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2H2S + Sr(NO3)2 → SO2 + 2NO + SrS + 2H2O

The reaction of hydrogen sulfide and strontium nitrate yields sulfur dioxide, nitrogen monoxide, strontium sulfide, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Reaction of reducing species and oxidizing species
Reducing speciesReducing agent + Oxidizing speciesOxidizing agent
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
H2SHydrogen sulfide2
Reducing
Reducing
Sr(NO3)2Strontium nitrate1
Oxidizing
Oxidizing

Products

Chemical formulaNameCoefficientTypeType in general
equation
SO2Sulfur dioxide1
Oxidized
NONitrogen monoxide2
Reduced
SrSStrontium sulfide1
H2OWater2

Thermodynamic changes

Changes in standard condition

Reaction of hydrogen sulfide and strontium nitrate
ΔrG−222.0 kJ/mol
K7.81 × 1038
pK−38.89
2H2SGas + Sr(NO3)2Crystalline solid
SO2Gas + 2NOGas + SrSCrystalline solid + 2H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−140.9−222.0271.680.47
per 1 mol of
−70.45−111.0135.840.23
per 1 mol of
−140.9−222.0271.680.47
per 1 mol of
−140.9−222.0271.680.47
per 1 mol of
−70.45−111.0135.840.23
per 1 mol of
−140.9−222.0271.680.47
per 1 mol of
−70.45−111.0135.840.23

Changes in aqueous solution (1)

Reaction of hydrogen sulfide and strontium nitrate
ΔrG−231.5 kJ/mol
K3.61 × 1040
pK−40.56
2H2SUn-ionized aqueous solution + Sr(NO3)2Ionized aqueous solution
SO2Gas + 2NOGas + SrSCrystalline solid + 2H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−120.5−231.5376
per 1 mol of
−60.25−115.8188
per 1 mol of
−120.5−231.5376
per 1 mol of
−120.5−231.5376
per 1 mol of
−60.25−115.8188
per 1 mol of
−120.5−231.5376
per 1 mol of
−60.25−115.8188

Changes in aqueous solution (2)

Reaction of hydrogen sulfide and strontium nitrate
ΔrG−232.0 kJ/mol
K4.41 × 1040
pK−40.64
2H2SUn-ionized aqueous solution + Sr(NO3)2Ionized aqueous solution
SO2Un-ionized aqueous solution + 2NOGas + SrSCrystalline solid + 2H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−146.6−232.0289
per 1 mol of
−73.30−116.0145
per 1 mol of
−146.6−232.0289
per 1 mol of
−146.6−232.0289
per 1 mol of
−73.30−116.0145
per 1 mol of
−146.6−232.0289
per 1 mol of
−73.30−116.0145

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
H2S (g)-20.63[1]-33.56[1]205.79[1]34.23[1]
H2S (ao)-39.7[1]-27.83[1]121[1]
Sr(NO3)2 (cr)-978.22[1]-780.02[1]194.56[1]149.91[1]
Sr(NO3)2 (ai)-960.52[1]-781.98[1]260.2[1]
Sr(NO3)2 (cr)
4 hydrate
-2154.8[1]-1730.39[1]369.0[1]
* (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
SO2 (l)-320.5[1]
SO2 (g)-296.830[1]-300.194[1]248.22[1]39.87[1]
SO2 (ao)-322.980[1]-300.676[1]161.9[1]
NO (g)90.25[1]86.55[1]210.761[1]29.844[1]
SrS (cr)-472.4[1]-467.8[1]68.2[1]48.70[1]
SrS (g)109[1]
H2O (cr)
H2O (l)-285.830[1]-237.129[1]69.91[1]75.291[1]
H2O (g)-241.818[1]-228.572[1]188.825[1]33.577[1]
* (l):Liquid, (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)