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2NH4I + 2O2 → NH4NO3 + H2O + 2HI

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Reaction of ammonium iodide and oxygen
2NH4IAmmonium iodide + 2O2Oxygen
⟶
NH4NO3Ammonium nitrate + H2OWater + 2HIHydrogen iodide

The reaction of ammonium iodide and oxygen yields ammonium nitrate, water, and hydrogen iodide (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

Reaction of ammonium iodide and oxygen
2NH4IAmmonium iodide + 2O2Oxygen
⟶
NH4NO3Ammonium nitrate + H2OWater + 2HIHydrogen iodide

General equation

Reaction of reducing species and oxidizing species
Reducing speciesReducing agent + Oxidizing speciesOxidizing agent
⟶
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reaction of ammonium iodide and oxygen

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
NH4IAmmonium iodide2
Reducing
Reducing
O2Oxygen2
Oxidizing
Oxidizing

Products

Chemical formulaNameCoefficientTypeType in general
equation
NH4NO3Ammonium nitrate1
Redoxed product
–
H2OWater1
Reduced
–
HIHydrogen iodide2
–
–

Thermodynamic changes

Changes in standard condition

Reaction of ammonium iodide and oxygen
◆
ΔrG−192.6 kJ/mol
K5.52 × 1033
pK−33.74
2NH4ICrystalline solid + 2O2Gas
⟶
NH4NO3Crystalline solid + H2OLiquid + 2HIGas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−195.59−192.6−10–
per 1 mol of
−97.795−96.30−5.0–
per 1 mol of
−97.795−96.30−5.0–
per 1 mol of
−195.59−192.6−10–
per 1 mol of
−195.59−192.6−10–
per 1 mol of
−97.795−96.30−5.0–

Changes in aqueous solution (1)

Reaction of ammonium iodide and oxygen
◆
ΔrG−195.3 kJ/mol
K1.64 × 1034
pK−34.22
2NH4IIonized aqueous solution + 2O2Un-ionized aqueous solution
⟶
NH4NO3Ionized aqueous solution + H2OLiquid + 2HIGas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−174.0−195.371.7–
per 1 mol of
−87.00−97.6535.9–
per 1 mol of
−87.00−97.6535.9–
per 1 mol of
−174.0−195.371.7–
per 1 mol of
−174.0−195.371.7–
per 1 mol of
−87.00−97.6535.9–

Changes in aqueous solution (2)

Reaction of ammonium iodide and oxygen
◆
ΔrG−301.9 kJ/mol
K7.77 × 1052
pK−52.89
2NH4IIonized aqueous solution + 2O2Un-ionized aqueous solution
⟶
NH4NO3Ionized aqueous solution + H2OLiquid + 2HIIonized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−337.3−301.9−118.9–
per 1 mol of
−168.7−150.9−59.45–
per 1 mol of
−168.7−150.9−59.45–
per 1 mol of
−337.3−301.9−118.9–
per 1 mol of
−337.3−301.9−118.9–
per 1 mol of
−168.7−150.9−59.45–

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1		Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1		Standard
molar entropy
S°
J · K−1 · mol−1		Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NH4I (cr)-201.42[1]-112.5[1]117[1]–
NH4I (ai)-187.69[1]-130.88[1]224.7[1]-62.3[1]
O2 (g)0[1]0[1]205.138[1]29.355[1]
O2 (ao)-11.7[1]16.4[1]110.9[1]–
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (g):Gas, (ao):Un-ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1		Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1		Standard
molar entropy
S°
J · K−1 · mol−1		Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NH4NO3 (cr)-365.56[1]-183.87[1]151.08[1]139.3[1]
NH4NO3 (ai)-339.87[1]-190.56[1]259.8[1]-6.7[1]
H2O (cr)––––
H2O (l)-285.830[1]-237.129[1]69.91[1]75.291[1]
H2O (g)-241.818[1]-228.572[1]188.825[1]33.577[1]
HI (g)26.48[1]1.70[1]206.594[1]29.158[1]
HI (ai)-55.19[1]-51.57[1]111.3[1]-142.3[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (l):Liquid, (g):Gas

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)