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ZnI2 + Mg(OH)2 → MgI2 + Zn(OH)2

The reaction of zinc iodide and magnesium hydroxide yields magnesium iodide and zinc hydroxide. This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
ZnI2Zinc iodide1
Brønsted acid
Salt of weak base
Mg(OH)2Magnesium hydroxide1
Brønsted base
Strong base

Products

Chemical formulaNameCoefficientTypeType in general
equation
MgI2Magnesium iodide1
Conjugate acid
Salt of strong base
Zn(OH)2Zinc hydroxide1
Conjugate base
Weak base

Thermodynamic changes

Changes in standard condition (1)

Reaction of zinc iodide and magnesium hydroxide
ΔrG130.5 kJ/mol
K0.14 × 10−22
pK22.86
ZnI2Crystalline solid + Mg(OH)2Crystalline solid
MgI2Crystalline solid + Zn(OH)2Crystalline solidγ
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
130.5
per 1 mol of
130.5
130.5
per 1 mol of
130.5
per 1 mol of
130.5

Changes in standard condition (2)

Reaction of zinc iodide and magnesium hydroxide
ΔrG130.7 kJ/mol
K0.13 × 10−22
pK22.90
ZnI2Crystalline solid + Mg(OH)2Crystalline solid
MgI2Crystalline solid + Zn(OH)2Crystalline solidβ
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
126.7130.7−13.4
per 1 mol of
126.7130.7−13.4
126.7130.7−13.4
per 1 mol of
126.7130.7−13.4
per 1 mol of
126.7130.7−13.4

Changes in standard condition (3)

Reaction of zinc iodide and magnesium hydroxide
ΔrG129.2 kJ/mol
K0.23 × 10−22
pK22.63
ZnI2Crystalline solid + Mg(OH)2Crystalline solid
MgI2Crystalline solid + Zn(OH)2Crystalline solidε
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
125.3129.2−13.0
per 1 mol of
125.3129.2−13.0
125.3129.2−13.0
per 1 mol of
125.3129.2−13.0
per 1 mol of
125.3129.2−13.0

Changes in standard condition (4)

Reaction of zinc iodide and magnesium hydroxide
ZnI2Crystalline solid + Mg(OH)2Crystalline solid
MgI2Crystalline solid + Zn(OH)2Crystalline solidprecipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
126.4
per 1 mol of
126.4
126.4
per 1 mol of
126.4
per 1 mol of
126.4

Changes in standard condition (5)

Reaction of zinc iodide and magnesium hydroxide
ZnI2Crystalline solid + Mg(OH)2Amorphous solidprecipitated
MgI2Crystalline solid + Zn(OH)2Crystalline solidγ
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of
per 1 mol of

Changes in standard condition (6)

Reaction of zinc iodide and magnesium hydroxide
ZnI2Crystalline solid + Mg(OH)2Amorphous solidprecipitated
MgI2Crystalline solid + Zn(OH)2Crystalline solidβ
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
122.6
per 1 mol of
122.6
122.6
per 1 mol of
122.6
per 1 mol of
122.6

Changes in standard condition (7)

Reaction of zinc iodide and magnesium hydroxide
ZnI2Crystalline solid + Mg(OH)2Amorphous solidprecipitated
MgI2Crystalline solid + Zn(OH)2Crystalline solidε
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
121.3
per 1 mol of
121.3
121.3
per 1 mol of
121.3
per 1 mol of
121.3

Changes in standard condition (8)

Reaction of zinc iodide and magnesium hydroxide
ZnI2Crystalline solid + Mg(OH)2Amorphous solidprecipitated
MgI2Crystalline solid + Zn(OH)2Crystalline solidprecipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
122.3
per 1 mol of
122.3
122.3
per 1 mol of
122.3
per 1 mol of
122.3

Changes in aqueous solution (1)

Reaction of zinc iodide and magnesium hydroxide
ΔrG2.9 kJ/mol
K0.31 × 100
pK0.51
ZnI2Ionized aqueous solution + Mg(OH)2Crystalline solid
MgI2Ionized aqueous solution + Zn(OH)2Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
2.9
per 1 mol of
2.9
2.9
per 1 mol of
2.9
per 1 mol of
2.9

Changes in aqueous solution (2)

