CoSO4 💧⚡→ Co + SO2↑ + O2↑
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- Electrolysis of aqueous cobalt(II) sulfate without water as reactant
Electrolysis of aqueous cobalt(II) sulfate yields , sulfur dioxide, and (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:
Table of contents
Reaction data
Chemical equation
- Electrolysis of aqueous cobalt(II) sulfate without water as reactant
General equation
- Electrolysis of aqueous solution without water as reactant
- Miscible with water/Very soluble in water/Soluble in waterSelf redox agent💧⚡⟶ ProductOxidation product + ProductReduction product
Oxidation state of each atom
- Electrolysis of aqueous cobalt(II) sulfate without water as reactant
Reactants
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| CoSO4 | Cobalt(II) sulfate | 1 | Self redox agent | Very soluble in water |
Products
| Chemical formula | Name | Coefficient | Type | Type in general equation |
|---|---|---|---|---|
| 1 | Reduced | – | ||
| SO2 | Sulfur dioxide | 1 | Reduced | – |
| 1 | Oxidized | – |
Thermodynamic changes
Changes in standard condition (1)
- Electrolysis of aqueous cobalt(II) sulfate without water as reactant◆
ΔrG 482.1 kJ/mol K 0.35 × 10−84 pK 84.46
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 591.5 | 482.1 | 365.4 | – |
per 1 mol of | 591.5 | 482.1 | 365.4 | – |
| 591.5 | 482.1 | 365.4 | – | |
per 1 mol of | 591.5 | 482.1 | 365.4 | – |
| 591.5 | 482.1 | 365.4 | – |
Changes in standard condition (2)
- Electrolysis of aqueous cobalt(II) sulfate without water as reactant◆
ΔrG 482.4 kJ/mol K 0.31 × 10−84 pK 84.51
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 591.9 | 482.4 | 366.1 | – |
per 1 mol of | 591.9 | 482.4 | 366.1 | – |
| 591.9 | 482.4 | 366.1 | – | |
per 1 mol of | 591.9 | 482.4 | 366.1 | – |
| 591.9 | 482.4 | 366.1 | – |
Changes in aqueous solution (1)
- Electrolysis of aqueous cobalt(II) sulfate without water as reactant◆
ΔrG 482.1 kJ/mol K 0.35 × 10−84 pK 84.46
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 591.5 | 482.1 | 365.4 | – |
per 1 mol of | 591.5 | 482.1 | 365.4 | – |
| 591.5 | 482.1 | 365.4 | – | |
per 1 mol of | 591.5 | 482.1 | 365.4 | – |
| 591.5 | 482.1 | 365.4 | – |
Changes in aqueous solution (2)
- Electrolysis of aqueous cobalt(II) sulfate without water as reactant◆
ΔrG 498.5 kJ/mol K 0.46 × 10−87 pK 87.33
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 579.8 | 498.5 | 271.2 | – |
per 1 mol of | 579.8 | 498.5 | 271.2 | – |
| 579.8 | 498.5 | 271.2 | – | |
per 1 mol of | 579.8 | 498.5 | 271.2 | – |
| 579.8 | 498.5 | 271.2 | – |
Changes in aqueous solution (3)
- Electrolysis of aqueous cobalt(II) sulfate without water as reactant◆
ΔrG 481.6 kJ/mol K 0.42 × 10−84 pK 84.37
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 565.3 | 481.6 | 279.1 | – |
per 1 mol of | 565.3 | 481.6 | 279.1 | – |
| 565.3 | 481.6 | 279.1 | – | |
per 1 mol of | 565.3 | 481.6 | 279.1 | – |
| 565.3 | 481.6 | 279.1 | – |
Changes in aqueous solution (4)
- Electrolysis of aqueous cobalt(II) sulfate without water as reactant◆
