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9H2 + Pb(CH3COO)2 → Pb + 4H2O + 4CH4

The reaction of hydrogen and lead(II) acetate yields lead, water, and methane (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

General equation

Reaction of reducing species and reducible species
Reducing speciesReducing agent + Reducible speciesOxidizing agent
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Reaction of hydrogen and lead(II) acetate

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
H2Hydrogen9
Reducing
Reducing
Pb(CH3COO)2Lead(II) acetate1
Oxidizing
Reducible

Products

Chemical formulaNameCoefficientTypeType in general
equation
PbLead1
Reduced
H2OWater4
Oxidized
CH4Methane4
Redoxed product

Thermodynamic changes

Changes in standard condition

Reaction of hydrogen and lead(II) acetate
9H2Gas + Pb(CH3COO)2Crystalline solid
PbCrystalline solid + 4H2OLiquid + 4CH4Gas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−478.73
per 1 mol of
−53.192
per 1 mol of
−478.73
per 1 mol of
−478.73
per 1 mol of
−119.68
per 1 mol of
−119.68

Changes in aqueous solution (1)

Reaction of hydrogen and lead(II) acetate
ΔrG−546.8 kJ/mol
K6.24 × 1095
pK−95.80
9H2Un-ionized aqueous solution + Pb(CH3COO)2Ionized aqueous solution
PbCrystalline solid + 4H2OLiquid + 4CH4Gas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−431.2−546.8−4286
per 1 mol of
−47.91−60.76−476.2
per 1 mol of
−431.2−546.8−4286
per 1 mol of
−431.2−546.8−4286
per 1 mol of
−107.8−136.7−1072
per 1 mol of
−107.8−136.7−1072

Changes in aqueous solution (2)

Reaction of hydrogen and lead(II) acetate
ΔrG−481.2 kJ/mol
K2.01 × 1084
pK−84.30
9H2Un-ionized aqueous solution + Pb(CH3COO)2Ionized aqueous solution
PbCrystalline solid + 4H2OLiquid + 4CH4Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−488.1−481.2−4697
per 1 mol of
−54.23−53.47−521.9
per 1 mol of
−488.1−481.2−4697
per 1 mol of
−488.1−481.2−4697
per 1 mol of
−122.0−120.3−1174
per 1 mol of
−122.0−120.3−1174

Changes in aqueous solution (3)

Reaction of hydrogen and lead(II) acetate
ΔrG−530.1 kJ/mol
K7.40 × 1092
pK−92.87
9H2Un-ionized aqueous solution + Pb(CH3COO)2Un-ionized aqueous solution
PbCrystalline solid + 4H2OLiquid + 4CH4Gas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−530.1
per 1 mol of
−58.90
per 1 mol of
−530.1
per 1 mol of
−530.1
per 1 mol of
−132.5
per 1 mol of
−132.5

Changes in aqueous solution (4)

Reaction of hydrogen and lead(II) acetate
ΔrG−464.5 kJ/mol
K2.38 × 1081
pK−81.38
9H2Un-ionized aqueous solution + Pb(CH3COO)2Un-ionized aqueous solution
PbCrystalline solid + 4H2OLiquid + 4CH4Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1
Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1
Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1
Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
−464.5
per 1 mol of
−51.61
per 1 mol of
−464.5
per 1 mol of
−464.5
per 1 mol of
−116.1
per 1 mol of
−116.1

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
H2 (g)0[1]0[1]130.684[1]28.824[1]
H2 (ao)-4.2[1]17.6[1]577[1]
Pb(CH3COO)2 (cr)-963.83[1]
Pb(CH3COO)2 (ai)-973.6[1]-763.04[1]182.8[1]
Pb(CH3COO)2 (ao)-779.7[1]
Pb(CH3COO)2 (cr)
3 hydrate
-1851.50[1]
* (g):Gas, (ao):Un-ionized aqueous solution, (cr):Crystalline solid, (ai):Ionized aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1
Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1
Standard
molar entropy
S°
J · K−1 · mol−1
Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
Pb (cr)0[1]0[1]64.81[1]26.44[1]
Pb (g)195.0[1]161.9[1]175.373[1]20.786[1]
H2O (cr)
H2O (l)-285.830[1]-237.129[1]69.91[1]75.291[1]
H2O (g)-241.818[1]-228.572[1]188.825[1]33.577[1]
CH4 (g)-74.81[1]-50.72[1]186.264[1]35.309[1]
CH4 (ao)-89.04[1]-34.33[1]83.7[1]
* (cr):Crystalline solid, (g):Gas, (l):Liquid, (ao):Un-ionized aqueous solution

References

List of references

  1. 1