2CH3COONH4 + 2KMnO4 → 2Mn + K2CO3 + 2H2CO3 + 3H2O + NH4CN
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The reaction of ammonium acetate and potassium permanganate yields , potassium carbonate, carbonic acid, water, and ammonium cyanide (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of ammonium acetate and potassium permanganate
General equation
- Reaction of reducing species and oxidizing species
- Reducing speciesReducing agent + Oxidizing speciesOxidizing agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of ammonium acetate and potassium permanganate
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
CH3COONH4 | Ammonium acetate | 2 | Reducing | Reducing |
KMnO4 | Potassium permanganate | 2 | Oxidizing | Oxidizing |
Products
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
2 | Reduced | – | ||
K2CO3 | Potassium carbonate | 1 | Oxidized | – |
H2CO3 | Carbonic acid | 2 | Oxidized | – |
H2O | Water | 3 | – | – |
NH4CN | Ammonium cyanide | 1 | Oxidized | – |
Thermodynamic changes
Changes in standard condition (1)
- Reaction of ammonium acetate and potassium permanganate◆
ΔrG −600.7 kJ/mol K 1.73 × 10105 pK −105.24
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −596.1 | −600.7 | 16.8 | – |
per 1 mol of | −298.1 | −300.4 | 8.40 | – |
per 1 mol of | −298.1 | −300.4 | 8.40 | – |
−298.1 | −300.4 | 8.40 | – | |
per 1 mol of | −596.1 | −600.7 | 16.8 | – |
per 1 mol of | −298.1 | −300.4 | 8.40 | – |
per 1 mol of | −198.7 | −200.2 | 5.60 | – |
per 1 mol of | −596.1 | −600.7 | 16.8 | – |
Changes in standard condition (2)
- Reaction of ammonium acetate and potassium permanganate
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −581.9 | – | – | – |
per 1 mol of | −290.9 | – | – | – |
per 1 mol of | −290.9 | – | – | – |
−290.9 | – | – | – | |
per 1 mol of | −581.9 | – | – | – |
per 1 mol of | −290.9 | – | – | – |
per 1 mol of | −194.0 | – | – | – |
per 1 mol of | −581.9 | – | – | – |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
CH3COONH4 (cr) | -616.14[1] | – | – | – |
CH3COONH4 (ai) | -618.52[1] | -448.61[1] | 200.0[1] | 73.6[1] |
KMnO4 (cr) | -837.2[1] | -737.6[1] | 171.71[1] | 117.57[1] |
KMnO4 (ai) | -793.8[1] | -730.5[1] | 293.7[1] | -60.2[1] |
* (cr):Crystalline solid, (ai):Ionized aqueous solution
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
(cr) α | 0[1] | 0[1] | 32.01[1] | 26.32[1] |
(cr) β | – | – | 34.39[1] | 26.53[1] |
(cr) γ | 1.55[1] | 1.42[1] | 32.43[1] | 27.57[1] |
(g) | 280.7[1] | 238.5[1] | 173.70[1] | 20.79[1] |
K2CO3 (cr) | -1151.02[1] | -1063.5[1] | 155.52[1] | 114.43[1] |
K2CO3 (ai) | -1181.90[1] | -1094.36[1] | 148.1[1] | – |
K2CO3 (cr) 1.5 hydrate | -1609.2[1] | -1432.5[1] | 203.3[1] | – |
H2CO3 (ao) | -699.65[1] | -623.08[1] | 187.4[1] | – |
H2O (cr) | – | – | – | – |
H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
NH4CN (cr) | 0.42[1] | – | – | 134[1] |
NH4CN (ai) | 18.0[1] | 93.0[1] | 207.5[1] | – |
NH4CN (aq) | 32.2[1] | – | – | – |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution, (l):Liquid, (aq):Aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -616.14 kJ · mol−1
- ^ ΔfH°, -618.52 kJ · mol−1
- ^ ΔfG°, -448.61 kJ · mol−1
- ^ S°, 200.0 J · K−1 · mol−1
- ^ Cp°, 73.6 J · K−1 · mol−1
- ^ ΔfH°, -837.2 kJ · mol−1
- ^ ΔfG°, -737.6 kJ · mol−1
- ^ S°, 171.71 J · K−1 · mol−1
- ^ Cp°, 117.57 J · K−1 · mol−1
- ^ ΔfH°, -793.8 kJ · mol−1
- ^ ΔfG°, -730.5 kJ · mol−1
- ^ S°, 293.7 J · K−1 · mol−1
- ^ Cp°, -60.2 J · K−1 · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 32.01 J · K−1 · mol−1
- ^ Cp°, 26.32 J · K−1 · mol−1
- ^ S°, 34.39 J · K−1 · mol−1
- ^ Cp°, 26.53 J · K−1 · mol−1
- ^ ΔfH°, 1.55 kJ · mol−1
- ^ ΔfG°, 1.42 kJ · mol−1
- ^ S°, 32.43 J · K−1 · mol−1
- ^ Cp°, 27.57 J · K−1 · mol−1
- ^ ΔfH°, 280.7 kJ · mol−1
- ^ ΔfG°, 238.5 kJ · mol−1
- ^ S°, 173.70 J · K−1 · mol−1
- ^ Cp°, 20.79 J · K−1 · mol−1
- ^ ΔfH°, -1151.02 kJ · mol−1
- ^ ΔfG°, -1063.5 kJ · mol−1
- ^ S°, 155.52 J · K−1 · mol−1
- ^ Cp°, 114.43 J · K−1 · mol−1
- ^ ΔfH°, -1181.90 kJ · mol−1
- ^ ΔfG°, -1094.36 kJ · mol−1
- ^ S°, 148.1 J · K−1 · mol−1
- ^ ΔfH°, -1609.2 kJ · mol−1
- ^ ΔfG°, -1432.5 kJ · mol−1
- ^ S°, 203.3 J · K−1 · mol−1
- ^ ΔfH°, -699.65 kJ · mol−1
- ^ ΔfG°, -623.08 kJ · mol−1
- ^ S°, 187.4 J · K−1 · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1
- ^ ΔfH°, 0.42 kJ · mol−1
- ^ Cp°, 134. J · K−1 · mol−1
- ^ ΔfH°, 18.0 kJ · mol−1
- ^ ΔfG°, 93.0 kJ · mol−1
- ^ S°, 207.5 J · K−1 · mol−1
- ^ ΔfH°, 32.2 kJ · mol−1