Li+ + CO32− + H+ → LiHCO3
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- Reaction of lithium ion and carbonate ion under acidic condition
The reaction of lithium ion, carbonate ion, and hydrogen ion yields lithium hydrogencarbonate. This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of lithium ion and carbonate ion under acidic condition
General equation
- Reaction of cation and anion under acidic condition
- CationLewis acid + AnionLewis base + H+Lewis acid ⟶ ProductLewis conjugate
Oxidation state of each atom
- Reaction of lithium ion and carbonate ion under acidic condition
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| Li+ | Lithium ion | 1 | Lewis acid | Cation |
| CO32− | Carbonate ion | 1 | Lewis base | Anion |
| H+ | Hydrogen ion | 1 | Lewis acid | Hydrogen ion |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| LiHCO3 | Lithium hydrogencarbonate | 1 | Lewis conjugate | – |
Thermodynamic changes
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| Li+ (g) | 685.783[1] | – | – | – |
| Li+ (ao) | -278.49[1] | -293.31[1] | 13.4[1] | 68.6[1] |
| CO32− (ao) | -677.14[1] | -527.81[1] | -56.9[1] | – |
| H+ (g) | 1536.202[1] | – | – | – |
| H+ (ao) | 0[1] | 0[1] | 0[1] | 0[1] |
* (g):Gas, (ao):Un-ionized aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| LiHCO3 | – | – | – | – |
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, 685.783 kJ · mol−1
- ^ ΔfH°, -278.49 kJ · mol−1
- ^ ΔfG°, -293.31 kJ · mol−1
- ^ S°, 13.4 J · K−1 · mol−1
- ^ Cp°, 68.6 J · K−1 · mol−1
- ^ ΔfH°, -677.14 kJ · mol−1
- ^ ΔfG°, -527.81 kJ · mol−1
- ^ S°, -56.9 J · K−1 · mol−1
- ^ ΔfH°, 1536.202 kJ · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 0 J · K−1 · mol−1
- ^ Cp°, 0 J · K−1 · mol−1