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3Mn(CH3COO)2 ๐Ÿ’งโšกโ†’ 3MnO2 + 12C + 9H2โ†‘ + 2O3โ†‘

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Electrolysis of aqueous manganese(II) acetate without water as reactant
3Mn(CH3COO)2Manganese(II) acetate
๐Ÿ’งโšก
โŸถ
3MnO2Manganese(IV) oxide + 12CCarbon + 9H2โ†‘Hydrogen + 2O3โ†‘Ozone

Electrolysis of aqueous manganese(II) acetate yields manganese(IV) oxide, carbon, hydrogen, and ozone (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

Electrolysis of aqueous manganese(II) acetate without water as reactant
3Mn(CH3COO)2Manganese(II) acetate
๐Ÿ’งโšก
โŸถ
3MnO2Manganese(IV) oxide + 12CCarbon + 9H2โ†‘Hydrogen + 2O3โ†‘Ozone

General equation

Electrolysis of aqueous solution without water as reactant
Miscible with water/Very soluble in water/Soluble in waterSelf redox agent
๐Ÿ’งโšก
โŸถ
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Electrolysis of aqueous manganese(II) acetate without water as reactant

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
Mn(CH3COO)2Manganese(II) acetate3
Self redox agent
Very soluble in water

Products

Chemical formulaNameCoefficientTypeType in general
equation
MnO2Manganese(IV) oxide3
Oxidized
โ€“
CCarbon12
Redoxed product
โ€“
H2Hydrogen9
Reduced
โ€“
O3Ozone2
Oxidized
โ€“

Thermodynamic changes

Changes in standard condition (1)

Electrolysis of aqueous manganese(II) acetate without water as reactant
3Mn(CH3COO)2Crystalline solid
๐Ÿ’งโšก
โŸถ
3MnO2Crystalline solid + 12CCrystalline solidgraphite + 9H2โ†‘Gas + 2O3โ†‘Gas
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
2169.6โ€“โ€“โ€“
723.20โ€“โ€“โ€“
723.20โ€“โ€“โ€“
per 1 mol of
180.80โ€“โ€“โ€“
per 1 mol of
241.07โ€“โ€“โ€“
per 1 mol of
1084.8โ€“โ€“โ€“

Changes in standard condition (2)

Electrolysis of aqueous manganese(II) acetate without water as reactant
3Mn(CH3COO)2Crystalline solid
๐Ÿ’งโšก
โŸถ
3MnO2Crystalline solid + 12CCrystalline soliddiamond + 9H2โ†‘Gas + 2O3โ†‘Gas
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
2192.4โ€“โ€“โ€“
730.80โ€“โ€“โ€“
730.80โ€“โ€“โ€“
per 1 mol of
182.70โ€“โ€“โ€“
per 1 mol of
243.60โ€“โ€“โ€“
per 1 mol of
1096.2โ€“โ€“โ€“

Changes in standard condition (3)

Electrolysis of aqueous manganese(II) acetate without water as reactant
3Mn(CH3COO)2Crystalline solid
๐Ÿ’งโšก
โŸถ
3MnO2Amorphous solidprecipitated + 12CCrystalline solidgraphite + 9H2โ†‘Gas + 2O3โ†‘Gas
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
2222.2โ€“โ€“โ€“
740.73โ€“โ€“โ€“
740.73โ€“โ€“โ€“
per 1 mol of
185.18โ€“โ€“โ€“
per 1 mol of
246.91โ€“โ€“โ€“
per 1 mol of
1111.1โ€“โ€“โ€“

Changes in standard condition (4)

Electrolysis of aqueous manganese(II) acetate without water as reactant
3Mn(CH3COO)2Crystalline solid
๐Ÿ’งโšก
โŸถ
3MnO2Amorphous solidprecipitated + 12CCrystalline soliddiamond + 9H2โ†‘Gas + 2O3โ†‘Gas
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
2244.9โ€“โ€“โ€“
748.30โ€“โ€“โ€“
748.30โ€“โ€“โ€“
per 1 mol of
187.08โ€“โ€“โ€“
per 1 mol of
249.43โ€“โ€“โ€“
per 1 mol of
1122.5โ€“โ€“โ€“

Changes in aqueous solution (1)

