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2LiI + Na2SiO3 ๐Ÿ’งโ†’ Li2SiO3โ†“ + 2NaI

The reaction of lithium iodide and sodium metasilicate yields lithium metasilicate and sodium iodide. This reaction is an acid-base reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related categories

Reaction data

Chemical equation

General equation

Oxidation state of each atom

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
LiILithium iodide2
Lewis acid
Very soluble in water
Na2SiO3Sodium metasilicate1
Lewis base
Soluble in water

Products

Chemical formulaNameCoefficientTypeType in general
equation
Li2SiO3Lithium metasilicate1
Lewis conjugate
Insoluble in water
NaISodium iodide2
Non-redox product
โ€“

Thermodynamic changes

Changes in standard condition

Reaction of lithium iodide and sodium metasilicate
โ—†
ฮ”rGโˆ’125.9 kJ/mol
K1.14 ร— 1022
pKโˆ’22.06
2LiICrystalline solid + Na2SiO3Crystalline solid
๐Ÿ’ง
โŸถ
Li2SiO3โ†“Crystalline solid + 2NaICrystalline solid
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
โˆ’127.9โˆ’125.9โˆ’10.52โ€“
per 1 mol of
โˆ’63.95โˆ’62.95โˆ’5.260โ€“
โˆ’127.9โˆ’125.9โˆ’10.52โ€“
โˆ’127.9โˆ’125.9โˆ’10.52โ€“
per 1 mol of
โˆ’63.95โˆ’62.95โˆ’5.260โ€“

Changes in aqueous solution

Reaction of lithium iodide and sodium metasilicate
2LiIIonized aqueous solution + Na2SiO3Aqueous solution
๐Ÿ’ง
โŸถ
Li2SiO3โ†“Crystalline solid + 2NaIIonized aqueous solution
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
14.8โ€“โ€“โ€“
per 1 mol of
7.40โ€“โ€“โ€“
14.8โ€“โ€“โ€“
14.8โ€“โ€“โ€“
per 1 mol of
7.40โ€“โ€“โ€“

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ฮ”fHยฐ
kJ ยท molโˆ’1
Standard Gibbs
energy of
formation
ฮ”fGยฐ
kJ ยท molโˆ’1
Standard
molar entropy
Sยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard molar
heat capacity at
constant pressure
Cpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
LiI (cr)-270.41[1]-270.29[1]86.78[1]51.04[1]
LiI (g)-81.09[1]-124.34[1]232.321[1]34.64[1]
LiI (ai)-333.67[1]-344.8[1]124.7[1]-73.6[1]
LiI (cr)
1 hydrate
-590.32[1]-531.3[1]123.0[1]โ€“
LiI (cr)
2 hydrate
-890.40[1]-780.2[1]184[1]โ€“
LiI (cr)
3 hydrate
-1192.15[1]-1032.13[1]250.2[1]โ€“
Na2SiO3 (cr)-1554.90[1]-1462.80[1]113.85[1]โ€“
Na2SiO3 (vit)-1540.1[1]โ€“โ€“โ€“
Na2SiO3 (aq)-1586.2[1]โ€“โ€“โ€“
Na2SiO3 (cr)
5 hydrate
-3048.5[1]โ€“โ€“โ€“
Na2SiO3 (cr)
9 hydrate
-4228.8[1]โ€“โ€“โ€“
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (vit):Vitreous liquid, (aq):Aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ฮ”fHยฐ
kJ ยท molโˆ’1
Standard Gibbs
energy of
formation
ฮ”fGยฐ
kJ ยท molโˆ’1
Standard
molar entropy
Sยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard molar
heat capacity at
constant pressure
Cpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Li2SiO3 (cr)-1648.1[1]-1557.2[1]79.83[1]99.08[1]
Li2SiO3 (vit)-1628[1]โ€“โ€“โ€“
NaI (cr)-287.78[1]-286.06[1]98.53[1]52.09[1]
NaI (g)-79.5[1]-121.0[1]248.978[1]36.65[1]
NaI (ai)-295.31[1]-313.47[1]170.3[1]-95.8[1]
NaI (cr)
1 hydrate
-883.096[1]-771.10[1]196.2[1]โ€“
* (cr):Crystalline solid, (vit):Vitreous liquid, (g):Gas, (ai):Ionized aqueous solution

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)