3H2 + Rb2SO4 → S + 2RbOH + 2H2O
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- Reaction of and rubidium sulfate
The reaction of and rubidium sulfate yields , rubidium hydroxide, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of and rubidium sulfate
General equation
- Reaction of reducing species and reducible species
- Reducing speciesReducing agent + Reducible speciesOxidizing agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of and rubidium sulfate
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| 3 | Reducing | Reducing | ||
| Rb2SO4 | Rubidium sulfate | 1 | Oxidizing | Reducible |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| 1 | Reduced | – | ||
| RbOH | Rubidium hydroxide | 2 | Oxidized | – |
| H2O | Water | 2 | Oxidized | – |
Thermodynamic changes
Changes in standard condition (1)
- Reaction of and rubidium sulfate
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 27.57 | – | – | – |
| 9.190 | – | – | – | |
per 1 mol of | 27.57 | – | – | – |
| 27.57 | – | – | – | |
per 1 mol of | 13.79 | – | – | – |
per 1 mol of | 13.79 | – | – | – |
Changes in standard condition (2)
- Reaction of and rubidium sulfate
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 27.90 | – | – | – |
| 9.300 | – | – | – | |
per 1 mol of | 27.90 | – | – | – |
| 27.90 | – | – | – | |
per 1 mol of | 13.95 | – | – | – |
per 1 mol of | 13.95 | – | – | – |
Changes in aqueous solution
- Reaction of and rubidium sulfate◆
ΔrG −97.0 kJ/mol K 9.86 × 1016 pK −16.99
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −109.8 | −97.0 | −1601 | – |
| −36.60 | −32.3 | −533.7 | – | |
per 1 mol of | −109.8 | −97.0 | −1601 | – |
| −109.8 | −97.0 | −1601 | – | |
per 1 mol of | −54.90 | −48.5 | −800.5 | – |
per 1 mol of | −54.90 | −48.5 | −800.5 | – |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| (g) | 0[1] | 0[1] | 130.684[1] | 28.824[1] |
| (ao) | -4.2[1] | 17.6[1] | 577[1] | – |
| Rb2SO4 (cr) | -1435.61[1] | -1316.89[1] | 197.44[1] | 134.06[1] |
| Rb2SO4 (g) | -1068.6[1] | – | – | – |
| Rb2SO4 (ai) | -1411.60[1] | -1312.50[1] | 263.2[1] | – |
* (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid, (ai):Ionized aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| (cr) rhombic | 0[1] | 0[1] | 31.80[1] | 22.64[1] |
| (cr) monoclinic | 0.33[1] | – | – | – |
| (g) | 278.805[1] | 238.250[1] | 167.821[1] | 23.673[1] |
| RbOH (cr) | -418.19[1] | – | – | – |
| RbOH (g) | -238[1] | – | – | – |
| RbOH (ai) | -481.16[1] | -441.21[1] | 110.75[1] | – |
| RbOH (cr) 1 hydrate | -748.85[1] | – | – | – |
| RbOH (cr) 2 hydrate | -1053.24[1] | – | – | – |
| H2O (cr) | – | – | – | – |
| H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
| H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (l):Liquid
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 130.684 J · K−1 · mol−1
- ^ Cp°, 28.824 J · K−1 · mol−1
- ^ ΔfH°, -4.2 kJ · mol−1
- ^ ΔfG°, 17.6 kJ · mol−1
- ^ S°, 577 J · K−1 · mol−1
- ^ ΔfH°, -1435.61 kJ · mol−1
- ^ ΔfG°, -1316.89 kJ · mol−1
- ^ S°, 197.44 J · K−1 · mol−1
- ^ Cp°, 134.06 J · K−1 · mol−1
- ^ ΔfH°, -1068.6 kJ · mol−1
- ^ ΔfH°, -1411.60 kJ · mol−1
- ^ ΔfG°, -1312.50 kJ · mol−1
- ^ S°, 263.2 J · K−1 · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 31.80 J · K−1 · mol−1
- ^ Cp°, 22.64 J · K−1 · mol−1
- ^ ΔfH°, 0.33 kJ · mol−1
- ^ ΔfH°, 278.805 kJ · mol−1
- ^ ΔfG°, 238.250 kJ · mol−1
- ^ S°, 167.821 J · K−1 · mol−1
- ^ Cp°, 23.673 J · K−1 · mol−1
- ^ ΔfH°, -418.19 kJ · mol−1
- ^ ΔfH°, -238. kJ · mol−1
- ^ ΔfH°, -481.16 kJ · mol−1
- ^ ΔfG°, -441.21 kJ · mol−1
- ^ S°, 110.75 J · K−1 · mol−1
- ^ ΔfH°, -748.85 kJ · mol−1
- ^ ΔfH°, -1053.24 kJ · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1