 124.3[1] |
| CH3COOH (g) | -432.25[1] | -374.0[1] | 282.5[1] | 66.5[1] |
| CH3COOH (ai) | -486.01[1] | -369.31[1] | 86.6[1] | -6.3[1] |
| CH3COOH (ao) | -485.76[1] | -396.46[1] | 178.7[1] | – |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (l):Liquid, (ao):Un-ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -92.307 kJ · mol−1
- ^ ΔfG°, -95.299 kJ · mol−1
- ^ S°, 186.908 J · K−1 · mol−1
- ^ Cp°, 29.12 J · K−1 · mol−1
- ^ ΔfH°, -167.159 kJ · mol−1
- ^ ΔfG°, -131.228 kJ · mol−1
- ^ S°, 56.5 J · K−1 · mol−1
- ^ Cp°, -136.4 J · K−1 · mol−1
- ^ ΔfH°, -408.61 kJ · mol−1
- ^ ΔfG°, -384.37 kJ · mol−1
- ^ S°, 59.33 J · K−1 · mol−1
- ^ Cp°, 47.99 J · K−1 · mol−1
- ^ ΔfH°, -195.4 kJ · mol−1
- ^ ΔfG°, -216.7 kJ · mol−1
- ^ S°, 212.824 J · K−1 · mol−1
- ^ Cp°, 33.22 J · K−1 · mol−1
- ^ ΔfH°, -445.64 kJ · mol−1
- ^ ΔfG°, -424.58 kJ · mol−1
- ^ S°, 69.9 J · K−1 · mol−1
- ^ Cp°, -67.8 J · K−1 · mol−1
- ^ ΔfH°, -712.58 kJ · mol−1
- ^ ΔfG°, -631.80 kJ · mol−1
- ^ S°, 102.84 J · K−1 · mol−1
- ^ ΔfH°, -1012.65 kJ · mol−1
- ^ ΔfH°, -1311.3 kJ · mol−1
- ^ ΔfH°, -484.5 kJ · mol−1
- ^ ΔfG°, -389.9 kJ · mol−1
- ^ S°, 159.8 J · K−1 · mol−1
- ^ Cp°, 124.3 J · K−1 · mol−1
- ^ ΔfH°, -432.25 kJ · mol−1
- ^ ΔfG°, -374.0 kJ · mol−1
- ^ S°, 282.5 J · K−1 · mol−1
- ^ Cp°, 66.5 J · K−1 · mol−1
- ^ ΔfH°, -486.01 kJ · mol−1
- ^ ΔfG°, -369.31 kJ · mol−1
- ^ S°, 86.6 J · K−1 · mol−1
- ^ Cp°, -6.3 J · K−1 · mol−1
- ^ ΔfH°, -485.76 kJ · mol−1
- ^ ΔfG°, -396.46 kJ · mol−1
- ^ S°, 178.7 J · K−1 · mol−1