8NaClO + 6RbOH 🔥→ 2NaClO4 + 3Na2O + 6RbCl + 3H2O
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The reaction of sodium hypochlorite and rubidium hydroxide yields sodium perchlorate, sodium oxide, rubidium chloride, and water (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of sodium hypochlorite and rubidium hydroxide
General equation
- Reaction of self redoxing species and base
- Self-redoxing speciesSelf redox agent + BaseNon-redox agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of sodium hypochlorite and rubidium hydroxide
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| NaClO | Sodium hypochlorite | 8 | – | Self redoxing |
| RbOH | Rubidium hydroxide | 6 | – | Base |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| NaClO4 | Sodium perchlorate | 2 | Oxidized | – |
| Na2O | Sodium oxide | 3 | – | – |
| RbCl | Rubidium chloride | 6 | Reduced | – |
| H2O | Water | 3 | – | – |
Thermodynamic changes
Changes in standard condition
- Reaction of sodium hypochlorite and rubidium hydroxide◆
ΔrG 167.1 kJ/mol K 0.53 × 10−29 pK 29.27
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 316.4 | 167.1 | 520 | – |
per 1 mol of | 39.55 | 20.89 | 65.0 | – |
per 1 mol of | 52.73 | 27.85 | 86.7 | – |
per 1 mol of | 158.2 | 83.55 | 260 | – |
per 1 mol of | 105.5 | 55.70 | 173 | – |
per 1 mol of | 52.73 | 27.85 | 86.7 | – |
per 1 mol of | 105.5 | 55.70 | 173 | – |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| NaClO (ai) | -347.3[1] | -298.7[1] | 100[1] | – |
| RbOH (cr) | -418.19[1] | – | – | – |
| RbOH (g) | -238[1] | – | – | – |
| RbOH (ai) | -481.16[1] | -441.21[1] | 110.75[1] | – |
| RbOH (cr) 1 hydrate | -748.85[1] | – | – | – |
| RbOH (cr) 2 hydrate | -1053.24[1] | – | – | – |
* (ai):Ionized aqueous solution, (cr):Crystalline solid, (g):Gas
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| NaClO4 (cr) | -383.30[1] | -254.85[1] | 142.3[1] | – |
| NaClO4 (ai) | -369.45[1] | -270.41[1] | 241.0[1] | – |
| NaClO4 (cr) 1 hydrate | -677.77[1] | -494.29[1] | 190.8[1] | – |
| Na2O (cr) | -414.22[1] | -375.46[1] | 75.06[1] | 69.12[1] |
| Na2O (g) | -35.6[1] | -52.3[1] | 261.2[1] | 55.2[1] |
| RbCl (cr) | -435.35[1] | -407.80[1] | 95.90[1] | 52.38[1] |
| RbCl (g) | -228.9[1] | -247.3[1] | 249.56[1] | 36.82[1] |
| RbCl (ai) | -418.32[1] | -415.20[1] | 177.99[1] | – |
| H2O (cr) | – | – | – | – |
| H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
| H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (g):Gas, (l):Liquid
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -347.3 kJ · mol−1
- ^ ΔfG°, -298.7 kJ · mol−1
- ^ S°, 100. J · K−1 · mol−1
- ^ ΔfH°, -418.19 kJ · mol−1
- ^ ΔfH°, -238. kJ · mol−1
- ^ ΔfH°, -481.16 kJ · mol−1
- ^ ΔfG°, -441.21 kJ · mol−1
- ^ S°, 110.75 J · K−1 · mol−1
- ^ ΔfH°, -748.85 kJ · mol−1
- ^ ΔfH°, -1053.24 kJ · mol−1
- ^ ΔfH°, -383.30 kJ · mol−1
- ^ ΔfG°, -254.85 kJ · mol−1
- ^ S°, 142.3 J · K−1 · mol−1
- ^ ΔfH°, -369.45 kJ · mol−1
- ^ ΔfG°, -270.41 kJ · mol−1
- ^ S°, 241.0 J · K−1 · mol−1
- ^ ΔfH°, -677.77 kJ · mol−1
- ^ ΔfG°, -494.29 kJ · mol−1
- ^ S°, 190.8 J · K−1 · mol−1
- ^ ΔfH°, -414.22 kJ · mol−1
- ^ ΔfG°, -375.46 kJ · mol−1
- ^ S°, 75.06 J · K−1 · mol−1
- ^ Cp°, 69.12 J · K−1 · mol−1
- ^ ΔfH°, -35.6 kJ · mol−1
- ^ ΔfG°, -52.3 kJ · mol−1
- ^ S°, 261.2 J · K−1 · mol−1
- ^ Cp°, 55.2 J · K−1 · mol−1
- ^ ΔfH°, -435.35 kJ · mol−1
- ^ ΔfG°, -407.80 kJ · mol−1
- ^ S°, 95.90 J · K−1 · mol−1
- ^ Cp°, 52.38 J · K−1 · mol−1
- ^ ΔfH°, -228.9 kJ · mol−1
- ^ ΔfG°, -247.3 kJ · mol−1
- ^ S°, 249.56 J · K−1 · mol−1
- ^ Cp°, 36.82 J · K−1 · mol−1
- ^ ΔfH°, -418.32 kJ · mol−1
- ^ ΔfG°, -415.20 kJ · mol−1
- ^ S°, 177.99 J · K−1 · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1