SrCl2 + CdSO4 ๐งโ SrSO4โ + CdCl2
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- Reaction of strontium chloride and cadmium sulfate
The reaction of strontium chloride and cadmium sulfate yields strontium sulfate and cadmium chloride. This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of strontium chloride and cadmium sulfate
General equation
- Precipitation reaction
- Miscible with water/Very soluble in water/Soluble in waterLewis acid + Miscible with water/Very soluble in water/Soluble in waterLewis base๐งโถ Insoluble in water/Very slightly soluble in water/Slightly soluble in waterLewis conjugate + Product(Non-redox product)
Oxidation state of each atom
- Reaction of strontium chloride and cadmium sulfate
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
SrCl2 | Strontium chloride | 1 | Lewis acid | Very soluble in water |
CdSO4 | Cadmium sulfate | 1 | Lewis base | Very soluble in water |
Products
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
SrSO4 | Strontium sulfate | 1 | Lewis conjugate | Very slightly soluble in water |
CdCl2 | Cadmium chloride | 1 | Non-redox product | โ |
Thermodynamic changes
Changes in standard condition (1)
- Reaction of strontium chloride and cadmium sulfateโ
ฮrG โ81.0 kJ/mol K 1.55 ร 1014 pK โ14.19
Standard enthalpy of reaction ฮrHยฐ kJ ยท molโ1 | Standard Gibbs energy of reaction ฮrGยฐ kJ ยท molโ1 | Standard entropy of reaction ฮrSยฐ J ยท Kโ1 ยท molโ1 | Standard heat capacity of reaction at constant pressure ฮrCpยฐ J ยท Kโ1 ยท molโ1 | |
---|---|---|---|---|
per 1 mol of Equation | โ82.4 | โ81.0 | โ6 | โ |
per 1 mol of | โ82.4 | โ81.0 | โ6 | โ |
per 1 mol of | โ82.4 | โ81.0 | โ6 | โ |
per 1 mol of | โ82.4 | โ81.0 | โ6 | โ |
per 1 mol of | โ82.4 | โ81.0 | โ6 | โ |
Changes in standard condition (2)
- Reaction of strontium chloride and cadmium sulfate
Standard enthalpy of reaction ฮrHยฐ kJ ยท molโ1 | Standard Gibbs energy of reaction ฮrGยฐ kJ ยท molโ1 | Standard entropy of reaction ฮrSยฐ J ยท Kโ1 ยท molโ1 | Standard heat capacity of reaction at constant pressure ฮrCpยฐ J ยท Kโ1 ยท molโ1 | |
---|---|---|---|---|
per 1 mol of Equation | โ79.1 | โ | โ | โ |
per 1 mol of | โ79.1 | โ | โ | โ |
per 1 mol of | โ79.1 | โ | โ | โ |
per 1 mol of | โ79.1 | โ | โ | โ |
per 1 mol of | โ79.1 | โ | โ | โ |
Changes in aqueous solution (1)
- Reaction of strontium chloride and cadmium sulfateโ
ฮrG โ36.3 kJ/mol K 2.29 ร 106 pK โ6.36
Standard enthalpy of reaction ฮrHยฐ kJ ยท molโ1 | Standard Gibbs energy of reaction ฮrGยฐ kJ ยท molโ1 | Standard entropy of reaction ฮrSยฐ J ยท Kโ1 ยท molโ1 | Standard heat capacity of reaction at constant pressure ฮrCpยฐ J ยท Kโ1 ยท molโ1 | |
---|---|---|---|---|
per 1 mol of Equation | โ49.9 | โ36.3 | โ47 | โ |
per 1 mol of | โ49.9 | โ36.3 | โ47 | โ |
per 1 mol of | โ49.9 | โ36.3 | โ47 | โ |
per 1 mol of | โ49.9 | โ36.3 | โ47 | โ |
per 1 mol of | โ49.9 | โ36.3 | โ47 | โ |
Changes in aqueous solution (2)
