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Na2S + 2KMnO4 → Na2MnO4 + S + K2MnO4

The reaction of sodium sulfide and potassium permanganate yields sodium manganate, sulfur, and potassium manganate (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Reaction of reducing species and oxidizing species
Reducing speciesReducing agent + Oxidizing speciesOxidizing agent
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
Na2SSodium sulfide1
Reducing
Reducing
KMnO4Potassium permanganate2
Oxidizing
Oxidizing

Products

Chemical formulaNameCoefficientTypeType in general
equation
Na2MnO4Sodium manganate1
Reduced
SSulfur1
Oxidized
K2MnO4Potassium manganate1
Reduced

Thermodynamic changes

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Na2S (cr)-364.8[1]-349.8[1]83.7[1]
Na2S (ai)-447.3[1]-438.1[1]103.3[1]
Na2S (cr)
4.5 hydrate
-1725.9[1]
Na2S (cr)
5 hydrate
-1886.6[1]
Na2S (cr)
9 hydrate
-3074.0[1]
KMnO4 (cr)-837.2[1]-737.6[1]171.71[1]117.57[1]
KMnO4 (ai)-793.8[1]-730.5[1]293.7[1]-60.2[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Na2MnO4 (cr)-1156.0[1]
Na2MnO4 (ai)-1134[1]-1024.6[1]176[1]
S (cr)
rhombic
0[1]0[1]31.80[1]22.64[1]
S (cr)
monoclinic
0.33[1]
S (g)278.805[1]238.250[1]167.821[1]23.673[1]
K2MnO4
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (g):Gas

References

List of references

  1. 1