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  3. 10NH4CN + 14H2O 💧⚡→ 4NO↑ + 5CH3COONH4 + 11NH3↑

10NH4CN + 14H2O 💧⚡→ 4NO↑ + 5CH3COONH4 + 11NH3↑

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Electrolysis of aqueous ammonium cyanide with water as non-redox agent
10NH4CNAmmonium cyanide + 14H2OWater
💧⚡
⟶
4NO↑Nitrogen monoxide + 5CH3COONH4Ammonium acetate + 11NH3↑Ammonia

Electrolysis of aqueous ammonium cyanide yields nitrogen monoxide, ammonium acetate, and ammonia (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

Electrolysis of aqueous ammonium cyanide with water as non-redox agent
10NH4CNAmmonium cyanide + 14H2OWater
💧⚡
⟶
4NO↑Nitrogen monoxide + 5CH3COONH4Ammonium acetate + 11NH3↑Ammonia

General equation

Electrolysis of aqueous solution with water as non redox agent
Miscible with water/Very soluble in water/Soluble in waterSelf redox agent + H2ONon-redox agent
💧⚡
⟶
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Electrolysis of aqueous ammonium cyanide with water as non-redox agent

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
NH4CNAmmonium cyanide10
Reducing
Very soluble in water
H2OWater14
–
Water

Products

Chemical formulaNameCoefficientTypeType in general
equation
NONitrogen monoxide4
Oxidized
–
CH3COONH4Ammonium acetate5
Redoxed product
–
NH3Ammonia11
–
–

Thermodynamic changes

Changes in standard condition

Electrolysis of aqueous ammonium cyanide with water as non-redox agent
10NH4CNCrystalline solid + 14H2OLiquid
💧⚡
⟶
4NO↑Gas + 5CH3COONH4Crystalline solid + 11NH3↑Gas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
770.51–––
per 1 mol of
77.051–––
per 1 mol of
55.036–––
per 1 mol of
192.63–––
per 1 mol of
154.10–––
per 1 mol of
70.046–––

Changes in aqueous solution (1)

Electrolysis of aqueous ammonium cyanide with water as non-redox agent
◆
ΔrG312.0 kJ/mol
K0.22 × 10−54
pK54.66
10NH4CNIonized aqueous solution + 14H2OLiquid
💧⚡
⟶
4NO↑Gas + 5CH3COONH4Ionized aqueous solution + 11NH3↑Gas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
582.8312.0906.3–
per 1 mol of
58.2831.2090.63–
per 1 mol of
41.6322.2964.74–
per 1 mol of
145.778.00226.6–
per 1 mol of
116.662.40181.3–
per 1 mol of
52.9828.3682.39–

Changes in aqueous solution (2)

Electrolysis of aqueous ammonium cyanide with water as non-redox agent
◆
ΔrG201.5 kJ/mol
K0.50 × 10−35
pK35.30
10NH4CNIonized aqueous solution + 14H2OLiquid
💧⚡
⟶
4NO↑Gas + 5CH3COONH4Ionized aqueous solution + 11NH3↑Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
206.8201.513.6–
per 1 mol of
20.6820.151.36–
per 1 mol of
14.7714.390.971–
per 1 mol of
51.7050.383.40–
per 1 mol of
41.3640.302.72–
per 1 mol of
18.8018.321.24–

Changes in aqueous solution (3)

Electrolysis of aqueous ammonium cyanide with water as non-redox agent
10NH4CNAqueous solution + 14H2OLiquid
💧⚡
⟶
4NO↑Gas + 5CH3COONH4Ionized aqueous solution + 11NH3↑Gas
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
440.8–––
per 1 mol of
44.08–––
per 1 mol of
31.49–––
per 1 mol of
110.2–––
per 1 mol of
88.16–––
per 1 mol of
40.07–––

Changes in aqueous solution (4)

Electrolysis of aqueous ammonium cyanide with water as non-redox agent
10NH4CNAqueous solution + 14H2OLiquid
💧⚡
⟶
4NO↑Gas + 5CH3COONH4Ionized aqueous solution + 11NH3↑Un-ionized aqueous solution
Standard enthalpy
of reaction
ΔrH°
kJ · mol−1		Standard
Gibbs energy
of reaction
ΔrG°
kJ · mol−1		Standard entropy
of reaction
ΔrS°
J · K−1 · mol−1		Standard heat
capacity of reaction
at constant pressure
ΔrCp°
J · K−1 · mol−1
per 1 mol of
Equation
64.8–––
per 1 mol of
6.48–––
per 1 mol of
4.63–––
per 1 mol of
16.2–––
per 1 mol of
13.0–––
per 1 mol of
5.89–––

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1		Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1		Standard
molar entropy
S°
J · K−1 · mol−1		Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NH4CN (cr)0.42[1]––134[1]
NH4CN (ai)18.0[1]93.0[1]207.5[1]–
NH4CN (aq)32.2[1]–––
H2O (cr)––––
H2O (l)-285.830[1]-237.129[1]69.91[1]75.291[1]
H2O (g)-241.818[1]-228.572[1]188.825[1]33.577[1]
* (cr):Crystalline solid, (ai):Ionized aqueous solution, (aq):Aqueous solution, (l):Liquid, (g):Gas

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ΔfH°
kJ · mol−1		Standard Gibbs
energy of
formation
ΔfG°
kJ · mol−1		Standard
molar entropy
S°
J · K−1 · mol−1		Standard molar
heat capacity at
constant pressure
Cp°
J · K−1 · mol−1
NO (g)90.25[1]86.55[1]210.761[1]29.844[1]
CH3COONH4 (cr)-616.14[1]–––
CH3COONH4 (ai)-618.52[1]-448.61[1]200.0[1]73.6[1]
NH3 (g)-46.11[1]-16.45[1]192.45[1]35.06[1]
NH3 (ao)-80.29[1]-26.50[1]111.3[1]–
* (g):Gas, (cr):Crystalline solid, (ai):Ionized aqueous solution, (ao):Un-ionized aqueous solution

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)