- Reaction of strontium chloride and cadmium sulfateโ
ฮrG โ55.6 kJ/mol K 5.50 ร 109 pK โ9.74
Standard enthalpy of reaction ฮrHยฐ kJ ยท molโ1 | Standard Gibbs energy of reaction ฮrGยฐ kJ ยท molโ1 | Standard entropy of reaction ฮrSยฐ J ยท Kโ1 ยท molโ1 | Standard heat capacity of reaction at constant pressure ฮrCpยฐ J ยท Kโ1 ยท molโ1 | |
---|---|---|---|---|
per 1 mol of Equation | โ44.7 | โ55.6 | 35 | โ |
per 1 mol of | โ44.7 | โ55.6 | 35 | โ |
per 1 mol of | โ44.7 | โ55.6 | 35 | โ |
per 1 mol of | โ44.7 | โ55.6 | 35 | โ |
per 1 mol of | โ44.7 | โ55.6 | 35 | โ |
Changes in aqueous solution (3)
- Reaction of strontium chloride and cadmium sulfate
Standard enthalpy of reaction ฮrHยฐ kJ ยท molโ1 | Standard Gibbs energy of reaction ฮrGยฐ kJ ยท molโ1 | Standard entropy of reaction ฮrSยฐ J ยท Kโ1 ยท molโ1 | Standard heat capacity of reaction at constant pressure ฮrCpยฐ J ยท Kโ1 ยท molโ1 | |
---|---|---|---|---|
per 1 mol of Equation | โ46.6 | โ | โ | โ |
per 1 mol of | โ46.6 | โ | โ | โ |
per 1 mol of | โ46.6 | โ | โ | โ |
per 1 mol of | โ46.6 | โ | โ | โ |
per 1 mol of | โ46.6 | โ | โ | โ |
Changes in aqueous solution (4)
- Reaction of strontium chloride and cadmium sulfate
Standard enthalpy of reaction ฮrHยฐ kJ ยท molโ1 | Standard Gibbs energy of reaction ฮrGยฐ kJ ยท molโ1 | Standard entropy of reaction ฮrSยฐ J ยท Kโ1 ยท molโ1 | Standard heat capacity of reaction at constant pressure ฮrCpยฐ J ยท Kโ1 ยท molโ1 | |
---|---|---|---|---|
per 1 mol of Equation | โ41.4 | โ | โ | โ |
per 1 mol of | โ41.4 | โ | โ | โ |
per 1 mol of | โ41.4 | โ | โ | โ |
per 1 mol of | โ41.4 | โ | โ | โ |
per 1 mol of | โ41.4 | โ | โ | โ |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ฮfHยฐ kJ ยท molโ1 | Standard Gibbs energy of formation ฮfGยฐ kJ ยท molโ1 | Standard molar entropy Sยฐ J ยท Kโ1 ยท molโ1 | Standard molar heat capacity at constant pressure Cpยฐ J ยท Kโ1 ยท molโ1 |
---|---|---|---|---|
SrCl2 (cr) ฮฑ | -828.9[1] | -781.1[1] | 114.85[1] | 75.60[1] |
SrCl2 (g) | -485.8[1] | -496.2[1] | 310.81[1] | 55.77[1] |
SrCl2 (ai) | -880.10[1] | -821.91[1] | 80.3[1] | โ |
SrCl2 (cr) 1 hydrate | -1136.8[1] | -1036.3[1] | 172[1] | 120.1[1] |
SrCl2 (cr) 2 hydrate | -1438.0[1] | -1281.8[1] | 218[1] | 160.2[1] |
SrCl2 (cr) 6 hydrate | -2623.8[1] | -2240.92[1] | 390.8[1] | โ |
CdSO4 (cr) | -933.28[1] | -822.72[1] | 123.039[1] | 99.58[1] |
CdSO4 (ai) | -985.16[1] | -822.13[1] | -53.1[1] | โ |
CdSO4 (cr) 1 hydrate | -1239.55[1] | -1068.73[1] | 154.030[1] | 134.56[1] |
CdSO4 (cr) 8/3 hydrate | -1729.4[1] | -1465.141[1] | 229.630[1] | 213.26[1] |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ฮfHยฐ kJ ยท molโ1 | Standard Gibbs energy of formation ฮfGยฐ kJ ยท molโ1 | Standard molar entropy Sยฐ J ยท Kโ1 ยท molโ1 | Standard molar heat capacity at constant pressure Cpยฐ J ยท Kโ1 ยท molโ1 |
---|---|---|---|---|
SrSO4 (cr) | -1453.1[1] | -1340.9[1] | 117[1] | โ |
