Na2SO3 + HNO3 → Na2SO4 + HNO2
Last updated:
- Reaction of sodium sulfite and nitric acid
The reaction of sodium sulfite and nitric acid yields sodium sulfate and nitrous acid (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of sodium sulfite and nitric acid
General equation
- Reaction of reducing species and oxidizing species
- Reducing speciesReducing agent + Oxidizing speciesOxidizing agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of sodium sulfite and nitric acid
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| Na2SO3 | Sodium sulfite | 1 | Reducing | Reducing |
| HNO3 | Nitric acid | 1 | Oxidizing | Oxidizing |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| Na2SO4 | Sodium sulfate | 1 | Oxidized | – |
| HNO2 | Nitrous acid | 1 | Reduced | – |
Thermodynamic changes
Changes in standard condition
- Reaction of sodium sulfite and nitric acid◆
ΔrG −197.3 kJ/mol K 3.68 × 1034 pK −34.57
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −185.5 | −197.3 | 39.4 | – |
per 1 mol of | −185.5 | −197.3 | 39.4 | – |
per 1 mol of | −185.5 | −197.3 | 39.4 | – |
per 1 mol of | −185.5 | −197.3 | 39.4 | – |
per 1 mol of | −185.5 | −197.3 | 39.4 | – |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| Na2SO3 (cr) | -1100.8[1] | -1012.5[1] | 145.94[1] | 120.25[1] |
| Na2SO3 (ai) | -1115.87[1] | -1010.39[1] | 87.9[1] | – |
| Na2SO3 (cr) 7 hydrate | -3162.3[1] | -2676.1[1] | 444[1] | – |
| HNO3 (l) | -174.10[1] | -80.71[1] | 155.60[1] | 109.87[1] |
| HNO3 (g) | -135.06[1] | -74.72[1] | 266.38[1] | 53.35[1] |
| HNO3 (ai) | -207.36[1] | -111.25[1] | 146.4[1] | -86.6[1] |
| HNO3 (l) 1 hydrate | -473.46[1] | -328.77[1] | 216.90[1] | 182.46[1] |
| HNO3 (l) 3 hydrate | -1056.04[1] | -811.09[1] | 346.98[1] | 325.14[1] |
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (l):Liquid, (g):Gas
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| Na2SO4 (cr) orthorhombic | -1387.08[1] | -1270.16[1] | 149.58[1] | 128.20[1] |
| Na2SO4 (cr) metastable | – | – | 154.934[1] | 129.29[1] |
| Na2SO4 (ai) | -1389.51[1] | -1268.36[1] | 138.1[1] | -201[1] |
| Na2SO4 (cr) 10 hydrate | -4327.26[1] | -3646.85[1] | 592.0[1] | – |
| HNO2 (g) cis | -77.99[1] | -42.94[1] | 248.76[1] | 44.77[1] |
| HNO2 (g) trans | -80.12[1] | -45.24[1] | 249.22[1] | 46.07[1] |
| HNO2 (g) | -79.5[1] | -46.0[1] | 254.1[1] | 45.6[1] |
| HNO2 (ao) | -119.2[1] | -50.6[1] | 135.6[1] | – |
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (g):Gas, (ao):Un-ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -1100.8 kJ · mol−1
- ^ ΔfG°, -1012.5 kJ · mol−1
- ^ S°, 145.94 J · K−1 · mol−1
- ^ Cp°, 120.25 J · K−1 · mol−1
- ^ ΔfH°, -1115.87 kJ · mol−1
- ^ ΔfG°, -1010.39 kJ · mol−1
- ^ S°, 87.9 J · K−1 · mol−1
- ^ ΔfH°, -3162.3 kJ · mol−1
- ^ ΔfG°, -2676.1 kJ · mol−1
- ^ S°, 444. J · K−1 · mol−1
- ^ ΔfH°, -174.10 kJ · mol−1
- ^ ΔfG°, -80.71 kJ · mol−1
- ^ S°, 155.60 J · K−1 · mol−1
- ^ Cp°, 109.87 J · K−1 · mol−1
- ^ ΔfH°, -135.06 kJ · mol−1
- ^ ΔfG°, -74.72 kJ · mol−1
- ^ S°, 266.38 J · K−1 · mol−1
- ^ Cp°, 53.35 J · K−1 · mol−1
- ^ ΔfH°, -207.36 kJ · mol−1
- ^ ΔfG°, -111.25 kJ · mol−1
- ^ S°, 146.4 J · K−1 · mol−1
- ^ Cp°, -86.6 J · K−1 · mol−1
- ^ ΔfH°, -473.46 kJ · mol−1
- ^ ΔfG°, -328.77 kJ · mol−1
- ^ S°, 216.90 J · K−1 · mol−1
- ^ Cp°, 182.46 J · K−1 · mol−1
- ^ ΔfH°, -1056.04 kJ · mol−1
- ^ ΔfG°, -811.09 kJ · mol−1
- ^ S°, 346.98 J · K−1 · mol−1
- ^ Cp°, 325.14 J · K−1 · mol−1
- ^ ΔfH°, -1387.08 kJ · mol−1
- ^ ΔfG°, -1270.16 kJ · mol−1
- ^ S°, 149.58 J · K−1 · mol−1
- ^ Cp°, 128.20 J · K−1 · mol−1
- ^ S°, 154.934 J · K−1 · mol−1
- ^ Cp°, 129.29 J · K−1 · mol−1
- ^ ΔfH°, -1389.51 kJ · mol−1
- ^ ΔfG°, -1268.36 kJ · mol−1
- ^ S°, 138.1 J · K−1 · mol−1
- ^ Cp°, -201. J · K−1 · mol−1
- ^ ΔfH°, -4327.26 kJ · mol−1
- ^ ΔfG°, -3646.85 kJ · mol−1
- ^ S°, 592.0 J · K−1 · mol−1
- ^ ΔfH°, -77.99 kJ · mol−1
- ^ ΔfG°, -42.94 kJ · mol−1
- ^ S°, 248.76 J · K−1 · mol−1
- ^ Cp°, 44.77 J · K−1 · mol−1
- ^ ΔfH°, -80.12 kJ · mol−1
- ^ ΔfG°, -45.24 kJ · mol−1
- ^ S°, 249.22 J · K−1 · mol−1
- ^ Cp°, 46.07 J · K−1 · mol−1
- ^ ΔfH°, -79.5 kJ · mol−1
- ^ ΔfG°, -46.0 kJ · mol−1
- ^ S°, 254.1 J · K−1 · mol−1
- ^ Cp°, 45.6 J · K−1 · mol−1
- ^ ΔfH°, -119.2 kJ · mol−1
- ^ ΔfG°, -50.6 kJ · mol−1
- ^ S°, 135.6 J · K−1 · mol−1