9FeO + Na2[Sn(OH)6] 🔥→ 2Fe3O4 + Sn + Na2O + 3Fe(OH)2
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The reaction of iron(II) oxide and sodium hexahydroxidostannate(IV) yields iron(II,III) oxide, , sodium oxide, and iron(II) hydroxide (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Reaction of iron(II) oxide and sodium hexahydroxidostannate(IV)
General equation
- Reaction of oxidizable species and reducible species
- Oxidizable speciesReducing agent + Reducible speciesOxidizing agent🔥⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Reaction of iron(II) oxide and sodium hexahydroxidostannate(IV)
Reactants
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
FeO | Iron(II) oxide | 9 | Reducing | Oxidizable |
Na2[Sn(OH)6] | Sodium hexahydroxidostannate(IV) | 1 | Oxidizing | Reducible |
Products
Chemical formula | Name | Coefficient | Type | Type in general equation |
---|---|---|---|---|
Fe3O4 | Iron(II,III) oxide | 2 | Oxidized | – |
1 | Reduced | – | ||
Na2O | Sodium oxide | 1 | – | – |
Fe(OH)2 | Iron(II) hydroxide | 3 | – | – |
Thermodynamic changes
Thermodynamic data of reactants
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
FeO (cr) | -272.0[1] | – | – | – |
Na2[Sn(OH)6] | – | – | – | – |
* (cr):Crystalline solid
Thermodynamic data of products
Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
---|---|---|---|---|
Fe3O4 (cr) | -1118.4[1] | -1015.4[1] | 146.4[1] | 143.43[1] |
(cr) white | 0[1] | 0[1] | 51.55[1] | 26.99[1] |
(cr) gray | -2.09[1] | 0.13[1] | 44.14[1] | 25.77[1] |
(g) | 302.1[1] | 267.3[1] | 168.486[1] | 21.259[1] |
Na2O (cr) | -414.22[1] | -375.46[1] | 75.06[1] | 69.12[1] |
Na2O (g) | -35.6[1] | -52.3[1] | 261.2[1] | 55.2[1] |
Fe(OH)2 (cr) precipitated | -569.0[1] | -486.5[1] | 88[1] | – |
Fe(OH)2 (g) | -372[1] | – | – | – |
* (cr):Crystalline solid, (g):Gas
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -272.0 kJ · mol−1
- ^ ΔfH°, -1118.4 kJ · mol−1
- ^ ΔfG°, -1015.4 kJ · mol−1
- ^ S°, 146.4 J · K−1 · mol−1
- ^ Cp°, 143.43 J · K−1 · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 51.55 J · K−1 · mol−1
- ^ Cp°, 26.99 J · K−1 · mol−1
- ^ ΔfH°, -2.09 kJ · mol−1
- ^ ΔfG°, 0.13 kJ · mol−1
- ^ S°, 44.14 J · K−1 · mol−1
- ^ Cp°, 25.77 J · K−1 · mol−1
- ^ ΔfH°, 302.1 kJ · mol−1
- ^ ΔfG°, 267.3 kJ · mol−1
- ^ S°, 168.486 J · K−1 · mol−1
- ^ Cp°, 21.259 J · K−1 · mol−1
- ^ ΔfH°, -414.22 kJ · mol−1
- ^ ΔfG°, -375.46 kJ · mol−1
- ^ S°, 75.06 J · K−1 · mol−1
- ^ Cp°, 69.12 J · K−1 · mol−1
- ^ ΔfH°, -35.6 kJ · mol−1
- ^ ΔfG°, -52.3 kJ · mol−1
- ^ S°, 261.2 J · K−1 · mol−1
- ^ Cp°, 55.2 J · K−1 · mol−1
- ^ ΔfH°, -569.0 kJ · mol−1
- ^ ΔfG°, -486.5 kJ · mol−1
- ^ S°, 88. J · K−1 · mol−1
- ^ ΔfH°, -372. kJ · mol−1