Electrolysis of aqueous manganese(II) acetate without water as reactant
3Mn(CH3COO)2Aqueous solution
๐Ÿ’งโšก
โŸถ
3MnO2Crystalline solid + 12CCrystalline solidgraphite + 9H2โ†‘Gas + 2O3โ†‘Gas
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
2322.6โ€“โ€“โ€“
774.20โ€“โ€“โ€“
774.20โ€“โ€“โ€“
per 1 mol of
193.55โ€“โ€“โ€“
per 1 mol of
258.07โ€“โ€“โ€“
per 1 mol of
1161.3โ€“โ€“โ€“

Changes in aqueous solution (2)

Electrolysis of aqueous manganese(II) acetate without water as reactant
3Mn(CH3COO)2Aqueous solution
๐Ÿ’งโšก
โŸถ
3MnO2Crystalline solid + 12CCrystalline solidgraphite + 9H2โ†‘Gas + 2O3โ†‘Un-ionized aqueous solution
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
2289.0โ€“โ€“โ€“
763.00โ€“โ€“โ€“
763.00โ€“โ€“โ€“
per 1 mol of
190.75โ€“โ€“โ€“
per 1 mol of
254.33โ€“โ€“โ€“
per 1 mol of
1144.5โ€“โ€“โ€“

Changes in aqueous solution (3)

Electrolysis of aqueous manganese(II) acetate without water as reactant
3Mn(CH3COO)2Aqueous solution
๐Ÿ’งโšก
โŸถ
3MnO2Crystalline solid + 12CCrystalline solidgraphite + 9H2โ†‘Un-ionized aqueous solution + 2O3โ†‘Gas
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
2284.8โ€“โ€“โ€“
761.60โ€“โ€“โ€“
761.60โ€“โ€“โ€“
per 1 mol of
190.40โ€“โ€“โ€“
per 1 mol of
253.87โ€“โ€“โ€“
per 1 mol of
1142.4โ€“โ€“โ€“

Changes in aqueous solution (4)

Electrolysis of aqueous manganese(II) acetate without water as reactant
3Mn(CH3COO)2Aqueous solution
๐Ÿ’งโšก
โŸถ
3MnO2Crystalline solid + 12CCrystalline solidgraphite + 9H2โ†‘Un-ionized aqueous solution + 2O3โ†‘Un-ionized aqueous solution
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1		Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1		Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
2251.2โ€“โ€“โ€“
750.40โ€“โ€“โ€“
750.40โ€“โ€“โ€“
per 1 mol of
187.60โ€“โ€“โ€“
per 1 mol of
250.13โ€“โ€“โ€“
per 1 mol of
1125.6โ€“โ€“โ€“

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ฮ”fHยฐ
kJ ยท molโˆ’1		Standard Gibbs
energy of
formation
ฮ”fGยฐ
kJ ยท molโˆ’1		Standard
molar entropy
Sยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard molar
heat capacity at
constant pressure
Cpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Mn(CH3COO)2 (cr)-1148.1[1]โ€“โ€“โ€“
Mn(CH3COO)2 (aq)-1199.1[1]โ€“โ€“โ€“
Mn(CH3COO)2 (cr)
4 hydrate
-2338.0[1]โ€“โ€“โ€“
* (cr):Crystalline solid, (aq):Aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ฮ”fHยฐ
kJ ยท molโˆ’1		Standard Gibbs
energy of
formation
ฮ”fGยฐ
kJ ยท molโˆ’1		Standard
molar entropy
Sยฐ
J ยท Kโˆ’1 ยท molโˆ’1		Standard molar
heat capacity at
constant pressure
Cpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
MnO2 (cr)-520.03[1]-465.14[1]53.05[1]54.14[1]
MnO2 (am)
precipitated
-502.5[1]โ€“โ€“โ€“
C (cr)
graphite
0[1]0[1]5.740[1]8.527[1]
C (cr)
diamond
1.895[1]2.900[1]2.377[1]6.113[1]
C (g)716.682[1]671.257[1]158.096[1]20.838[1]
H2 (g)0[1]0[1]130.684[1]28.824[1]
H2 (ao)-4.2[1]17.6[1]577[1]โ€“
O3 (g)142.7[1]163.2[1]238.93[1]39.20[1]
O3 (ao)125.9[1]174.1[1]146[1]โ€“
* (cr):Crystalline solid, (am):Amorphous solid, (g):Gas, (ao):Un-ionized aqueous solution

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)