Sr(NO3)2 + K2S 💧→ SrS↓ + 2KNO3
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The reaction of strontium nitrate and potassium sulfide yields strontium sulfide and potassium nitrate. This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of strontium nitrate and potassium sulfide
General equation
- Precipitation reaction
- Miscible with water/Very soluble in water/Soluble in waterLewis acid + Miscible with water/Very soluble in water/Soluble in waterLewis base💧⟶ Insoluble in water/Very slightly soluble in water/Slightly soluble in waterLewis conjugate + Product(Non-redox product)
Oxidation state of each atom
- Reaction of strontium nitrate and potassium sulfide
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
Sr(NO3)2 | Strontium nitrate | 1 | Lewis acid | Very soluble in water |
K2S | Potassium sulfide | 1 | Lewis base | Soluble in water |
Products
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
SrS | Strontium sulfide | 1 | Lewis conjugate | Slightly soluble in water |
KNO3 | Potassium nitrate | 2 | Non-redox product | – |
Thermodynamic changes
Changes in standard condition
- Reaction of strontium nitrate and potassium sulfide◆
ΔrG −113.5 kJ/mol K 7.66 × 1019 pK −19.88
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −102.7 | −113.5 | 35 | – |
per 1 mol of | −102.7 | −113.5 | 35 | – |
per 1 mol of | −102.7 | −113.5 | 35 | – |
per 1 mol of | −102.7 | −113.5 | 35 | – |
per 1 mol of | −51.35 | −56.75 | 18 | – |
Changes in aqueous solution
- Reaction of strontium nitrate and potassium sulfide◆
ΔrG 5.8 kJ/mol K 0.96 × 10−1 pK 1.02
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | 40.1 | 5.8 | 115.4 | – |
per 1 mol of | 40.1 | 5.8 | 115.4 | – |
per 1 mol of | 40.1 | 5.8 | 115.4 | – |
per 1 mol of | 40.1 | 5.8 | 115.4 | – |
per 1 mol of | 20.1 | 2.9 | 57.70 | – |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
Sr(NO3)2 (cr) | -978.22[1] | -780.02[1] | 194.56[1] | 149.91[1] |
Sr(NO3)2 (ai) | -960.52[1] | -781.98[1] | 260.2[1] | – |
Sr(NO3)2 (cr) 4 hydrate | -2154.8[1] | -1730.39[1] | 369.0[1] | – |
K2S (cr) | -380.7[1] | -364.0[1] | 105[1] | – |
K2S (ai) | -471.5[1] | -480.7[1] | 190.4[1] | – |
K2S (cr) 2 hydrate | -975.3[1] | – | – | – |
K2S (cr) 5 hydrate | -1871.5[1] | – | – | – |
* (cr):Crystalline solid, (ai):Ionized aqueous solution
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
SrS (cr) | -472.4[1] | -467.8[1] | 68.2[1] | 48.70[1] |
SrS (g) | 109[1] | – | – | – |
KNO3 (cr) | -494.63[1] | -394.86[1] | 133.05[1] | 96.40[1] |
KNO3 (ai) | -459.74[1] | -394.53[1] | 248.9[1] | -64.9[1] |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -978.22 kJ · mol−1
- ^ ΔfG°, -780.02 kJ · mol−1
- ^ S°, 194.56 J · K−1 · mol−1
- ^ Cp°, 149.91 J · K−1 · mol−1
- ^ ΔfH°, -960.52 kJ · mol−1
- ^ ΔfG°, -781.98 kJ · mol−1
- ^ S°, 260.2 J · K−1 · mol−1
- ^ ΔfH°, -2154.8 kJ · mol−1
- ^ ΔfG°, -1730.39 kJ · mol−1
- ^ S°, 369.0 J · K−1 · mol−1
- ^ ΔfH°, -380.7 kJ · mol−1
- ^ ΔfG°, -364.0 kJ · mol−1
- ^ S°, 105. J · K−1 · mol−1
- ^ ΔfH°, -471.5 kJ · mol−1
- ^ ΔfG°, -480.7 kJ · mol−1
- ^ S°, 190.4 J · K−1 · mol−1
- ^ ΔfH°, -975.3 kJ · mol−1
- ^ ΔfH°, -1871.5 kJ · mol−1
- ^ ΔfH°, -472.4 kJ · mol−1
- ^ ΔfG°, -467.8 kJ · mol−1
- ^ S°, 68.2 J · K−1 · mol−1
- ^ Cp°, 48.70 J · K−1 · mol−1
- ^ ΔfH°, 109. kJ · mol−1
- ^ ΔfH°, -494.63 kJ · mol−1
- ^ ΔfG°, -394.86 kJ · mol−1
- ^ S°, 133.05 J · K−1 · mol−1
- ^ Cp°, 96.40 J · K−1 · mol−1
- ^ ΔfH°, -459.74 kJ · mol−1
- ^ ΔfG°, -394.53 kJ · mol−1
- ^ S°, 248.9 J · K−1 · mol−1
- ^ Cp°, -64.9 J · K−1 · mol−1