9H2 + Pb(CH3COO)2 → Pb + 4H2O + 4CH4
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- Reaction of and lead(II) acetate
The reaction of and lead(II) acetate yields , water, and (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of and lead(II) acetate
General equation
- Reaction of reducing species and reducible species
- Reducing speciesReducing agent + Reducible speciesOxidizing agent ⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of and lead(II) acetate
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
9 | Reducing | Reducing | ||
Pb(CH3COO)2 | Lead(II) acetate | 1 | Oxidizing | Reducible |
Products
Thermodynamic changes
Changes in standard condition
- Reaction of and lead(II) acetate
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −478.73 | – | – | – |
−53.192 | – | – | – | |
per 1 mol of | −478.73 | – | – | – |
−478.73 | – | – | – | |
per 1 mol of | −119.68 | – | – | – |
−119.68 | – | – | – |
Changes in aqueous solution (1)
- Reaction of and lead(II) acetate◆
ΔrG −546.8 kJ/mol K 6.24 × 1095 pK −95.80 - 9Un-ionized aqueous solution + Pb(CH3COO)2Ionized aqueous solutionCrystalline solid + 4H2OLiquid + 4Gas⟶
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −431.2 | −546.8 | −4286 | – |
−47.91 | −60.76 | −476.2 | – | |
per 1 mol of | −431.2 | −546.8 | −4286 | – |
−431.2 | −546.8 | −4286 | – | |
per 1 mol of | −107.8 | −136.7 | −1072 | – |
−107.8 | −136.7 | −1072 | – |
Changes in aqueous solution (2)
- Reaction of and lead(II) acetate◆
ΔrG −481.2 kJ/mol K 2.01 × 1084 pK −84.30 - 9Un-ionized aqueous solution + Pb(CH3COO)2Ionized aqueous solutionCrystalline solid + 4H2OLiquid + 4Un-ionized aqueous solution⟶
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | −488.1 | −481.2 | −4697 | – |
−54.23 | −53.47 | −521.9 | – | |
per 1 mol of | −488.1 | −481.2 | −4697 | – |
−488.1 | −481.2 | −4697 | – | |
per 1 mol of | −122.0 | −120.3 | −1174 | – |
−122.0 | −120.3 | −1174 | – |
Changes in aqueous solution (3)
- Reaction of and lead(II) acetate◆
ΔrG −530.1 kJ/mol K 7.40 × 1092 pK −92.87 - 9Un-ionized aqueous solution + Pb(CH3COO)2Un-ionized aqueous solutionCrystalline solid + 4H2OLiquid + 4Gas⟶
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | −530.1 | – | – |
– | −58.90 | – | – | |
per 1 mol of | – | −530.1 | – | – |
– | −530.1 | – | – | |
per 1 mol of | – | −132.5 | – | – |
– | −132.5 | – | – |
Changes in aqueous solution (4)
- Reaction of and lead(II) acetate◆
ΔrG −464.5 kJ/mol K 2.38 × 1081 pK −81.38 - 9Un-ionized aqueous solution + Pb(CH3COO)2Un-ionized aqueous solutionCrystalline solid + 4H2OLiquid + 4Un-ionized aqueous solution⟶
Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
---|---|---|---|---|
per 1 mol of Equation | – | −464.5 | – | – |
– | −51.61 | – | – | |
per 1 mol of | – | −464.5 | – | – |
– | −464.5 | – | – | |
per 1 mol of | – | −116.1 | – | – |
– | −116.1 | – | – |
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
(g) | 0[1] | 0[1] | 130.684[1] | 28.824[1] |
(ao) | -4.2[1] | 17.6[1] | 577[1] | – |
Pb(CH3COO)2 (cr) | -963.83[1] | – | – | – |
Pb(CH3COO)2 (ai) | -973.6[1] | -763.04[1] | 182.8[1] | – |
Pb(CH3COO)2 (ao) | – | -779.7[1] | – | – |
Pb(CH3COO)2 (cr) 3 hydrate | -1851.50[1] | – | – | – |
* (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid, (ai):Ionized aqueous solution
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
(cr) | 0[1] | 0[1] | 64.81[1] | 26.44[1] |
(g) | 195.0[1] | 161.9[1] | 175.373[1] | 20.786[1] |
H2O (cr) | – | – | – | – |
H2O (l) | -285.830[1] | -237.129[1] | 69.91[1] | 75.291[1] |
H2O (g) | -241.818[1] | -228.572[1] | 188.825[1] | 33.577[1] |
(g) | -74.81[1] | -50.72[1] | 186.264[1] | 35.309[1] |
(ao) | -89.04[1] | -34.33[1] | 83.7[1] | – |
* (cr):Crystalline solid, (g):Gas, (l):Liquid, (ao):Un-ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 130.684 J · K−1 · mol−1
- ^ Cp°, 28.824 J · K−1 · mol−1
- ^ ΔfH°, -4.2 kJ · mol−1
- ^ ΔfG°, 17.6 kJ · mol−1
- ^ S°, 577 J · K−1 · mol−1
- ^ ΔfH°, -963.83 kJ · mol−1
- ^ ΔfH°, -973.6 kJ · mol−1
- ^ ΔfG°, -763.04 kJ · mol−1
- ^ S°, 182.8 J · K−1 · mol−1
- ^ ΔfG°, -779.7 kJ · mol−1
- ^ ΔfH°, -1851.50 kJ · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 64.81 J · K−1 · mol−1
- ^ Cp°, 26.44 J · K−1 · mol−1
- ^ ΔfH°, 195.0 kJ · mol−1
- ^ ΔfG°, 161.9 kJ · mol−1
- ^ S°, 175.373 J · K−1 · mol−1
- ^ Cp°, 20.786 J · K−1 · mol−1
- ^ ΔfH°, -285.830 kJ · mol−1
- ^ ΔfG°, -237.129 kJ · mol−1
- ^ S°, 69.91 J · K−1 · mol−1
- ^ Cp°, 75.291 J · K−1 · mol−1
- ^ ΔfH°, -241.818 kJ · mol−1
- ^ ΔfG°, -228.572 kJ · mol−1
- ^ S°, 188.825 J · K−1 · mol−1
- ^ Cp°, 33.577 J · K−1 · mol−1
- ^ ΔfH°, -74.81 kJ · mol−1
- ^ ΔfG°, -50.72 kJ · mol−1
- ^ S°, 186.264 J · K−1 · mol−1
- ^ Cp°, 35.309 J · K−1 · mol−1
- ^ ΔfH°, -89.04 kJ · mol−1
- ^ ΔfG°, -34.33 kJ · mol−1
- ^ S°, 83.7 J · K−1 · mol−1