SnS + 2HCl → SnCl2 + H2S
Last updated:
The reaction of tin(II) sulfide and hydrogen chloride yields tin(II) chloride and hydrogen sulfide. This reaction is an acid-base reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of tin(II) sulfide and hydrogen chloride
General equation
- Salt of weak acidBrønsted base + Strong acidBrønsted acid ⟶ Salt of strong acidConjugate base + Weak acidConjugate acid
Oxidation state of each atom
- Reaction of tin(II) sulfide and hydrogen chloride
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| SnS | Tin(II) sulfide | 1 | Brønsted base | Salt of weak acid |
| HCl | Hydrogen chloride | 2 | Brønsted acid | Strong acid |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| SnCl2 | Tin(II) chloride | 1 | Conjugate base | Salt of strong acid |
| H2S | Hydrogen sulfide | 1 | Conjugate acid | Weak acid |
Thermodynamic changes
Changes in standard condition
- Reaction of tin(II) sulfide and hydrogen chloride
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −61 | – | – | – |
per 1 mol of | −61 | – | – | – |
per 1 mol of | −31 | – | – | – |
per 1 mol of | −61 | – | – | – |
per 1 mol of | −61 | – | – | – |
Changes in aqueous solution (1)
- Reaction of tin(II) sulfide and hydrogen chloride
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 89 | – | – | – |
per 1 mol of | 89 | – | – | – |
per 1 mol of | 45 | – | – | – |
per 1 mol of | 89 | – | – | – |
per 1 mol of | 89 | – | – | – |
Changes in aqueous solution (2)
- Reaction of tin(II) sulfide and hydrogen chloride
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 70 | – | – | – |
per 1 mol of | 70 | – | – | – |
per 1 mol of | 35 | – | – | – |
per 1 mol of | 70 | – | – | – |
per 1 mol of | 70 | – | – | – |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| SnS (cr) | -100[1] | -98.3[1] | 77.0[1] | 49.25[1] |
| SnS (g) | 119.2[1] | – | – | – |
| HCl (g) | -92.307[1] | -95.299[1] | 186.908[1] | 29.12[1] |
| HCl (ai) | -167.159[1] | -131.228[1] | 56.5[1] | -136.4[1] |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| SnCl2 (cr) | -325.1[1] | – | – | – |
| SnCl2 (cr) 2 hydrate | -921.3[1] | – | – | – |
| H2S (g) | -20.63[1] | -33.56[1] | 205.79[1] | 34.23[1] |
| H2S (ao) | -39.7[1] | -27.83[1] | 121[1] | – |
* (cr):Crystalline solid, (g):Gas, (ao):Un-ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -100. kJ · mol−1
- ^ ΔfG°, -98.3 kJ · mol−1
- ^ S°, 77.0 J · K−1 · mol−1
- ^ Cp°, 49.25 J · K−1 · mol−1
- ^ ΔfH°, 119.2 kJ · mol−1
- ^ ΔfH°, -92.307 kJ · mol−1
- ^ ΔfG°, -95.299 kJ · mol−1
- ^ S°, 186.908 J · K−1 · mol−1
- ^ Cp°, 29.12 J · K−1 · mol−1
- ^ ΔfH°, -167.159 kJ · mol−1
- ^ ΔfG°, -131.228 kJ · mol−1
- ^ S°, 56.5 J · K−1 · mol−1
- ^ Cp°, -136.4 J · K−1 · mol−1
- ^ ΔfH°, -325.1 kJ · mol−1
- ^ ΔfH°, -921.3 kJ · mol−1
- ^ ΔfH°, -20.63 kJ · mol−1
- ^ ΔfG°, -33.56 kJ · mol−1
- ^ S°, 205.79 J · K−1 · mol−1
- ^ Cp°, 34.23 J · K−1 · mol−1
- ^ ΔfH°, -39.7 kJ · mol−1
- ^ ΔfG°, -27.83 kJ · mol−1
- ^ S°, 121. J · K−1 · mol−1