Reaction of zinc iodide and magnesium hydroxide
ΔrG−28.2 kJ/mol
K8.72 × 104
pK−4.94
ZnI2Ionized aqueous solution + Mg(OH)2Crystalline solid
MgI2Ionized aqueous solution + Zn(OH)2Crystalline solidγ
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−28.2
per 1 mol of
−28.2
−28.2
per 1 mol of
−28.2
per 1 mol of
−28.2

Changes in aqueous solution (3)

Reaction of zinc iodide and magnesium hydroxide
ΔrG−27.9 kJ/mol
K7.72 × 104
pK−4.89
ZnI2Ionized aqueous solution + Mg(OH)2Crystalline solid
MgI2Ionized aqueous solution + Zn(OH)2Crystalline solidβ
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−30.33−27.9−8.0
per 1 mol of
−30.33−27.9−8.0
−30.33−27.9−8.0
per 1 mol of
−30.33−27.9−8.0
per 1 mol of
−30.33−27.9−8.0

Changes in aqueous solution (4)

Reaction of zinc iodide and magnesium hydroxide
ΔrG−29.5 kJ/mol
K1.47 × 105
pK−5.17
ZnI2Ionized aqueous solution + Mg(OH)2Crystalline solid
MgI2Ionized aqueous solution + Zn(OH)2Crystalline solidε
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−31.67−29.5−7.6
per 1 mol of
−31.67−29.5−7.6
−31.67−29.5−7.6
per 1 mol of
−31.67−29.5−7.6
per 1 mol of
−31.67−29.5−7.6

Changes in aqueous solution (5)

Reaction of zinc iodide and magnesium hydroxide
ZnI2Ionized aqueous solution + Mg(OH)2Crystalline solid
MgI2Ionized aqueous solution + Zn(OH)2Crystalline solidprecipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−30.6
per 1 mol of
−30.6
−30.6
per 1 mol of
−30.6
per 1 mol of
−30.6

Changes in aqueous solution (6)

Reaction of zinc iodide and magnesium hydroxide
ZnI2Ionized aqueous solution + Mg(OH)2Amorphous solidprecipitated
MgI2Ionized aqueous solution + Zn(OH)2Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of
per 1 mol of

Changes in aqueous solution (7)

Reaction of zinc iodide and magnesium hydroxide
ZnI2Ionized aqueous solution + Mg(OH)2Amorphous solidprecipitated
MgI2Ionized aqueous solution + Zn(OH)2Crystalline solidγ
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of
per 1 mol of

Changes in aqueous solution (8)

Reaction of zinc iodide and magnesium hydroxide
ZnI2Ionized aqueous solution + Mg(OH)2Amorphous solidprecipitated
MgI2Ionized aqueous solution + Zn(OH)2Crystalline solidβ
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−34.4
per 1 mol of
−34.4
−34.4
per 1 mol of
−34.4
per 1 mol of
−34.4

Changes in aqueous solution (9)

Reaction of zinc iodide and magnesium hydroxide
ZnI2Ionized aqueous solution + Mg(OH)2Amorphous solidprecipitated
MgI2Ionized aqueous solution + Zn(OH)2Crystalline solidε
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−35.7
per 1 mol of
−35.7
−35.7
per 1 mol of
−35.7
per 1 mol of
−35.7

Changes in aqueous solution (10)

Reaction of zinc iodide and magnesium hydroxide
ZnI2Ionized aqueous solution + Mg(OH)2Amorphous solidprecipitated
MgI2Ionized aqueous solution + Zn(OH)2Crystalline solidprecipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−34.7
per 1 mol of
−34.7
−34.7
per 1 mol of
−34.7
per 1 mol of
−34.7

Changes in aqueous solution (11)

Reaction of zinc iodide and magnesium hydroxide
ΔrG−6.7 kJ/mol
K1.49 × 101
pK−1.17
ZnI2Un-ionized aqueous solution + Mg(OH)2Crystalline solid
MgI2Ionized aqueous solution + Zn(OH)2Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−6.7
per 1 mol of
−6.7
−6.7
per 1 mol of
−6.7
per 1 mol of
−6.7

Changes in aqueous solution (12)

