2H2 + BaMnO4 → MnO + BaO + 2H2O
Last updated:
- Reaction of and barium manganate
The reaction of and barium manganate yields manganese(II) oxide, barium oxide, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of and barium manganate
General equation
- Reaction of reducing species and oxidizing species
- Reducing speciesReducing agent + Oxidizing speciesOxidizing agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of and barium manganate
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
2 | Reducing | Reducing | ||
BaMnO4 | Barium manganate | 1 | Oxidizing | Oxidizing |
Products
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
MnO | Manganese(II) oxide | 1 | Reduced | – |
BaO | Barium oxide | 1 | – | – |
H2O | Water | 2 | Oxidized | – |
Thermodynamic changes
Changes in standard condition
- Reaction of and barium manganate◆
ΔrG −243.1 kJ/mol K 3.88 × 1042 pK −42.59
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | −243.1 | – | – |
– | −121.5 | – | – | |
per 1 mol of | – | −243.1 | – | – |
per 1 mol of | – | −243.1 | – | – |
per 1 mol of | – | −243.1 | – | – |
per 1 mol of | – | −121.5 | – | – |
Changes in aqueous solution
- Reaction of and barium manganate◆
ΔrG −278.3 kJ/mol K 5.70 × 1048 pK −48.76
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | −278.3 | – | – |
– | −139.2 | – | – | |
per 1 mol of | – | −278.3 | – | – |
per 1 mol of | – | −278.3 | – | – |
per 1 mol of | – | −278.3 | – | – |
per 1 mol of | – | −139.2 | – | – |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
(g) | 0[1] | 0[1] | 130.684[1] | 28.824[1] |
(ao) | -4.2[1] | 17.6[1] | 577[1] | – |
BaMnO4 (cr) | – | -1119.2[1] | – | – |
* (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
MnO (cr) | -385.22[1] | -362.90[1] | 59.71[1] | 45.44[1] |
MnO (g) | 124.22[1] | – | – | – |
BaO (cr) | -553.5[1] | -525.1[1] | 70.42[1] | 47.78[1] |
BaO (g) | -117[1] | – | – | 33.1[1] |
H2O (cr) | – | – | – | – |
H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
* (cr):Crystalline solid, (g):Gas, (l):Liquid
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 130.684 J · K−1 · mol−1
- ^ Cp°, 28.824 J · K−1 · mol−1
- ^ ΔfH°, -4.2 kJ · mol−1
- ^ ΔfG°, 17.6 kJ · mol−1
- ^ S°, 577 J · K−1 · mol−1
- ^ ΔfG°, -1119.2 kJ · mol−1
- ^ ΔfH°, -385.22 kJ · mol−1
- ^ ΔfG°, -362.90 kJ · mol−1
- ^ S°, 59.71 J · K−1 · mol−1
- ^ Cp°, 45.44 J · K−1 · mol−1
- ^ ΔfH°, 124.22 kJ · mol−1
- ^ ΔfH°, -553.5 kJ · mol−1
- ^ ΔfG°, -525.1 kJ · mol−1
- ^ S°, 70.42 J · K−1 · mol−1
- ^ Cp°, 47.78 J · K−1 · mol−1
- ^ ΔfH°, -117. kJ · mol−1
- ^ Cp°, 33.1 J · K−1 · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1