ΔrG 498.0 kJ/mol K 0.57 × 10−87 pK 87.25
| Standard enthalpy of reaction ΔrH° kJ · mol−1 | Standard Gibbs energy of reaction ΔrG° kJ · mol−1 | Standard entropy of reaction ΔrS° J · K−1 · mol−1 | Standard heat capacity of reaction at constant pressure ΔrCp° J · K−1 · mol−1 | |
|---|---|---|---|---|
per 1 mol of Equation | 553.6 | 498.0 | 184.8 | – |
per 1 mol of | 553.6 | 498.0 | 184.8 | – |
| 553.6 | 498.0 | 184.8 | – | |
per 1 mol of | 553.6 | 498.0 | 184.8 | – |
| 553.6 | 498.0 | 184.8 | – |
Thermodynamic data of reactants
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| CoSO4 (cr) | -888.3[1] | -782.3[1] | 118.0[1] | – |
| CoSO4 (ai) | -967.3[1] | -799.1[1] | -92[1] | – |
| CoSO4 (cr) 6 hydrate | -2683.6[1] | -2235.36[1] | 367.61[1] | 353.38[1] |
| CoSO4 (cr) 7 hydrate | -2979.93[1] | -2473.42[1] | 406.06[1] | 390.49[1] |
* (cr):Crystalline solid, (ai):Ionized aqueous solution
Thermodynamic data of products
| Chemical formula | Standard enthalpy of formation ΔfH° kJ · mol−1 | Standard Gibbs energy of formation ΔfG° kJ · mol−1 | Standard molar entropy S° J · K−1 · mol−1 | Standard molar heat capacity at constant pressure Cp° J · K−1 · mol−1 |
|---|---|---|---|---|
| (cr) α, hexagonal | 0[1] | 0[1] | 30.04[1] | 24.81[1] |
| (cr) β, face centered cubic | 0.46[1] | 0.25[1] | 30.71[1] | – |
| (g) | 424.7[1] | 380.3[1] | 179.515[1] | 23.020[1] |
| SO2 (l) | -320.5[1] | – | – | – |
| SO2 (g) | -296.830[1] | -300.194[1] | 248.22[1] | 39.87[1] |
| SO2 (ao) | -322.980[1] | -300.676[1] | 161.9[1] | – |
| (g) | 0[1] | 0[1] | 205.138[1] | 29.355[1] |
| (ao) | -11.7[1] | 16.4[1] | 110.9[1] | – |
* (cr):Crystalline solid, (g):Gas, (l):Liquid, (ao):Un-ionized aqueous solution
References
List of references
- 1Janiel J. Reed (1989)The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI UnitsNational Institute of Standards and Technology (NIST)
- ^ ΔfH°, -888.3 kJ · mol−1
- ^ ΔfG°, -782.3 kJ · mol−1
- ^ S°, 118.0 J · K−1 · mol−1
- ^ ΔfH°, -967.3 kJ · mol−1
- ^ ΔfG°, -799.1 kJ · mol−1
- ^ S°, -92. J · K−1 · mol−1
- ^ ΔfH°, -2683.6 kJ · mol−1
- ^ ΔfG°, -2235.36 kJ · mol−1
- ^ S°, 367.61 J · K−1 · mol−1
- ^ Cp°, 353.38 J · K−1 · mol−1
- ^ ΔfH°, -2979.93 kJ · mol−1
- ^ ΔfG°, -2473.42 kJ · mol−1
- ^ S°, 406.06 J · K−1 · mol−1
- ^ Cp°, 390.49 J · K−1 · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 30.04 J · K−1 · mol−1
- ^ Cp°, 24.81 J · K−1 · mol−1
- ^ ΔfH°, 0.46 kJ · mol−1
- ^ ΔfG°, 0.25 kJ · mol−1
- ^ S°, 30.71 J · K−1 · mol−1
- ^ ΔfH°, 424.7 kJ · mol−1
- ^ ΔfG°, 380.3 kJ · mol−1
- ^ S°, 179.515 J · K−1 · mol−1
- ^ Cp°, 23.020 J · K−1 · mol−1
- ^ ΔfH°, -320.5 kJ · mol−1
- ^ ΔfH°, -296.830 kJ · mol−1
- ^ ΔfG°, -300.194 kJ · mol−1
- ^ S°, 248.22 J · K−1 · mol−1
- ^ Cp°, 39.87 J · K−1 · mol−1
- ^ ΔfH°, -322.980 kJ · mol−1
- ^ ΔfG°, -300.676 kJ · mol−1
- ^ S°, 161.9 J · K−1 · mol−1
- ^ ΔfH°, 0 kJ · mol−1
- ^ ΔfG°, 0 kJ · mol−1
- ^ S°, 205.138 J · K−1 · mol−1
- ^ Cp°, 29.355 J · K−1 · mol−1
- ^ ΔfH°, -11.7 kJ · mol−1
- ^ ΔfG°, 16.4 kJ · mol−1
- ^ S°, 110.9 J · K−1 · mol−1