Reaction of zinc iodide and magnesium hydroxide
ΔrG−37.8 kJ/mol
K4.19 × 106
pK−6.62
ZnI2Un-ionized aqueous solution + Mg(OH)2Crystalline solid
MgI2Ionized aqueous solution + Zn(OH)2Crystalline solidγ
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−37.8
per 1 mol of
−37.8
−37.8
per 1 mol of
−37.8
per 1 mol of
−37.8

Changes in aqueous solution (13)

Reaction of zinc iodide and magnesium hydroxide
ΔrG−37.5 kJ/mol
K3.71 × 106
pK−6.57
ZnI2Un-ionized aqueous solution + Mg(OH)2Crystalline solid
MgI2Ionized aqueous solution + Zn(OH)2Crystalline solidβ
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−37.5
per 1 mol of
−37.5
−37.5
per 1 mol of
−37.5
per 1 mol of
−37.5

Changes in aqueous solution (14)

Reaction of zinc iodide and magnesium hydroxide
ΔrG−39.1 kJ/mol
K7.08 × 106
pK−6.85
ZnI2Un-ionized aqueous solution + Mg(OH)2Crystalline solid
MgI2Ionized aqueous solution + Zn(OH)2Crystalline solidε
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−39.1
per 1 mol of
−39.1
−39.1
per 1 mol of
−39.1
per 1 mol of
−39.1

Changes in aqueous solution (15)

Reaction of zinc iodide and magnesium hydroxide
ZnI2Un-ionized aqueous solution + Mg(OH)2Crystalline solid
MgI2Ionized aqueous solution + Zn(OH)2Crystalline solidprecipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of
per 1 mol of

Changes in aqueous solution (16)

Reaction of zinc iodide and magnesium hydroxide
ZnI2Un-ionized aqueous solution + Mg(OH)2Amorphous solidprecipitated
MgI2Ionized aqueous solution + Zn(OH)2Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of
per 1 mol of

Changes in aqueous solution (17)

Reaction of zinc iodide and magnesium hydroxide
ZnI2Un-ionized aqueous solution + Mg(OH)2Amorphous solidprecipitated
MgI2Ionized aqueous solution + Zn(OH)2Crystalline solidγ
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of
per 1 mol of

Changes in aqueous solution (18)

Reaction of zinc iodide and magnesium hydroxide
ZnI2Un-ionized aqueous solution + Mg(OH)2Amorphous solidprecipitated
MgI2Ionized aqueous solution + Zn(OH)2Crystalline solidβ
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of
per 1 mol of

Changes in aqueous solution (19)

Reaction of zinc iodide and magnesium hydroxide
ZnI2Un-ionized aqueous solution + Mg(OH)2Amorphous solidprecipitated
MgI2Ionized aqueous solution + Zn(OH)2Crystalline solidε
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of
per 1 mol of

Changes in aqueous solution (20)

Reaction of zinc iodide and magnesium hydroxide
ZnI2Un-ionized aqueous solution + Mg(OH)2Amorphous solidprecipitated
MgI2Ionized aqueous solution + Zn(OH)2Crystalline solidprecipitated
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
per 1 mol of
per 1 mol of
per 1 mol of

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
ZnI2 (cr)-208.03[1]-208.95[1]161.1[1]
ZnI2 (ai)-264.26[1]-250.20[1]110.5[1]-238[1]
ZnI2 (ao)-240.6[1]
Mg(OH)2 (cr)-924.54[1]-833.51[1]63.18[1]77.03[1]
Mg(OH)2 (am)
precipitated
-920.5[1]
Mg(OH)2 (g)-561[1]
Mg(OH)2 (ai)-926.84[1]-769.4[1]-159.4[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution, (am):Amorphous solid, (g):Gas

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
MgI2 (cr)-364.0[1]-358.2[1]129.7[1]
MgI2 (g)-172[1]
MgI2 (ai)-577.22[1]-558.1[1]84.5[1]
Zn(OH)2 (cr)
γ
-553.81[1]
Zn(OH)2 (cr)
β
-641.91[1]-553.52[1]81.2[1]
Zn(OH)2 (cr)
ε
-643.25[1]-555.07[1]81.6[1]72.4[1]
Zn(OH)2 (cr)
precipitated
-642.2[1]
Zn(OH)2 (ai)-613.88[1]-461.56[1]-133.5[1]-251[1]
Zn(OH)2 (ao)-522.73[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution

References

List of references

  1. 1