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  3. 64NaCl + 102CsClO3 + 102H^+ 🔥→ 64NaClO3 + 8ClO2↑ + 47Cl2O↑ + 102Cs^+ + 51H2O

64NaCl + 102CsClO3 + 102H+ 🔥→ 64NaClO3 + 8ClO2↑ + 47Cl2O↑ + 102Cs+ + 51H2O

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Reaction of sodium chloride and caesium chlorate under acidic condition
64NaClSodium chloride + 102CsClO3Caesium chlorate + 102H+Hydrogen ion
🔥
⟶
64NaClO3Sodium chlorate + 8ClO2↑Chlorine dioxide + 47Cl2O↑Dichlorine monoxide + 102Cs+Caesium ion + 51H2OWater

The reaction of sodium chloride, caesium chlorate, and hydrogen ion yields sodium chlorate, chlorine dioxide, dichlorine monoxide, caesium ion, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

Reaction of sodium chloride and caesium chlorate under acidic condition
64NaClSodium chloride + 102CsClO3Caesium chlorate + 102H+Hydrogen ion
🔥
⟶
64NaClO3Sodium chlorate + 8ClO2↑Chlorine dioxide + 47Cl2O↑Dichlorine monoxide + 102Cs+Caesium ion + 51H2OWater

General equation

Reaction of hardly oxidizable species and oxidizing species under acidic condition
Hardly oxidizable speciesReducing agent + Oxidizing speciesOxidizing agent + H+Non-redox agent
⟶
ProductOxidation product + ProductReduction product + H2ONon-redox product

Oxidation state of each atom

Reaction of sodium chloride and caesium chlorate under acidic condition

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
NaClSodium chloride64
Reducing
Hardly oxidizable
CsClO3Caesium chlorate102
Oxidizing
Oxidizing under acidic condition
H+Hydrogen ion102
–
Hydrogen ion

Products

Chemical formulaNameCoefficientTypeType in general
equation
NaClO3Sodium chlorate64
–
–
ClO2Chlorine dioxide8
Reduced
–
Cl2ODichlorine monoxide47
Redoxed product
–
Cs+Caesium ion102
–
–
H2OWater51
–
Water

Thermodynamic changes

Changes in standard condition (1)

Reaction of sodium chloride and caesium chlorate under acidic condition
◆
ΔrG2173.4 kJ/mol
K0.17 × 10−380
pK380.76
64NaClIonized aqueous solution + 102CsClO3Ionized aqueous solution + 102H+Un-ionized aqueous solution
🔥
⟶
64NaClO3Ionized aqueous solution + 8ClO2↑Gas + 47Cl2O↑Gas + 102Cs+Un-ionized aqueous solution + 51H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
4665.22173.48343.5–
per 1 mol of
72.89433.959130.37–
per 1 mol of
45.73721.30881.799–
per 1 mol of
Hydrogen ion
45.73721.30881.799–
per 1 mol of
72.89433.959130.37–
per 1 mol of
583.15271.681042.9–
99.26046.243177.52–
per 1 mol of
Caesium ion
45.73721.30881.799–
per 1 mol of
91.47542.616163.60–

Changes in standard condition (2)

Reaction of sodium chloride and caesium chlorate under acidic condition
◆
ΔrG2170.2 kJ/mol
K0.63 × 10−380
pK380.20
64NaClIonized aqueous solution + 102CsClO3Ionized aqueous solution + 102H+Un-ionized aqueous solution
🔥
⟶
64NaClO3Ionized aqueous solution + 8ClO2↑Un-ionized aqueous solution + 47Cl2O↑Gas + 102Cs+Un-ionized aqueous solution + 51H2OLiquid
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
4444.42170.27607.2–
per 1 mol of
69.44433.909118.86–
per 1 mol of
43.57321.27674.580–
per 1 mol of
Hydrogen ion
43.57321.27674.580–
per 1 mol of
69.44433.909118.86–
per 1 mol of
555.55271.27950.90–
94.56246.174161.86–
per 1 mol of
Caesium ion
43.57321.27674.580–
per 1 mol of
87.14542.553149.16–

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1		Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1		Standard
molar entropy
S°
J · K−1 · mol−1		Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NaCl (cr)-411.153[1]-384.138[1]72.13[1]50.50[1]
NaCl (g)-176.65[1]-196.66[1]229.81[1]35.77[1]
NaCl (ai)-407.27[1]-393.133[1]115.5[1]-90.0[1]
CsClO3 (cr)-411.7[1]-307.9[1]156.1[1]–
CsClO3 (ai)-362.25[1]-299.97[1]295.4[1]–
H+ (g)1536.202[1]–––
H+ (ao)0[1]0[1]0[1]0[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1		Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1		Standard
molar entropy
S°
J · K−1 · mol−1		Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NaClO3 (cr)-365.774[1]-262.259[1]123.4[1]–
NaClO3 (ai)-344.09[1]-269.84[1]221.3[1]–
ClO2 (g)102.5[1]120.5[1]256.84[1]41.97[1]
ClO2 (ao)74.9[1]120.1[1]164.8[1]–
Cl2O (g)80.3[1]97.9[1]266.21[1]45.40[1]
Cs+ (g)457.964[1]–––
Cs+ (ao)-258.28[1]-292.02[1]133.05[1]-10.5[1]
H2O (cr)––––
H2O (l)-285.830[1]-237.129[1]69.91[1]75.291[1]
H2O (g)-241.818[1]-228.572[1]188.825[1]33.577[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (g):Gas, (ao):Un-ionized aqueous solution, (l):Liquid

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)