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6Mn(CH3COO)2 ๐Ÿ’งโšกโ†’ 3Mn2O3 + 24C + 18H2โ†‘ + 5O3โ†‘

Electrolysis of aqueous manganese(II) acetate without water as reactant
6Mn(CH3COO)2Manganese(II) acetate
๐Ÿ’งโšก
โŸถ
3Mn2O3Manganese(III) oxide + 24CCarbon + 18H2โ†‘Hydrogen + 5O3โ†‘Ozone

Electrolysis of aqueous manganese(II) acetate yields manganese(III) oxide, carbon, hydrogen, and ozone (Other reactions are here). This reaction is an oxidation-reduction reaction and is classified as follows:

Table of contents
  1. 1Reaction data
  2. 2Thermodynamic changes
  3. 3References
  4. 4Related reactions
  5. 5Related categories

Reaction data

Chemical equation

Electrolysis of aqueous manganese(II) acetate without water as reactant
6Mn(CH3COO)2Manganese(II) acetate
๐Ÿ’งโšก
โŸถ
3Mn2O3Manganese(III) oxide + 24CCarbon + 18H2โ†‘Hydrogen + 5O3โ†‘Ozone

General equation

Electrolysis of aqueous solution without water as reactant
Miscible with water/Very soluble in water/Soluble in waterSelf redox agent
๐Ÿ’งโšก
โŸถ
ProductOxidation product + ProductReduction product

Oxidation state of each atom

Electrolysis of aqueous manganese(II) acetate without water as reactant

Reactants

Chemical formulaNameCoefficientTypeType in general
equation
Mn(CH3COO)2Manganese(II) acetate6
Self redox agent
Very soluble in water

Products

Chemical formulaNameCoefficientTypeType in general
equation
Mn2O3Manganese(III) oxide3
Oxidized
โ€“
CCarbon24
Redoxed product
โ€“
H2Hydrogen18
Reduced
โ€“
O3Ozone5
Oxidized
โ€“

Thermodynamic changes

Changes in standard condition (1)

Electrolysis of aqueous manganese(II) acetate without water as reactant
6Mn(CH3COO)2Crystalline solid
๐Ÿ’งโšก
โŸถ
3Mn2O3Crystalline solid + 24CCrystalline solidgraphite + 18H2โ†‘Gas + 5O3โ†‘Gas
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
4725.1โ€“โ€“โ€“
787.52โ€“โ€“โ€“
1575.0โ€“โ€“โ€“
per 1 mol of
196.88โ€“โ€“โ€“
per 1 mol of
262.51โ€“โ€“โ€“
per 1 mol of
945.02โ€“โ€“โ€“

Changes in standard condition (2)

Electrolysis of aqueous manganese(II) acetate without water as reactant
6Mn(CH3COO)2Crystalline solid
๐Ÿ’งโšก
โŸถ
3Mn2O3Crystalline solid + 24CCrystalline soliddiamond + 18H2โ†‘Gas + 5O3โ†‘Gas
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
4770.6โ€“โ€“โ€“
795.10โ€“โ€“โ€“
1590.2โ€“โ€“โ€“
per 1 mol of
198.78โ€“โ€“โ€“
per 1 mol of
265.03โ€“โ€“โ€“
per 1 mol of
954.12โ€“โ€“โ€“

Changes in aqueous solution (1)

Electrolysis of aqueous manganese(II) acetate without water as reactant
6Mn(CH3COO)2Aqueous solution
๐Ÿ’งโšก
โŸถ
3Mn2O3Crystalline solid + 24CCrystalline solidgraphite + 18H2โ†‘Gas + 5O3โ†‘Gas
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
5031.1โ€“โ€“โ€“
838.52โ€“โ€“โ€“
1677.0โ€“โ€“โ€“
per 1 mol of
209.63โ€“โ€“โ€“
per 1 mol of
279.51โ€“โ€“โ€“
per 1 mol of
1006.2โ€“โ€“โ€“

Changes in aqueous solution (2)

