2H2S + Sr(NO3)2 → SO2 + 2NO + SrS + 2H2O
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The reaction of hydrogen sulfide and strontium nitrate yields sulfur dioxide, nitrogen monoxide, strontium sulfide, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of hydrogen sulfide and strontium nitrate
General equation
- Reaction of reducing species and oxidizing species
- Reducing speciesReducing agent + Oxidizing speciesOxidizing agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of hydrogen sulfide and strontium nitrate
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
H2S | Hydrogen sulfide | 2 | Reducing | Reducing |
Sr(NO3)2 | Strontium nitrate | 1 | Oxidizing | Oxidizing |
Products
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
SO2 | Sulfur dioxide | 1 | Oxidized | – |
NO | Nitrogen monoxide | 2 | Reduced | – |
SrS | Strontium sulfide | 1 | – | – |
H2O | Water | 2 | – | – |
Thermodynamic changes
Changes in standard condition
- Reaction of hydrogen sulfide and strontium nitrate◆
ΔrG −222.0 kJ/mol K 7.81 × 1038 pK −38.89
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −140.9 | −222.0 | 271.6 | 80.47 |
per 1 mol of | −70.45 | −111.0 | 135.8 | 40.23 |
per 1 mol of | −140.9 | −222.0 | 271.6 | 80.47 |
per 1 mol of | −140.9 | −222.0 | 271.6 | 80.47 |
per 1 mol of | −70.45 | −111.0 | 135.8 | 40.23 |
per 1 mol of | −140.9 | −222.0 | 271.6 | 80.47 |
per 1 mol of | −70.45 | −111.0 | 135.8 | 40.23 |
Changes in aqueous solution (1)
- Reaction of hydrogen sulfide and strontium nitrate◆
ΔrG −231.5 kJ/mol K 3.61 × 1040 pK −40.56
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −120.5 | −231.5 | 376 | – |
per 1 mol of | −60.25 | −115.8 | 188 | – |
per 1 mol of | −120.5 | −231.5 | 376 | – |
per 1 mol of | −120.5 | −231.5 | 376 | – |
per 1 mol of | −60.25 | −115.8 | 188 | – |
per 1 mol of | −120.5 | −231.5 | 376 | – |
per 1 mol of | −60.25 | −115.8 | 188 | – |
Changes in aqueous solution (2)
- Reaction of hydrogen sulfide and strontium nitrate◆
ΔrG −232.0 kJ/mol K 4.41 × 1040 pK −40.64
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −146.6 | −232.0 | 289 | – |
per 1 mol of | −73.30 | −116.0 | 145 | – |
per 1 mol of | −146.6 | −232.0 | 289 | – |
per 1 mol of | −146.6 | −232.0 | 289 | – |
per 1 mol of | −73.30 | −116.0 | 145 | – |
per 1 mol of | −146.6 | −232.0 | 289 | – |
per 1 mol of | −73.30 | −116.0 | 145 | – |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
H2S (g) | -20.63[1] | -33.56[1] | 205.79[1] | 34.23[1] |
H2S (ao) | -39.7[1] | -27.83[1] | 121[1] | – |
Sr(NO3)2 (cr) | -978.22[1] | -780.02[1] | 194.56[1] | 149.91[1] |
Sr(NO3)2 (ai) | -960.52[1] | -781.98[1] | 260.2[1] | – |
Sr(NO3)2 (cr) 4 hydrate | -2154.8[1] | -1730.39[1] | 369.0[1] | – |
* (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid, (ai):Ionized aqueous solution
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
SO2 (l) | -320.5[1] | – | – | – |
SO2 (g) | -296.830[1] | -300.194[1] | 248.22[1] | 39.87[1] |
SO2 (ao) | -322.980[1] | -300.676[1] | 161.9[1] | – |
NO (g) | 90.25[1] | 86.55[1] | 210.761[1] | 29.844[1] |
SrS (cr) | -472.4[1] | -467.8[1] | 68.2[1] | 48.70[1] |
SrS (g) | 109[1] | – | – | – |
H2O (cr) | – | – | – | – |
H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
* (l):Liquid, (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -20.63 kJ · mol−1
- ^ ΔfG°, -33.56 kJ · mol−1
- ^ S°, 205.79 J · K−1 · mol−1
- ^ Cp°, 34.23 J · K−1 · mol−1
- ^ ΔfH°, -39.7 kJ · mol−1
- ^ ΔfG°, -27.83 kJ · mol−1
- ^ S°, 121. J · K−1 · mol−1
- ^ ΔfH°, -978.22 kJ · mol−1
- ^ ΔfG°, -780.02 kJ · mol−1
- ^ S°, 194.56 J · K−1 · mol−1
- ^ Cp°, 149.91 J · K−1 · mol−1
- ^ ΔfH°, -960.52 kJ · mol−1
- ^ ΔfG°, -781.98 kJ · mol−1
- ^ S°, 260.2 J · K−1 · mol−1
- ^ ΔfH°, -2154.8 kJ · mol−1
- ^ ΔfG°, -1730.39 kJ · mol−1
- ^ S°, 369.0 J · K−1 · mol−1
- ^ ΔfH°, -320.5 kJ · mol−1
- ^ ΔfH°, -296.830 kJ · mol−1
- ^ ΔfG°, -300.194 kJ · mol−1
- ^ S°, 248.22 J · K−1 · mol−1
- ^ Cp°, 39.87 J · K−1 · mol−1
- ^ ΔfH°, -322.980 kJ · mol−1
- ^ ΔfG°, -300.676 kJ · mol−1
- ^ S°, 161.9 J · K−1 · mol−1
- ^ ΔfH°, 90.25 kJ · mol−1
- ^ ΔfG°, 86.55 kJ · mol−1
- ^ S°, 210.761 J · K−1 · mol−1
- ^ Cp°, 29.844 J · K−1 · mol−1
- ^ ΔfH°, -472.4 kJ · mol−1
- ^ ΔfG°, -467.8 kJ · mol−1
- ^ S°, 68.2 J · K−1 · mol−1
- ^ Cp°, 48.70 J · K−1 · mol−1
- ^ ΔfH°, 109. kJ · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1