6KI + CaSeO4 🔥→ 3K2O + 3I2 + Se + CaO
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- Reaction of potassium iodide and calcium selenate
The reaction of potassium iodide and calcium selenate yields potassium oxide, , , and calcium oxide (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of potassium iodide and calcium selenate
General equation
- Reaction of oxidizable species and reducible species
- Oxidizable speciesReducing agent + Reducible speciesOxidizing agent🔥⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of potassium iodide and calcium selenate
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| KI | Potassium iodide | 6 | Reducing | Oxidizable |
| CaSeO4 | Calcium selenate | 1 | Oxidizing | Reducible |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| K2O | Potassium oxide | 3 | – | – |
| 3 | Oxidized | – | ||
| 1 | Reduced | – | ||
| CaO | Calcium oxide | 1 | – | – |
Thermodynamic changes
Changes in standard condition (1)
- Reaction of potassium iodide and calcium selenate
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 1357.6 | – | – | – |
per 1 mol of | 226.27 | – | – | – |
per 1 mol of | 1357.6 | – | – | – |
per 1 mol of | 452.53 | – | – | – |
| 452.53 | – | – | – | |
| 1357.6 | – | – | – | |
per 1 mol of | 1357.6 | – | – | – |
Changes in standard condition (2)
- Reaction of potassium iodide and calcium selenate
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 1364.3 | – | – | – |
per 1 mol of | 227.38 | – | – | – |
per 1 mol of | 1364.3 | – | – | – |
per 1 mol of | 454.77 | – | – | – |
| 454.77 | – | – | – | |
| 1364.3 | – | – | – | |
per 1 mol of | 1364.3 | – | – | – |
Changes in aqueous solution
- Reaction of potassium iodide and calcium selenate
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 1303.4 | – | – | – |
per 1 mol of | 217.23 | – | – | – |
per 1 mol of | 1303.4 | – | – | – |
per 1 mol of | 434.47 | – | – | – |
| 434.47 | – | – | – | |
| 1303.4 | – | – | – | |
per 1 mol of | 1303.4 | – | – | – |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| KI (cr) | -327.900[1] | -324.892[1] | 106.32[1] | 52.93[1] |
| KI (g) | -125.5[1] | -166.1[1] | 258.3[1] | 37.11[1] |
| KI (ai) | -307.57[1] | -334.85[1] | 213.8[1] | -120.5[1] |
| CaSeO4 (cr) | -1109.81[1] | – | – | – |
| CaSeO4 (cr) 2 hydrate | -1706.7[1] | -1486.8[1] | 222[1] | – |
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| K2O (cr) | -361.5[1] | -322.1[2] | 94.1[2] | 83.7[2] |
| K2O (g) | -63[1] | – | – | – |
| (cr) | 0[1] | 0[1] | 116.135[1] | 54.438[1] |
| (g) | 62.438[1] | 19.327[1] | 260.69[1] | 36.90[1] |
| (ao) | 22.6[1] | 16.40[1] | 137.2[1] | – |
| (cr) hexagonal, gray | 0[1] | 0[1] | 42.442[1] | 25.363[1] |
| (cr) monoclinic, red | 6.7[1] | – | – | – |
| (vit) | 5.0[1] | – | – | – |
| (g) | 227.07[1] | 187.03[1] | 176.72[1] | 20.820[1] |
| CaO (cr) | -635.09[1] | -604.03[1] | 39.75[1] | 42.80[1] |
| CaO (g) | – | – | – | – |
* (cr):Crystalline solid, (g):Gas, (ao):Un-ionized aqueous solution, (vit):Vitreous liquid
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -327.900 kJ · mol−1
- ^ ΔfG°, -324.892 kJ · mol−1
- ^ S°, 106.32 J · K−1 · mol−1
- ^ Cp°, 52.93 J · K−1 · mol−1
- ^ ΔfH°, -125.5 kJ · mol−1
- ^ ΔfG°, -166.1 kJ · mol−1
- ^ S°, 258.3 J · K−1 · mol−1
- ^ Cp°, 37.11 J · K−1 · mol−1
- ^ ΔfH°, -307.57 kJ · mol−1
- ^ ΔfG°, -334.85 kJ · mol−1
- ^ S°, 213.8 J · K−1 · mol−1
- ^ Cp°, -120.5 J · K−1 · mol−1
- ^ ΔfH°, -1109.81 kJ · mol−1
- ^ ΔfH°, -1706.7 kJ · mol−1
- ^ ΔfG°, -1486.8 kJ · mol−1
- ^ S°, 222. J · K−1 · mol−1
- ^ ΔfH°, -361.5 kJ · mol−1
- ^ ΔfH°, -63. kJ · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 116.135 J · K−1 · mol−1
- ^ Cp°, 54.438 J · K−1 · mol−1
- ^ ΔfH°, 62.438 kJ · mol−1
- ^ ΔfG°, 19.327 kJ · mol−1
- ^ S°, 260.69 J · K−1 · mol−1
- ^ Cp°, 36.90 J · K−1 · mol−1
- ^ ΔfH°, 22.6 kJ · mol−1
- ^ ΔfG°, 16.40 kJ · mol−1
- ^ S°, 137.2 J · K−1 · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 42.442 J · K−1 · mol−1
- ^ Cp°, 25.363 J · K−1 · mol−1
- ^ ΔfH°, 6.7 kJ · mol−1
- ^ ΔfH°, 5.0 kJ · mol−1
- ^ ΔfH°, 227.07 kJ · mol−1
- ^ ΔfG°, 187.03 kJ · mol−1
- ^ S°, 176.72 J · K−1 · mol−1
- ^ Cp°, 20.820 J · K−1 · mol−1
- ^ ΔfH°, -635.09 kJ · mol−1
- ^ ΔfG°, -604.03 kJ · mol−1
- ^ S°, 39.75 J · K−1 · mol−1
- ^ Cp°, 42.80 J · K−1 · mol−1
- 2James G. Speight (2017)Lange's Handbook of Chemistry, 17th editionMcGraw Hill Education
- ^ ΔfG°, -322.1 kJ · mol−1 - p.280
- ^ S°, 94.1 J · K−1 · mol−1 - p.280
- ^ Cp°, 83.7 J · K−1 · mol−1 - p.280