Electrolysis of aqueous manganese(II) acetate without water as reactant
6Mn(CH3COO)2Aqueous solution
๐Ÿ’งโšก
โŸถ
3Mn2O3Crystalline solid + 24CCrystalline solidgraphite + 18H2โ†‘Gas + 5O3โ†‘Un-ionized aqueous solution
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
4947.1โ€“โ€“โ€“
824.52โ€“โ€“โ€“
1649.0โ€“โ€“โ€“
per 1 mol of
206.13โ€“โ€“โ€“
per 1 mol of
274.84โ€“โ€“โ€“
per 1 mol of
989.42โ€“โ€“โ€“

Changes in aqueous solution (3)

Electrolysis of aqueous manganese(II) acetate without water as reactant
6Mn(CH3COO)2Aqueous solution
๐Ÿ’งโšก
โŸถ
3Mn2O3Crystalline solid + 24CCrystalline solidgraphite + 18H2โ†‘Un-ionized aqueous solution + 5O3โ†‘Gas
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
4955.5โ€“โ€“โ€“
825.92โ€“โ€“โ€“
1651.8โ€“โ€“โ€“
per 1 mol of
206.48โ€“โ€“โ€“
per 1 mol of
275.31โ€“โ€“โ€“
per 1 mol of
991.10โ€“โ€“โ€“

Changes in aqueous solution (4)

Electrolysis of aqueous manganese(II) acetate without water as reactant
6Mn(CH3COO)2Aqueous solution
๐Ÿ’งโšก
โŸถ
3Mn2O3Crystalline solid + 24CCrystalline solidgraphite + 18H2โ†‘Un-ionized aqueous solution + 5O3โ†‘Un-ionized aqueous solution
Standard enthalpy
of reaction
ฮ”rHยฐ
kJ ยท molโˆ’1
Standard
Gibbs energy
of reaction
ฮ”rGยฐ
kJ ยท molโˆ’1
Standard entropy
of reaction
ฮ”rSยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard heat
capacity of reaction
at constant pressure
ฮ”rCpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
per 1 mol of
Equation
4871.5โ€“โ€“โ€“
811.92โ€“โ€“โ€“
1623.8โ€“โ€“โ€“
per 1 mol of
202.98โ€“โ€“โ€“
per 1 mol of
270.64โ€“โ€“โ€“
per 1 mol of
974.30โ€“โ€“โ€“

Thermodynamic data of reactants

Chemical formulaStandard enthalpy
of formation
ฮ”fHยฐ
kJ ยท molโˆ’1
Standard Gibbs
energy of
formation
ฮ”fGยฐ
kJ ยท molโˆ’1
Standard
molar entropy
Sยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard molar
heat capacity at
constant pressure
Cpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Mn(CH3COO)2 (cr)-1148.1[1]โ€“โ€“โ€“
Mn(CH3COO)2 (aq)-1199.1[1]โ€“โ€“โ€“
Mn(CH3COO)2 (cr)
4 hydrate
-2338.0[1]โ€“โ€“โ€“
* (cr):Crystalline solid, (aq):Aqueous solution

Thermodynamic data of products

Chemical formulaStandard enthalpy
of formation
ฮ”fHยฐ
kJ ยท molโˆ’1
Standard Gibbs
energy of
formation
ฮ”fGยฐ
kJ ยท molโˆ’1
Standard
molar entropy
Sยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Standard molar
heat capacity at
constant pressure
Cpยฐ
J ยท Kโˆ’1 ยท molโˆ’1
Mn2O3 (cr)-959.0[1]-881.1[1]110.5[1]107.65[1]
C (cr)
graphite
0[1]0[1]5.740[1]8.527[1]
C (cr)
diamond
1.895[1]2.900[1]2.377[1]6.113[1]
C (g)716.682[1]671.257[1]158.096[1]20.838[1]
H2 (g)0[1]0[1]130.684[1]28.824[1]
H2 (ao)-4.2[1]17.6[1]577[1]โ€“
O3 (g)142.7[1]163.2[1]238.93[1]39.20[1]
O3 (ao)125.9[1]174.1[1]146[1]โ€“
* (cr):Crystalline solid, (g):Gas, (ao):Un-ionized aqueous solution

References

List of references

  1. 1
    Janiel J. Reed (1989)
    The NBS Tables of Chemical Thermodynamic Properties: Selected Values for Inorganic and C1 and C2 Organic Substances in SI Units
    National Institute of Standards and Technology (NIST)