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  3. 73NaCl + 53CsClO3 + 24H^+ ๐Ÿ”ฅโ†’ 49NaClO3 + 24Na^+ + 12Cl2โ†‘ + 53CsCl + 12H2O

73NaCl + 53CsClO3 + 24H+ ๐Ÿ”ฅโ†’ 49NaClO3 + 24Na+ + 12Cl2โ†‘ + 53CsCl + 12H2O

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Reaction of sodium chloride and caesium chlorate under acidic condition
73NaClSodium chloride + 53CsClO3Caesium chlorate + 24H+Hydrogen ion
๐Ÿ”ฅ
โŸถ
49NaClO3Sodium chlorate + 24Na+Sodium ion + 12Cl2โ†‘Chlorine + 53CsClCaesium chloride + 12H2OWater

The reaction of sodium chloride, caesium chlorate, and hydrogen ion yields sodium chlorate, sodium ion, chlorine, caesium chloride, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

Reaction of sodium chloride and caesium chlorate under acidic condition
73NaClSodium chloride + 53CsClO3Caesium chlorate + 24H+Hydrogen ion
๐Ÿ”ฅ
โŸถ
49NaClO3Sodium chlorate + 24Na+Sodium ion + 12Cl2โ†‘Chlorine + 53CsClCaesium chloride + 12H2OWater

General equation

Reaction of hardly oxidizable species and oxidizing species under acidic condition
Hardly oxidizable speciesReducing agent + Oxidizing speciesOxidizing agent + H+Non-redox agent
โŸถ
ProductOxidation product + ProductReduction product + H2ONon-redox product

Oxidation state of each atom

Reaction of sodium chloride and caesium chlorate under acidic condition

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
NaClSodium chloride73
Reducing
Hardly oxidizable
CsClO3Caesium chlorate53
Oxidizing
Oxidizing under acidic condition
H+Hydrogen ion24
โ€“
Hydrogen ion

Products

Chemical formulaNameCoefficientTypeType in general
equation
NaClO3Sodium chlorate49
โ€“
โ€“
Na+Sodium ion24
โ€“
โ€“
Cl2Chlorine12
Redoxed product
โ€“
CsClCaesium chloride53
โ€“
โ€“
H2OWater12
โ€“
Water

Thermodynamic changes

Changes in standard condition (1)

Reaction of sodium chloride and caesium chlorate under acidic condition
โ—†
ฮ”rGโˆ’188.03 kJ/mol
K8.74 ร— 1032
pKโˆ’32.94
73NaClIonized aqueous solution + 53CsClO3Ionized aqueous solution + 24H+Un-ionized aqueous solution
๐Ÿ”ฅ
โŸถ
49NaClO3Ionized aqueous solution + 24Na+Un-ionized aqueous solution + 12Cl2โ†‘Gas + 53CsClIonized aqueous solution + 12H2OLiquid
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
328.92โˆ’188.031733.3โ€“
per 1 mol of
4.5058โˆ’2.575823.744โ€“
per 1 mol of
6.2060โˆ’3.547732.704โ€“
per 1 mol of
Hydrogen ion
13.705โˆ’7.834672.221โ€“
per 1 mol of
6.7127โˆ’3.837335.373โ€“
per 1 mol of
Sodium ion
13.705โˆ’7.834672.221โ€“
per 1 mol of
27.410โˆ’15.669144.44โ€“
per 1 mol of
6.2060โˆ’3.547732.704โ€“
per 1 mol of
27.410โˆ’15.669144.44โ€“

Changes in standard condition (2)

Reaction of sodium chloride and caesium chlorate under acidic condition
โ—†
ฮ”rGโˆ’104.75 kJ/mol
K2.25 ร— 1018
pKโˆ’18.35
73NaClIonized aqueous solution + 53CsClO3Ionized aqueous solution + 24H+Un-ionized aqueous solution
๐Ÿ”ฅ
โŸถ
49NaClO3Ionized aqueous solution + 24Na+Un-ionized aqueous solution + 12Cl2โ†‘Un-ionized aqueous solution + 53CsClIonized aqueous solution + 12H2OLiquid
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
48.1โˆ’104.75509โ€“
per 1 mol of
0.659โˆ’1.43496.97โ€“
per 1 mol of
0.908โˆ’1.97649.60โ€“
per 1 mol of
Hydrogen ion
2.00โˆ’4.364621.2โ€“
per 1 mol of
0.982โˆ’2.137810.4โ€“
per 1 mol of
Sodium ion
2.00โˆ’4.364621.2โ€“
per 1 mol of
4.01โˆ’8.729242.4โ€“
per 1 mol of
0.908โˆ’1.97649.60โ€“
per 1 mol of
4.01โˆ’8.729242.4โ€“

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ฮ”fHยฐ
kJ ยท molโˆ’1		Standard Gibbs
energy of
formation
ฮ”fGยฐ
kJ ยท molโˆ’1		Standard
molar entropy
Sยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard molar
heat capacity at
constant pressure
Cpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
NaCl (cr)-411.153[1]-384.138[1]72.13[1]50.50[1]
NaCl (g)-176.65[1]-196.66[1]229.81[1]35.77[1]
NaCl (ai)-407.27[1]-393.133[1]115.5[1]-90.0[1]
CsClO3 (cr)-411.7[1]-307.9[1]156.1[1]โ€“
CsClO3 (ai)-362.25[1]-299.97[1]295.4[1]โ€“
H+ (g)1536.202[1]โ€“โ€“โ€“
H+ (ao)0[1]0[1]0[1]0[1]
* (cr):Crystalline solid, (g):Gas, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ฮ”fHยฐ
kJ ยท molโˆ’1		Standard Gibbs
energy of
formation
ฮ”fGยฐ
kJ ยท molโˆ’1		Standard
molar entropy
Sยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard molar
heat capacity at
constant pressure
Cpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
NaClO3 (cr)-365.774[1]-262.259[1]123.4[1]โ€“
NaClO3 (ai)-344.09[1]-269.84[1]221.3[1]โ€“
Na+ (g)609.358[1]โ€“โ€“โ€“
Na+ (ao)-240.12[1]-261.905[1]59.0[1]46.4[1]
Cl2 (g)0[1]0[1]223.066[1]33.907[1]
Cl2 (ao)-23.4[1]6.94[1]121[1]โ€“
CsCl (cr)-443.04[1]-414.53[1]101.17[1]52.47[1]
CsCl (g)-240.20[1]-257.80[1]255.96[1]36.94[1]
CsCl (ai)-425.43[1]-423.24[1]189.54[1]-146.9[1]
H2O (cr)โ€“โ€“โ€“โ€“
H2O (l)-285.830[1]-237.129[1]69.91[1]75.291[1]
H2O (g)-241.818[1]-228.572[1]188.825[1]33.577[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (g):Gas, (ao):Un-ionized aqueous solution, (l):Liquid

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)