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Silver(I) permanganate

Chemical structure of silver(I) permanganate

Silver(I) permanganate is an inorganic compound with formula AgMnO4.

Table of contents
  1. 1Names
  2. 2Formulae and structures
  3. 3Properties
  4. 4Constituents
  5. 5Thermodynamic properties
  6. 6Solubility
  7. 7Preparations
  8. 8Chemical reactions
  9. 9References
  10. 10Related substances
  11. 11Related categories

Names

List of substance names

Nomenclature
Name
Typical name
Silver(I) permanganate
Compositional nomenclature
Silver(I) permanganate
Additive nomenclature
Silver(I) tetraoxidomanganate(1−)
Other names
Silver(I) manganate(VII)

Formulae and structures

List of formulae

Formula name
Formula
Typical formula
AgMnO4
Compositional formula
AgMnO4
Structural formula
Chemical structure of silver(I) permanganate
Other structural formulas
Chemical structure of silver(I) permanganate with double bonds
Lewis structure
Lewis structure of silver(I) permanganate
Colored Lewis structure
Colored Lewis structure of silver(I) permanganate

Properties

List of substance properties

Item
Value
Name
Silver(I) permanganate
Formula
AgMnO4
Appearance
Black purple solid
Odor
Odorless
Molar mass
226.802 g/mol
Density
4.49 g/cm3[1]
Solid
Melting point
Boiling point

Constituents

Constituent ions

IonNameCharge numberNumber
Ag+Silver(I) ion11
MnO4Permanganate ion-11

Constituent atoms

AtomNameOxidation stateNumber
AgSilver+11
MnMangenese+71
OOxygen−24

Ratio of atoms

AtomAtomic weightNumberAtomic ratioWeight ratio
Ag107.8682116.67%47.56%
Mn54.938116.67%24.22%
O15.999466.67%28.22%
AgMnOAtomic ratio
AgMnOWeight ratio

Thermodynamic properties

Phase transition properties

Item
Value
Enthalpy of fusion
Enthalpy of vaporization
Enthalpy of vaporization at 25°C
Enthalpy of other transition

Solubility

Qualitative solubility

Reactive
R-OH[1]Alcohol
Miscible
Very soluble
Soluble
Slightly soluble
Very slightly soluble
Insoluble

Solubility in water (g/100 mL)[2]

20°C
0.92

Solubility in water (g/100 mL)[1]

20°C
0.9

Solubility curve (g/100 mL)

0°C20°C40°C60°C80°C100°CTemperature (°C)0.00.20.40.60.81.0Solubility (g/100 mL)

Preparations

Reaction of basic oxide and acid

The reaction of silver(I) oxide and permanganic acid yields silver(I) permanganate and water.

Reaction of basic oxide and acidic oxide

The reaction of silver(I) oxide and manganese(VII) oxide yields silver(I) permanganate.

Reaction of salt of weak acid and strong acid

The reaction of salt of weak acid and strong acid can yield silver(I) permanganate.

Precipitation reaction

When silver(I) ion and permanganate ion react in aqueous solution, a precipitate of silver(I) permanganate is formed.

Reaction of inactive metal and oxidizing acid

The reaction of silver and permanganic acid yields silver(I) permanganate, manganese(IV) oxide, and water.

Chemical reactions

Electrolytic dissociation

Electrolytic dissociation of silver(I) permanganate yields silver(I) ion and permanganate ion.

Reaction with dehydrating acid

The reaction of silver(I) permanganate and sulfuric acid yields silver(I) sulfate, manganese(VII) oxide, and water.

Reaction with reducing species

The reaction of reducing species and silver(I) permanganate yields a variety of products.

Reaction with oxidizable species

The reaction of oxidizable species and silver(I) permanganate yields a variety of products.

Reaction with oxidizable species under acidic condition

The reaction of oxidizable species, silver(I) permanganate, and hydrogen ion yields a variety of products.

Reaction of copper and silver(I) permanganate under acidic condition
5CuCopper + 2AgMnO4Silver(I) permanganate + 16H+Hydrogen ion
🔥
5Cu2+Copper(II) ion + 2Mn2+Manganese(II) ion + 2Ag+Silver(I) ion + 8H2OWater
Reaction of copper and silver(I) permanganate under acidic condition
2CuCopper + AgMnO4Silver(I) permanganate + 8H+Hydrogen ion
🔥
2Cu2+Copper(II) ion + Mn3+Manganese(III) ion + Ag+Silver(I) ion + 4H2OWater

Reaction with oxidizable species under neutral condition

The reaction of oxidizable species, silver(I) permanganate, and water yields a variety of products.

Reaction with hardly oxidizable species

The reaction of hardly oxidizable species and silver(I) permanganate yields a variety of products.

Reaction with hardly oxidizable species under acidic condition

The reaction of hardly oxidizable species, silver(I) permanganate, and hydrogen ion yields a variety of products.

Reaction of hydrogen chloride and silver(I) permanganate under acidic condition
10HClHydrogen chloride + 2AgMnO4Silver(I) permanganate + 6H+Hydrogen ion
5Cl2Chlorine + 2Mn2+Manganese(II) ion + 2Ag+Silver(I) ion + 8H2OWater
Reaction of hydrogen chloride and silver(I) permanganate under acidic condition
4HClHydrogen chloride + AgMnO4Silver(I) permanganate + 4H+Hydrogen ion
2Cl2Chlorine + Mn3+Manganese(III) ion + Ag+Silver(I) ion + 4H2OWater
Reaction of gold and silver(I) permanganate under acidic condition
5AuGold + 3AgMnO4Silver(I) permanganate + 24H+Hydrogen ion
🔥
5Au3+Gold(III) ion + 3Mn2+Manganese(II) ion + 3Ag+Silver(I) ion + 12H2OWater
Reaction of gold and silver(I) permanganate under acidic condition
4AuGold + 3AgMnO4Silver(I) permanganate + 24H+Hydrogen ion
🔥
4Au3+Gold(III) ion + 3Mn3+Manganese(III) ion + 3Ag+Silver(I) ion + 12H2OWater

Reaction with hardly oxidizable species under neutral condition

The reaction of hardly oxidizable species, silver(I) permanganate, and water yields a variety of products.

Decomposition

Decomposition of silver(I) permanganate yields a variety of products.

References

List of references

  1. 1
  2. 2
    Atherton Seidell (1919)
    Solubilities of Inorganic and Organic Compounds: A Compilation of Quantitative Solubility Data From the Periodical Literature
    D. Van Nostrand Company