K+ + [Fe(CN)6]3− → K[Fe(CN)6]2−
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- Reaction of potassium ion and hexacyanidoferrate(III) ion
- K+Potassium ion + [Fe(CN)6]3−Hexacyanidoferrate(III) ionK[Fe(CN)6]2−Potassium hexacyanidoferrate(III) ion⟶
The reaction of potassium ion and hexacyanidoferrate(III) ion yields potassium hexacyanidoferrate(III) ion (Other reactions are here). This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of potassium ion and hexacyanidoferrate(III) ion
- K+Potassium ion + [Fe(CN)6]3−Hexacyanidoferrate(III) ionK[Fe(CN)6]2−Potassium hexacyanidoferrate(III) ion⟶
General equation
- Reaction of cation and anion
- CationLewis acid + AnionLewis base ⟶ ProductLewis conjugate + (H2O)
Oxidation state of each atom
- Reaction of potassium ion and hexacyanidoferrate(III) ion
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| K+ | Potassium ion | 1 | Lewis acid | Cation |
| [Fe(CN)6]3− | Hexacyanidoferrate(III) ion | 1 | Lewis base | Anion |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| K[Fe(CN)6]2− | Potassium hexacyanidoferrate(III) ion | 1 | Lewis conjugate | – |
Thermodynamic changes
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| K+ (g) | 514.26[1] | – | – | – |
| K+ (ao) | -252.38[1] | -283.27[1] | 102.5[1] | 21.8[1] |
| [Fe(CN)6]3− (ao) | 561.9[1] | 729.4[1] | 270.3[1] | – |
* (g):Gas, (ao):Un-ionized aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| K[Fe(CN)6]2− | – | – | – | – |
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)