SrSO4 (cr) precipitated | -1449.8[1] | โ | โ | โ |
SrSO4 (ai) | -1455.07[1] | -1304.00[1] | -12.6[1] | โ |
CdCl2 (cr) | -391.50[1] | -343.93[1] | 115.27[1] | 74.68[1] |
CdCl2 (ai) | -410.20[1] | -340.068[1] | 39.7[1] | โ |
CdCl2 (ao) | -405.0[1] | -359.29[1] | 121.8[1] | โ |
CdCl2 (cr) 1 hydrate | -688.44[1] | -586.975[1] | 167.8[1] | โ |
CdCl2 (cr) 2.5 hydrate | -1131.94[1] | -943.939[1] | 227.2[1] | โ |
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ฮfHยฐ, -828.9 kJ ยท molโ1
- ^ ฮfGยฐ, -781.1 kJ ยท molโ1
- ^ Sยฐ, 114.85 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 75.60 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -485.8 kJ ยท molโ1
- ^ ฮfGยฐ, -496.2 kJ ยท molโ1
- ^ Sยฐ, 310.81 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 55.77 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -880.10 kJ ยท molโ1
- ^ ฮfGยฐ, -821.91 kJ ยท molโ1
- ^ Sยฐ, 80.3 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1136.8 kJ ยท molโ1
- ^ ฮfGยฐ, -1036.3 kJ ยท molโ1
- ^ Sยฐ, 172. J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 120.1 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1438.0 kJ ยท molโ1
- ^ ฮfGยฐ, -1281.8 kJ ยท molโ1
- ^ Sยฐ, 218. J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 160.2 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -2623.8 kJ ยท molโ1
- ^ ฮfGยฐ, -2240.92 kJ ยท molโ1
- ^ Sยฐ, 390.8 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -933.28 kJ ยท molโ1
- ^ ฮfGยฐ, -822.72 kJ ยท molโ1
- ^ Sยฐ, 123.039 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 99.58 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -985.16 kJ ยท molโ1
- ^ ฮfGยฐ, -822.13 kJ ยท molโ1
- ^ Sยฐ, -53.1 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1239.55 kJ ยท molโ1
- ^ ฮfGยฐ, -1068.73 kJ ยท molโ1
- ^ Sยฐ, 154.030 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 134.56 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1729.4 kJ ยท molโ1
- ^ ฮfGยฐ, -1465.141 kJ ยท molโ1
- ^ Sยฐ, 229.630 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 213.26 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1453.1 kJ ยท molโ1
- ^ ฮfGยฐ, -1340.9 kJ ยท molโ1
- ^ Sยฐ, 117. J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1449.8 kJ ยท molโ1
- ^ ฮfHยฐ, -1455.07 kJ ยท molโ1
- ^ ฮfGยฐ, -1304.00 kJ ยท molโ1
- ^ Sยฐ, -12.6 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -391.50 kJ ยท molโ1
- ^ ฮfGยฐ, -343.93 kJ ยท molโ1
- ^ Sยฐ, 115.27 J ยท Kโ1 ยท molโ1
- ^ Cpยฐ, 74.68 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -410.20 kJ ยท molโ1
- ^ ฮfGยฐ, -340.068 kJ ยท molโ1
- ^ Sยฐ, 39.7 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -405.0 kJ ยท molโ1
- ^ ฮfGยฐ, -359.29 kJ ยท molโ1
- ^ Sยฐ, 121.8 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -688.44 kJ ยท molโ1
- ^ ฮfGยฐ, -586.975 kJ ยท molโ1
- ^ Sยฐ, 167.8 J ยท Kโ1 ยท molโ1
- ^ ฮfHยฐ, -1131.94 kJ ยท molโ1
- ^ ฮfGยฐ, -943.939 kJ ยท molโ1
- ^ Sยฐ, 227.2 J ยท Kโ1 ยท molโ1