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SrCl2 + CdSO4 ๐Ÿ’งโ†’ SrSO4โ†“ + CdCl2

The reaction of strontium chloride and cadmium sulfate yields strontium sulfate and cadmium chloride. This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
SrCl2Strontium chloride1
Lewis acid
Very soluble in water
CdSO4Cadmium sulfate1
Lewis base
Very soluble in water

Products

Chemical formulaNameCoefficientTypeType in general
equation
SrSO4Strontium sulfate1
Lewis conjugate
Very slightly soluble in water
CdCl2Cadmium chloride1
Non-redox product
โ€“

Thermodynamic changes

Changes in standard condition (1)

Reaction of strontium chloride and cadmium sulfate
โ—†
ฮ”rGโˆ’81.0 kJ/mol
K1.55 ร— 1014
pKโˆ’14.19
SrCl2Crystalline solidฮฑ + CdSO4Crystalline solid
๐Ÿ’ง
โŸถ
SrSO4โ†“Crystalline solid + CdCl2Crystalline solid
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
โˆ’82.4โˆ’81.0โˆ’6โ€“
per 1 mol of
โˆ’82.4โˆ’81.0โˆ’6โ€“
per 1 mol of
โˆ’82.4โˆ’81.0โˆ’6โ€“
per 1 mol of
โˆ’82.4โˆ’81.0โˆ’6โ€“
per 1 mol of
โˆ’82.4โˆ’81.0โˆ’6โ€“

Changes in standard condition (2)

Reaction of strontium chloride and cadmium sulfate
SrCl2Crystalline solidฮฑ + CdSO4Crystalline solid
๐Ÿ’ง
โŸถ
SrSO4โ†“Crystalline solidprecipitated + CdCl2Crystalline solid
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
โˆ’79.1โ€“โ€“โ€“
per 1 mol of
โˆ’79.1โ€“โ€“โ€“
per 1 mol of
โˆ’79.1โ€“โ€“โ€“
per 1 mol of
โˆ’79.1โ€“โ€“โ€“
per 1 mol of
โˆ’79.1โ€“โ€“โ€“

Changes in aqueous solution (1)

Reaction of strontium chloride and cadmium sulfate
โ—†
ฮ”rGโˆ’36.3 kJ/mol
K2.29 ร— 106
pKโˆ’6.36
SrCl2Ionized aqueous solution + CdSO4Crystalline solid
๐Ÿ’ง
โŸถ
SrSO4โ†“Crystalline solid + CdCl2Ionized aqueous solution
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
โˆ’49.9โˆ’36.3โˆ’47โ€“
per 1 mol of
โˆ’49.9โˆ’36.3โˆ’47โ€“
per 1 mol of
โˆ’49.9โˆ’36.3โˆ’47โ€“
per 1 mol of
โˆ’49.9โˆ’36.3โˆ’47โ€“
per 1 mol of
โˆ’49.9โˆ’36.3โˆ’47โ€“

Changes in aqueous solution (2)

Reaction of strontium chloride and cadmium sulfate
โ—†
ฮ”rGโˆ’55.6 kJ/mol
K5.50 ร— 109
pKโˆ’9.74
SrCl2Ionized aqueous solution + CdSO4Crystalline solid
๐Ÿ’ง
โŸถ
SrSO4โ†“Crystalline solid + CdCl2Un-ionized aqueous solution
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
โˆ’44.7โˆ’55.635โ€“
per 1 mol of
โˆ’44.7โˆ’55.635โ€“
per 1 mol of
โˆ’44.7โˆ’55.635โ€“
per 1 mol of
โˆ’44.7โˆ’55.635โ€“
per 1 mol of
โˆ’44.7โˆ’55.635โ€“

Changes in aqueous solution (3)

Reaction of strontium chloride and cadmium sulfate
SrCl2Ionized aqueous solution + CdSO4Crystalline solid
๐Ÿ’ง
โŸถ
SrSO4โ†“Crystalline solidprecipitated + CdCl2Ionized aqueous solution
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
โˆ’46.6โ€“โ€“โ€“
per 1 mol of
โˆ’46.6โ€“โ€“โ€“
per 1 mol of
โˆ’46.6โ€“โ€“โ€“
per 1 mol of
โˆ’46.6โ€“โ€“โ€“
per 1 mol of
โˆ’46.6โ€“โ€“โ€“

Changes in aqueous solution (4)

Reaction of strontium chloride and cadmium sulfate
SrCl2Ionized aqueous solution + CdSO4Crystalline solid
๐Ÿ’ง
โŸถ
SrSO4โ†“Crystalline solidprecipitated + CdCl2Un-ionized aqueous solution
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
โˆ’41.4โ€“โ€“โ€“
per 1 mol of
โˆ’41.4โ€“โ€“โ€“
per 1 mol of
โˆ’41.4โ€“โ€“โ€“
per 1 mol of
โˆ’41.4โ€“โ€“โ€“
per 1 mol of
โˆ’41.4โ€“โ€“โ€“

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ฮ”fHยฐ
kJ ยท molโˆ’1
Standard Gibbs
energy of
formation
ฮ”fGยฐ
kJ ยท molโˆ’1
Standard
molar entropy
Sยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard molar
heat capacity at
constant pressure
Cpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
SrCl2 (cr)
ฮฑ
-828.9[1]-781.1[1]114.85[1]75.60[1]
SrCl2 (g)-485.8[1]-496.2[1]310.81[1]55.77[1]
SrCl2 (ai)-880.10[1]-821.91[1]80.3[1]โ€“
SrCl2 (cr)
1 hydrate
-1136.8[1]-1036.3[1]172[1]120.1[1]
SrCl2 (cr)
2 hydrate
-1438.0[1]-1281.8[1]218[1]160.2[1]
SrCl2 (cr)
6 hydrate
-2623.8[1]-2240.92[1]390.8[1]โ€“
CdSO4 (cr)-933.28[1]-822.72[1]123.039[1]99.58[1]
CdSO4 (ai)-985.16[1]-822.13[1]-53.1[1]โ€“
CdSO4 (cr)
1 hydrate
-1239.55[1]-1068.73[1]154.030[1]134.56[1]
CdSO4 (cr)
8/3 hydrate
-1729.4[1]-1465.141[1]229.630[1]213.26[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ฮ”fHยฐ
kJ ยท molโˆ’1
Standard Gibbs
energy of
formation
ฮ”fGยฐ
kJ ยท molโˆ’1
Standard
molar entropy
Sยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard molar
heat capacity at
constant pressure
Cpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
SrSO4 (cr)-1453.1[1]-1340.9[1]117[1]โ€“
SrSO4 (cr)
precipitated
-1449.8[1]โ€“โ€“โ€“
SrSO4 (ai)-1455.07[1]-1304.00[1]-12.6[1]โ€“
CdCl2 (cr)-391.50[1]-343.93[1]115.27[1]74.68[1]
CdCl2 (ai)-410.20[1]-340.068[1]39.7[1]โ€“
CdCl2 (ao)-405.0[1]-359.29[1]121.8[1]โ€“
CdCl2 (cr)
1 hydrate
-688.44[1]-586.975[1]167.8[1]โ€“
CdCl2 (cr)
2.5 hydrate
-1131.94[1]-943.939[1]227.2[1]โ€“
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)