LiBr + 7HNO3 🔥→ LiNO3 + HBrO3 + 3N2O4 + 3H2O
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- Reaction of lithium bromide and nitric acid
The reaction of lithium bromide and nitric acid yields lithium nitrate, bromic acid, dinitrogen tetraoxide, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of lithium bromide and nitric acid
General equation
- Reaction of hardly oxidizable species and oxidizing species
- Hardly oxidizable speciesReducing agent + Oxidizing speciesOxidizing agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of lithium bromide and nitric acid
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| LiBr | Lithium bromide | 1 | Reducing | Hardly oxidizable |
| HNO3 | Nitric acid | 7 | Oxidizing | Oxidizing |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| LiNO3 | Lithium nitrate | 1 | – | – |
| HBrO3 | Bromic acid | 1 | Oxidized | – |
| N2O4 | Dinitrogen tetraoxide | 3 | Reduced | – |
| H2O | Water | 3 | – | – |
Thermodynamic changes
Changes in standard condition (1)
- Reaction of lithium bromide and nitric acid◆
ΔrG 371.4 kJ/mol K 0.86 × 10−65 pK 65.07
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 382.65 | 371.4 | 38.6 | – |
per 1 mol of | 382.65 | 371.4 | 38.6 | – |
per 1 mol of | 54.664 | 53.06 | 5.51 | – |
per 1 mol of | 382.65 | 371.4 | 38.6 | – |
per 1 mol of | 382.65 | 371.4 | 38.6 | – |
per 1 mol of | 127.55 | 123.8 | 12.9 | – |
per 1 mol of | 127.55 | 123.8 | 12.9 | – |
Changes in standard condition (2)
- Reaction of lithium bromide and nitric acid◆
ΔrG 369.3 kJ/mol K 0.20 × 10−64 pK 64.70
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | – | 369.3 | – | – |
per 1 mol of | – | 369.3 | – | – |
per 1 mol of | – | 52.76 | – | – |
per 1 mol of | – | 369.3 | – | – |
per 1 mol of | – | 369.3 | – | – |
per 1 mol of | – | 123.1 | – | – |
per 1 mol of | – | 123.1 | – | – |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| LiBr (cr) | -351.213[1] | -342.00[1] | 74.27[1] | – |
| LiBr (g) | – | – | 224.33[1] | 33.93[1] |
| LiBr (ai) | -400.041[1] | -397.27[1] | 95.8[1] | -73.2[1] |
| LiBr (cr) 1 hydrate | -662.58[1] | -594.29[1] | 109.6[1] | – |
| LiBr (cr) 2 hydrate | -962.7[1] | -840.5[1] | 162.3[1] | – |
| HNO3 (l) | -174.10[1] | -80.71[1] | 155.60[1] | 109.87[1] |
| HNO3 (g) | -135.06[1] | -74.72[1] | 266.38[1] | 53.35[1] |
| HNO3 (ai) | -207.36[1] | -111.25[1] | 146.4[1] | -86.6[1] |
| HNO3 (l) 1 hydrate | -473.46[1] | -328.77[1] | 216.90[1] | 182.46[1] |
| HNO3 (l) 3 hydrate | -1056.04[1] | -811.09[1] | 346.98[1] | 325.14[1] |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (l):Liquid
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| LiNO3 (cr) | -483.13[1] | -381.1[1] | 90.0[1] | – |
| LiNO3 (ai) | -485.85[1] | -404.5[1] | 160.2[1] | -18.0[1] |
| LiNO3 (ao) | – | -406.6[1] | – | – |
| LiNO3 (cr) 3 hydrate | -1374.4[1] | -1103.5[1] | 223.4[1] | – |
| HBrO3 (ai) | -67.07[1] | 18.60[1] | 161.71[1] | – |
| N2O4 (l) | -19.50[1] | 97.54[1] | 209.2[1] | 142.7[1] |
| N2O4 (g) | 9.16[1] | 97.89[1] | 304.29[1] | 77.28[1] |
| H2O (cr) | – | – | – | – |
| H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
| H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution, (l):Liquid, (g):Gas
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -351.213 kJ · mol−1
- ^ ΔfG°, -342.00 kJ · mol−1
- ^ S°, 74.27 J · K−1 · mol−1
- ^ S°, 224.33 J · K−1 · mol−1
- ^ Cp°, 33.93 J · K−1 · mol−1
- ^ ΔfH°, -400.041 kJ · mol−1
- ^ ΔfG°, -397.27 kJ · mol−1
- ^ S°, 95.8 J · K−1 · mol−1
- ^ Cp°, -73.2 J · K−1 · mol−1
- ^ ΔfH°, -662.58 kJ · mol−1
- ^ ΔfG°, -594.29 kJ · mol−1
- ^ S°, 109.6 J · K−1 · mol−1
- ^ ΔfH°, -962.7 kJ · mol−1
- ^ ΔfG°, -840.5 kJ · mol−1
- ^ S°, 162.3 J · K−1 · mol−1
- ^ ΔfH°, -174.10 kJ · mol−1
- ^ ΔfG°, -80.71 kJ · mol−1
- ^ S°, 155.60 J · K−1 · mol−1
- ^ Cp°, 109.87 J · K−1 · mol−1
- ^ ΔfH°, -135.06 kJ · mol−1
- ^ ΔfG°, -74.72 kJ · mol−1
- ^ S°, 266.38 J · K−1 · mol−1
- ^ Cp°, 53.35 J · K−1 · mol−1
- ^ ΔfH°, -207.36 kJ · mol−1
- ^ ΔfG°, -111.25 kJ · mol−1
- ^ S°, 146.4 J · K−1 · mol−1
- ^ Cp°, -86.6 J · K−1 · mol−1
- ^ ΔfH°, -473.46 kJ · mol−1
- ^ ΔfG°, -328.77 kJ · mol−1
- ^ S°, 216.90 J · K−1 · mol−1
- ^ Cp°, 182.46 J · K−1 · mol−1
- ^ ΔfH°, -1056.04 kJ · mol−1
- ^ ΔfG°, -811.09 kJ · mol−1
- ^ S°, 346.98 J · K−1 · mol−1
- ^ Cp°, 325.14 J · K−1 · mol−1
- ^ ΔfH°, -483.13 kJ · mol−1
- ^ ΔfG°, -381.1 kJ · mol−1
- ^ S°, 90.0 J · K−1 · mol−1
- ^ ΔfH°, -485.85 kJ · mol−1
- ^ ΔfG°, -404.5 kJ · mol−1
- ^ S°, 160.2 J · K−1 · mol−1
- ^ Cp°, -18.0 J · K−1 · mol−1
- ^ ΔfG°, -406.6 kJ · mol−1
- ^ ΔfH°, -1374.4 kJ · mol−1
- ^ ΔfG°, -1103.5 kJ · mol−1
- ^ S°, 223.4 J · K−1 · mol−1
- ^ ΔfH°, -67.07 kJ · mol−1
- ^ ΔfG°, 18.60 kJ · mol−1
- ^ S°, 161.71 J · K−1 · mol−1
- ^ ΔfH°, -19.50 kJ · mol−1
- ^ ΔfG°, 97.54 kJ · mol−1
- ^ S°, 209.2 J · K−1 · mol−1
- ^ Cp°, 142.7 J · K−1 · mol−1
- ^ ΔfH°, 9.16 kJ · mol−1
- ^ ΔfG°, 97.89 kJ · mol−1
- ^ S°, 304.29 J · K−1 · mol−1
- ^ Cp°, 77.28 J · K−1 · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1