2Na + SrBr2 🔥→ 2NaBr + Sr
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- Reaction of and strontium bromide
The reaction of and strontium bromide yields sodium bromide and . This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of and strontium bromide
General equation
- Reaction of reducing species and hardly reducible species
- Reducing speciesReducing agent + Hardly reducible speciesOxidizing agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of and strontium bromide
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
2 | Reducing | Reducing | ||
SrBr2 | Strontium bromide | 1 | Oxidizing | Hardly reducible |
Products
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
NaBr | Sodium bromide | 2 | Oxidized | – |
1 | Reduced | – |
Thermodynamic changes
Changes in standard condition
- Reaction of and strontium bromide◆
ΔrG −0.9 kJ/mol K 1.44 × 100 pK −0.16
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −4.5 | −0.9 | −11.6 | −2.7 |
−2.3 | −0.45 | −5.80 | −1.4 | |
per 1 mol of | −4.5 | −0.90 | −11.6 | −2.7 |
per 1 mol of | −2.3 | −0.45 | −5.80 | −1.4 |
−4.5 | −0.90 | −11.6 | −2.7 |
Changes in aqueous solution
- Reaction of and strontium bromide◆
ΔrG 35.69 kJ/mol K 0.56 × 10−6 pK 6.25
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | 65.56 | 35.69 | 100.5 | – |
32.78 | 17.84 | 50.25 | – | |
per 1 mol of | 65.56 | 35.69 | 100.5 | – |
per 1 mol of | 32.78 | 17.84 | 50.25 | – |
65.56 | 35.69 | 100.5 | – |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
(cr) | 0[1] | 0[1] | 51.21[1] | 28.24[1] |
(g) | 107.32[1] | 76.761[1] | 153.712[1] | 20.786[1] |
SrBr2 (cr) | -717.6[1] | -697.1[1] | 135.10[1] | 75.35[1] |
SrBr2 (g) | -410[1] | -444[1] | 323.5[1] | 60.7[1] |
SrBr2 (ai) | -788.89[1] | -767.39[1] | 132.2[1] | – |
SrBr2 (cr) 1 hydrate | -1031.4[1] | -954.3[1] | 180[1] | 120.9[1] |
SrBr2 (cr) 6 hydrate | -2531.3[1] | -2174.1[1] | 406[1] | 343.5[1] |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
NaBr (cr) | -361.062[1] | -348.983[1] | 86.82[1] | 51.38[1] |
NaBr (g) | -143.1[1] | -177.06[1] | 241.19[1] | 36.32[1] |
NaBr (ai) | -361.665[1] | -365.849[1] | 141.4[1] | -95.4[1] |
NaBr (cr) 2 hydrate | -951.94[1] | -828.29[1] | 179.1[1] | – |
(cr) α | 0[1] | 0[1] | 52.3[1] | 26.4[1] |
(g) | 164.4[1] | 130.9[1] | 164.62[1] | 20.786[1] |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 51.21 J · K−1 · mol−1
- ^ Cp°, 28.24 J · K−1 · mol−1
- ^ ΔfH°, 107.32 kJ · mol−1
- ^ ΔfG°, 76.761 kJ · mol−1
- ^ S°, 153.712 J · K−1 · mol−1
- ^ Cp°, 20.786 J · K−1 · mol−1
- ^ ΔfH°, -717.6 kJ · mol−1
- ^ ΔfG°, -697.1 kJ · mol−1
- ^ S°, 135.10 J · K−1 · mol−1
- ^ Cp°, 75.35 J · K−1 · mol−1
- ^ ΔfH°, -410. kJ · mol−1
- ^ ΔfG°, -444. kJ · mol−1
- ^ S°, 323.5 J · K−1 · mol−1
- ^ Cp°, 60.7 J · K−1 · mol−1
- ^ ΔfH°, -788.89 kJ · mol−1
- ^ ΔfG°, -767.39 kJ · mol−1
- ^ S°, 132.2 J · K−1 · mol−1
- ^ ΔfH°, -1031.4 kJ · mol−1
- ^ ΔfG°, -954.3 kJ · mol−1
- ^ S°, 180. J · K−1 · mol−1
- ^ Cp°, 120.9 J · K−1 · mol−1
- ^ ΔfH°, -2531.3 kJ · mol−1
- ^ ΔfG°, -2174.1 kJ · mol−1
- ^ S°, 406. J · K−1 · mol−1
- ^ Cp°, 343.5 J · K−1 · mol−1
- ^ ΔfH°, -361.062 kJ · mol−1
- ^ ΔfG°, -348.983 kJ · mol−1
- ^ S°, 86.82 J · K−1 · mol−1
- ^ Cp°, 51.38 J · K−1 · mol−1
- ^ ΔfH°, -143.1 kJ · mol−1
- ^ ΔfG°, -177.06 kJ · mol−1
- ^ S°, 241.19 J · K−1 · mol−1
- ^ Cp°, 36.32 J · K−1 · mol−1
- ^ ΔfH°, -361.665 kJ · mol−1
- ^ ΔfG°, -365.849 kJ · mol−1
- ^ S°, 141.4 J · K−1 · mol−1
- ^ Cp°, -95.4 J · K−1 · mol−1
- ^ ΔfH°, -951.94 kJ · mol−1
- ^ ΔfG°, -828.29 kJ · mol−1
- ^ S°, 179.1 J · K−1 · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 52.3 J · K−1 · mol−1
- ^ Cp°, 26.4 J · K−1 · mol−1
- ^ ΔfH°, 164.4 kJ · mol−1
- ^ ΔfG°, 130.9 kJ · mol−1
- ^ S°, 164.62 J · K−1 · mol−1
- ^ Cp°, 20.786 J · K−1 · mol−1