2AlOH2+ + 2e− → 2Al3+ + 2O2− + H2
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Reduction of aluminium hydroxide ion yields aluminium ion, oxide ion, and (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reduction of aluminium hydroxide ion
General equation
- Reduction of reducible species
- ReactantOxidizing agent + e− ⟶ ProductReduction product
Oxidation state of each atom
- Reduction of aluminium hydroxide ion
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
AlOH2+ | Aluminium hydroxide ion | 2 | Oxidizing | – |
e− | Electron | 2 | – | Electron |
Products
Thermodynamic changes
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
AlOH2+ (ao) | – | -694.1[1] | – | – |
e− | – | – | – | – |
* (ao):Un-ionized aqueous solution
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
Al3+ (g) | 5483.17[1] | – | – | – |
Al3+ (ao) | -531[1] | -485[1] | -321.7[1] | – |
O2− | – | – | – | – |
(g) | 0[1] | 0[1] | 130.684[1] | 28.824[1] |
(ao) | -4.2[1] | 17.6[1] | 577[1] | – |
* (g):Gas, (ao):Un-ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)