8H2S + 6CsNO3 → 5H2SO3 + 3N2 + 3Cs2S + 3H2O
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- Reaction of hydrogen sulfide and caesium nitrate
The reaction of hydrogen sulfide and caesium nitrate yields sulfurous acid, , caesium sulfide, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of hydrogen sulfide and caesium nitrate
General equation
- Reaction of reducing species and oxidizing species
- Reducing speciesReducing agent + Oxidizing speciesOxidizing agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of hydrogen sulfide and caesium nitrate
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| H2S | Hydrogen sulfide | 8 | Reducing | Reducing |
| CsNO3 | Caesium nitrate | 6 | Oxidizing | Oxidizing |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| H2SO3 | Sulfurous acid | 5 | Oxidized | – |
| 3 | Reduced | – | ||
| Cs2S | Caesium sulfide | 3 | – | – |
| H2O | Water | 3 | – | – |
Thermodynamic changes
Changes in standard condition
- Reaction of hydrogen sulfide and caesium nitrate◆
ΔrG −2253.1 kJ/mol K 5.32 × 10394 pK −394.73
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | −2241.2 | −2253.1 | 55 | – |
per 1 mol of | −280.15 | −281.64 | 6.9 | – |
per 1 mol of | −373.53 | −375.52 | 9.2 | – |
per 1 mol of | −448.24 | −450.62 | 11 | – |
| −747.07 | −751.03 | 18 | – | |
per 1 mol of | −747.07 | −751.03 | 18 | – |
per 1 mol of | −747.07 | −751.03 | 18 | – |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| H2S (g) | -20.63[1] | -33.56[1] | 205.79[1] | 34.23[1] |
| H2S (ao) | -39.7[1] | -27.83[1] | 121[1] | – |
| CsNO3 (cr) | -505.97[1] | -406.54[1] | 155.2[1] | – |
| CsNO3 (g) | -374.0[1] | – | – | – |
| CsNO3 (ai) | -465.64[1] | -403.27[1] | 279.5[1] | -99[1] |
* (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid, (ai):Ionized aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| H2SO3 (ao) | -608.81[1] | -537.81[1] | 232.2[1] | – |
| (g) | 0[1] | 0[1] | 191.61[1] | 29.125[1] |
| Cs2S (cr) | -359.8[1] | – | – | – |
| Cs2S (ai) | -483.7[1] | -498.3[1] | 251.5[1] | – |
| H2O (cr) | – | – | – | – |
| H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
| H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
* (ao):Un-ionized aqueous solution, (g):Gas, (cr):Crystalline solid, (ai):Ionized aqueous solution, (l):Liquid
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -20.63 kJ · mol−1
- ^ ΔfG°, -33.56 kJ · mol−1
- ^ S°, 205.79 J · K−1 · mol−1
- ^ Cp°, 34.23 J · K−1 · mol−1
- ^ ΔfH°, -39.7 kJ · mol−1
- ^ ΔfG°, -27.83 kJ · mol−1
- ^ S°, 121. J · K−1 · mol−1
- ^ ΔfH°, -505.97 kJ · mol−1
- ^ ΔfG°, -406.54 kJ · mol−1
- ^ S°, 155.2 J · K−1 · mol−1
- ^ ΔfH°, -374.0 kJ · mol−1
- ^ ΔfH°, -465.64 kJ · mol−1
- ^ ΔfG°, -403.27 kJ · mol−1
- ^ S°, 279.5 J · K−1 · mol−1
- ^ Cp°, -99. J · K−1 · mol−1
- ^ ΔfH°, -608.81 kJ · mol−1
- ^ ΔfG°, -537.81 kJ · mol−1
- ^ S°, 232.2 J · K−1 · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 191.61 J · K−1 · mol−1
- ^ Cp°, 29.125 J · K−1 · mol−1
- ^ ΔfH°, -359.8 kJ · mol−1
- ^ ΔfH°, -483.7 kJ · mol−1
- ^ ΔfG°, -498.3 kJ · mol−1
- ^ S°, 251.5 J · K−1 · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1